data_250807_byx_0806_bn
_audit_creation_date               2025-08-19
_audit_creation_method
;
Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
;
_shelx_SHELXL_version_number       '2019/3'
_audit_contact_author_address      ?
_audit_contact_author_email        ?
_audit_contact_author_name         ''
_audit_contact_author_phone        ?
_publ_contact_author_id_orcid      ?
_publ_section_references
;
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.

Sheldrick, G.M. (2015). Acta Cryst. A71, 3-8.

Sheldrick, G.M. (2015). Acta Cryst. C71, 3-8.
;
_chemical_name_common              ?
_chemical_name_systematic          ?
_chemical_formula_moiety           'C16 H42 Ge Si4'
_chemical_formula_sum              'C16 H42 Ge Si4'
_chemical_formula_weight           419.44
_chemical_melting_point            ?
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'C' 'C' 0.0148 0.0070 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Ge' 'Ge' -1.5187 0.6907
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Si' 'Si' 0.2153 0.2529 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system        'monoclinic'
_space_group_IT_number             14
_space_group_name_H-M_alt          'P 1 21/c 1'
_space_group_name_Hall             '-P 2ybc'
loop_
  _space_group_symop_operation_xyz
 'x, y, z'
 '-x, y+1/2, -z+1/2'
 '-x, -y, -z'
 'x, -y-1/2, z-1/2'

_cell_length_a                     16.7818(12)
_cell_length_b                     6.9005(5)
_cell_length_c                     21.8834(14)
_cell_angle_alpha                  90
_cell_angle_beta                   108.776(2)
_cell_angle_gamma                  90
_cell_volume                       2399.3(3)
_cell_formula_units_Z              4
_cell_measurement_reflns_used      6476
_cell_measurement_temperature      170(2)
_cell_measurement_theta_max        60.639
_cell_measurement_theta_min        3.712
_shelx_estimated_absorpt_T_max     0.888
_shelx_estimated_absorpt_T_min     0.530
_exptl_absorpt_coefficient_mu      2.425
_exptl_absorpt_correction_T_max    0.7519
_exptl_absorpt_correction_T_min    0.5689
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1650 before and 0.0956 after correction.
The Ratio of minimum to maximum transmission is 0.7566.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details     ?
_exptl_crystal_colour              colourless
_exptl_crystal_colour_primary      colourless
_exptl_crystal_density_diffrn      1.161
_exptl_crystal_density_meas        ?
_exptl_crystal_density_method      'not measured'
_exptl_crystal_description         needle
_exptl_crystal_F_000               904
_exptl_crystal_mounting_method
;
 Crystals were removed from the crystallisation vial and immediately coated
 with PDMS (polydimethylsiloxane/Dimethicone, CAS: 9006-65-9 on a glass slide.
 A suitable single crystal was selected and mounted on a glass fiber using
 vacuum silicone grease as adhesive. The glass fiber with single crystal was
 mounted on copper pin with solid paraffin. Operator: DJ_Tokyo.
;
_exptl_crystal_size_max            0.3
_exptl_crystal_size_mid            0.05
_exptl_crystal_size_min            0.05
_exptl_transmission_factor_max     ?
_exptl_transmission_factor_min     ?
_diffrn_reflns_av_R_equivalents    0.0610
_diffrn_reflns_av_unetI/netI       0.0672
_diffrn_reflns_Laue_measured_fraction_full  0.998
_diffrn_reflns_Laue_measured_fraction_max  0.989
_diffrn_reflns_limit_h_max         21
_diffrn_reflns_limit_h_min         -21
_diffrn_reflns_limit_k_max         8
_diffrn_reflns_limit_k_min         -8
_diffrn_reflns_limit_l_max         23
_diffrn_reflns_limit_l_min         -28
_diffrn_reflns_number              22098
_diffrn_reflns_point_group_measured_fraction_full  0.998
_diffrn_reflns_point_group_measured_fraction_max  0.989
_diffrn_reflns_theta_full          53.594
_diffrn_reflns_theta_max           60.856
_diffrn_reflns_theta_min           2.419
_diffrn_ambient_temperature        170(2)
_diffrn_detector                   'Bruker PHOTON-II area detector'
_diffrn_detector_area_resol_mean   7.4
_diffrn_detector_type              'CMOS-PHOTONII area detector'
_diffrn_measured_fraction_theta_full  0.998
_diffrn_measured_fraction_theta_max  0.989
_diffrn_measurement_device         'three-circle diffractometer'
_diffrn_measurement_device_type    'Bruker D8 Venture_Air'
_diffrn_measurement_method         'phi and omega scans'
_diffrn_radiation_monochromator    graphite
_diffrn_radiation_probe            X-ray
_diffrn_radiation_type             GaK\a
_diffrn_radiation_wavelength       1.34139
_diffrn_source                     'sealed X-ray tube'
_diffrn_source_current             3.57
_diffrn_source_power               0.24957869999999996
_diffrn_source_target              Mo
_diffrn_source_voltage             69.91
_reflns_Friedel_coverage           0.000
_reflns_Friedel_fraction_full      .
_reflns_Friedel_fraction_max       .
_reflns_number_gt                  4361
_reflns_number_total               5466
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression       'I > 2σ(I)'
_computing_cell_refinement         'SAINT V8.40B (Bruker, 2016)'
_computing_data_collection         'Bruker D8 Venture diffractometer'
_computing_data_reduction          'SAINT V8.40B (Bruker, 2016)'
_computing_molecular_graphics      'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement    'SHELXL 2019/3 (Sheldrick, 2015)'
_computing_structure_solution      'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max           0.396
_refine_diff_density_min           -0.482
_refine_diff_density_rms           0.096
_refine_ls_extinction_coef         .
_refine_ls_extinction_method       none
_refine_ls_goodness_of_fit_ref     1.128
_refine_ls_hydrogen_treatment      mixed
_refine_ls_matrix_type             full
_refine_ls_number_parameters       264
_refine_ls_number_reflns           5466
_refine_ls_number_restraints       26
_refine_ls_R_factor_all            0.0628
_refine_ls_R_factor_gt             0.0501
_refine_ls_restrained_S_all        1.128
_refine_ls_shift/su_max            0.001
_refine_ls_shift/su_mean           0.000
_refine_ls_structure_factor_coef   Fsqd
_refine_ls_weighting_details      
 'w=1/[σ²(Fo²)+(0.0647P)²+0.4711P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme        calc
_refine_ls_wR_factor_gt            0.1261
_refine_ls_wR_factor_ref           0.1327
_refine_special_details            ?
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 C2-C1 = C3-C2 = C4-C3
 1.54 with sigma of 0.01
 Si03-C4 \\sim Si03-C4A
 with sigma of 0.01
3. Uiso/Uaniso restraints and constraints
Uanis(C4A) \\sim Ueq, Uanis(C4) \\sim Ueq: with sigma of 0.01 and sigma for
terminal atoms of 0.02
4. Same fragment restrains
{Ge2, C1A, C2A, C3A, C4A} sigma for 1-2: 0.02, 1-3: 0.02
as in
{Ge1, C1, C2, C3, C4}
5. Others
 Sof(Ge1)=Sof(C1)=Sof(C2)=Sof(H2A)=Sof(H2B)=Sof(C3)=Sof(H3A)=Sof(H3B)=Sof(C4)=
 Sof(H1A)=Sof(H1B)=1-FVAR(1)
 Sof(Ge2)=Sof(C1A)=Sof(C2A)=Sof(H2AA)=Sof(H2AB)=Sof(C3A)=Sof(H3AA)=Sof(H3AB)=
 Sof(C4A)=Sof(H2C)=Sof(H2D)=FVAR(1)
6.a Secondary CH2 refined with riding coordinates:
 C2(H2A,H2B), C3(H3A,H3B), C2A(H2AA,H2AB), C3A(H3AA,H3AB)
6.b Idealised Me refined as rotating group:
 C5(H5A,H5B,H5C), C6(H6A,H6B,H6C), C7(H7A,H7B,H7C), C8(H8A,H8B,H8C), C9(H9A,
 H9B,H9C), C10(H10A,H10B,H10C), C11(H11A,H11B,H11C), C12(H12A,H12B,H12C),
 C13(H13A,H13B,H13C), C14(H14A,H14B,H14C), C15(H15A,H15B,H15C), C16(H16A,H16B,
 H16C)
;
_atom_sites_solution_hydrogens     mixed
_atom_sites_solution_primary       dual
_atom_sites_solution_secondary     difmap
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_site_symmetry_order
  _atom_site_calc_flag
  _atom_site_refinement_flags_posn
  _atom_site_refinement_flags_adp
  _atom_site_refinement_flags_occupancy
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 Si03 Si 0.34803(4) 0.56046(9) 0.65187(3) 0.03029(17) Uani 1 1 d D . . . .
 Si04 Si 0.15258(4) 0.50964(10) 0.60215(3) 0.03521(18) Uani 1 1 d . . . . .
 Si05 Si 0.16485(4) 0.31670(10) 0.83323(3) 0.03757(19) Uani 1 1 d . . . . .
 Si06 Si 0.34925(4) 0.47597(11) 0.88524(3) 0.0413(2) Uani 1 1 d . . . . .
 C5 C 0.4135(2) 0.2517(6) 0.9127(2) 0.0795(11) Uani 1 1 d . . . . .
 H5A H 0.457904 0.277589 0.953696 0.119 Uiso 1 1 calc R U . . .
 H5B H 0.439027 0.212943 0.880155 0.119 Uiso 1 1 calc R U . . .
 H5C H 0.377212 0.147193 0.918784 0.119 Uiso 1 1 calc R U . . .
 C6 C 0.31841(17) 0.5682(5) 0.95462(11) 0.0533(7) Uani 1 1 d . . . . .
 H6A H 0.285707 0.687715 0.941944 0.080 Uiso 1 1 calc R U . . .
 H6B H 0.369112 0.594809 0.991211 0.080 Uiso 1 1 calc R U . . .
 H6C H 0.284204 0.470450 0.967130 0.080 Uiso 1 1 calc R U . . .
 C7 C 0.4224(3) 0.6652(6) 0.87367(16) 0.0866(14) Uani 1 1 d . . . . .
 H7A H 0.391339 0.786311 0.859669 0.130 Uiso 1 1 calc R U . . .
 H7B H 0.446553 0.622053 0.840769 0.130 Uiso 1 1 calc R U . . .
 H7C H 0.467606 0.686786 0.914505 0.130 Uiso 1 1 calc R U . . .
 C8 C 0.20201(18) 0.1106(5) 0.88983(15) 0.0571(8) Uani 1 1 d . . . . .
 H8A H 0.233442 0.019456 0.871922 0.086 Uiso 1 1 calc R U . . .
 H8B H 0.153504 0.044373 0.895982 0.086 Uiso 1 1 calc R U . . .
 H8C H 0.238713 0.159245 0.931450 0.086 Uiso 1 1 calc R U . . .
 C9 C 0.11133(18) 0.4990(5) 0.87039(16) 0.0610(8) Uani 1 1 d . . . . .
 H9A H 0.147440 0.528260 0.914423 0.092 Uiso 1 1 calc R U . . .
 H9B H 0.057673 0.446041 0.871580 0.092 Uiso 1 1 calc R U . . .
 H9C H 0.100936 0.618041 0.844580 0.092 Uiso 1 1 calc R U . . .
 C10 C 0.0794(2) 0.2120(6) 0.76309(14) 0.0773(12) Uani 1 1 d . . . . .
 H10A H 0.057362 0.312736 0.730427 0.116 Uiso 1 1 calc R U . . .
 H10B H 0.033880 0.163347 0.777907 0.116 Uiso 1 1 calc R U . . .
 H10C H 0.102244 0.105307 0.744291 0.116 Uiso 1 1 calc R U . . .
 C11 C 0.44874(15) 0.4813(4) 0.71361(12) 0.0449(6) Uani 1 1 d . . . . .
 H11A H 0.452751 0.537936 0.755565 0.067 Uiso 1 1 calc R U . . .
 H11B H 0.496493 0.524933 0.700616 0.067 Uiso 1 1 calc R U . . .
 H11C H 0.449652 0.339645 0.716941 0.067 Uiso 1 1 calc R U . . .
 C12 C 0.35937(19) 0.8267(4) 0.63939(15) 0.0568(8) Uani 1 1 d . . . . .
 H12A H 0.307818 0.875655 0.607523 0.085 Uiso 1 1 calc R U . . .
 H12B H 0.407185 0.848420 0.623738 0.085 Uiso 1 1 calc R U . . .
 H12C H 0.369037 0.895171 0.680379 0.085 Uiso 1 1 calc R U . . .
 C13 C 0.34772(17) 0.4275(5) 0.57749(12) 0.0546(8) Uani 1 1 d . . . . .
 H13A H 0.342062 0.288203 0.583747 0.082 Uiso 1 1 calc R U . . .
 H13B H 0.400599 0.452405 0.568859 0.082 Uiso 1 1 calc R U . . .
 H13C H 0.300348 0.472181 0.540815 0.082 Uiso 1 1 calc R U . . .
 C14 C 0.1407(2) 0.2732(5) 0.55847(19) 0.0763(11) Uani 1 1 d . . . . .
 H14A H 0.195875 0.229641 0.557461 0.114 Uiso 1 1 calc R U . . .
 H14B H 0.102638 0.289481 0.514218 0.114 Uiso 1 1 calc R U . . .
 H14C H 0.117452 0.176441 0.580817 0.114 Uiso 1 1 calc R U . . .
 C15 C 0.0532(2) 0.5479(8) 0.62073(16) 0.0993(17) Uani 1 1 d . . . . .
 H15A H 0.043931 0.438645 0.646270 0.149 Uiso 1 1 calc R U . . .
 H15B H 0.006000 0.556998 0.580368 0.149 Uiso 1 1 calc R U . . .
 H15C H 0.057137 0.668174 0.645340 0.149 Uiso 1 1 calc R U . . .
 C16 C 0.15350(19) 0.7067(5) 0.54406(14) 0.0594(8) Uani 1 1 d . . . . .
 H16A H 0.155160 0.832753 0.565037 0.089 Uiso 1 1 calc R U . . .
 H16B H 0.102566 0.698084 0.506377 0.089 Uiso 1 1 calc R U . . .
 H16C H 0.203251 0.692662 0.530246 0.089 Uiso 1 1 calc R U . . .
 Ge1 Ge 0.26655(3) 0.30373(7) 0.73640(3) 0.0277(2) Uani 0.5568(13) 1 d D . P A
 1
 C1 C 0.2443(5) 0.4446(13) 0.8085(3) 0.0255(15) Uani 0.5568(13) 1 d D . P A 1
 C2 C 0.2081(3) 0.6402(6) 0.7746(2) 0.0348(10) Uani 0.5568(13) 1 d D . P A 1
 H2A H 0.146646 0.627097 0.753209 0.042 Uiso 0.5568(13) 1 calc R U P A 1
 H2B H 0.217626 0.743828 0.807427 0.042 Uiso 0.5568(13) 1 calc R U P A 1
 C3 C 0.2505(3) 0.6981(7) 0.7235(2) 0.0362(10) Uani 0.5568(13) 1 d D . P A 1
 H3A H 0.220365 0.810621 0.698503 0.043 Uiso 0.5568(13) 1 calc R U P A 1
 H3B H 0.309338 0.737872 0.745965 0.043 Uiso 0.5568(13) 1 calc R U P A 1
 C4 C 0.2500(4) 0.5297(14) 0.6765(3) 0.027(2) Uani 0.5568(13) 1 d D U P A 1
 H1A H 0.353(3) 0.209(7) 0.762(2) 0.041(13) Uiso 0.5568(13) 1 d . . P A 1
 H1B H 0.199(3) 0.137(7) 0.706(2) 0.037(12) Uiso 0.5568(13) 1 d . . P A 1
 Ge2 Ge 0.23651(5) 0.62586(10) 0.75043(4) 0.0314(3) Uani 0.4432(13) 1 d D . P A
 2
 C1A C 0.2677(7) 0.4062(17) 0.8128(4) 0.0256(19) Uani 0.4432(13) 1 d D . P A 2
 C2A C 0.3012(4) 0.2563(7) 0.7734(3) 0.0300(11) Uani 0.4432(13) 1 d D . P A 2
 H2AA H 0.362079 0.278540 0.781970 0.036 Uiso 0.4432(13) 1 calc R U P A 2
 H2AB H 0.294172 0.123938 0.788400 0.036 Uiso 0.4432(13) 1 calc R U P A 2
 C3A C 0.2549(4) 0.2698(8) 0.6994(3) 0.0320(12) Uani 0.4432(13) 1 d D . P A 2
 H3AA H 0.196692 0.220368 0.689596 0.038 Uiso 0.4432(13) 1 calc R U P A 2
 H3AB H 0.284211 0.187484 0.676346 0.038 Uiso 0.4432(13) 1 calc R U P A 2
 C4A C 0.2522(5) 0.4854(18) 0.6750(4) 0.027(2) Uani 0.4432(13) 1 d D U P A 2
 H2C H 0.148(4) 0.698(9) 0.737(3) 0.048(17) Uiso 0.4432(13) 1 d . . P A 2
 H2D H 0.306(5) 0.799(12) 0.767(4) 0.09(3) Uiso 0.4432(13) 1 d . . P A 2


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 Si03 C11 1.873(2) . ?
 Si03 C12 1.876(3) . ?
 Si03 C13 1.867(3) . ?
 Si03 C4 1.900(5) . ?
 Si03 C4A 1.907(6) . ?
 Si04 C14 1.869(3) . ?
 Si04 C15 1.859(3) . ?
 Si04 C16 1.865(3) . ?
 Si04 C4 1.905(8) . ?
 Si04 C4A 1.909(10) . ?
 Si05 C8 1.857(3) . ?
 Si05 C9 1.876(3) . ?
 Si05 C10 1.876(3) . ?
 Si05 C1 1.821(9) . ?
 Si05 C1A 2.014(12) . ?
 Si06 C5 1.871(4) . ?
 Si06 C6 1.867(3) . ?
 Si06 C7 1.864(3) . ?
 Si06 C1 2.017(9) . ?
 Si06 C1A 1.795(12) . ?
 C5 H5A 0.9800 . ?
 C5 H5B 0.9800 . ?
 C5 H5C 0.9800 . ?
 C6 H6A 0.9800 . ?
 C6 H6B 0.9800 . ?
 C6 H6C 0.9800 . ?
 C7 H7A 0.9800 . ?
 C7 H7B 0.9800 . ?
 C7 H7C 0.9800 . ?
 C8 H8A 0.9800 . ?
 C8 H8B 0.9800 . ?
 C8 H8C 0.9800 . ?
 C9 H9A 0.9800 . ?
 C9 H9B 0.9800 . ?
 C9 H9C 0.9800 . ?
 C10 H10A 0.9800 . ?
 C10 H10B 0.9800 . ?
 C10 H10C 0.9800 . ?
 C11 H11A 0.9800 . ?
 C11 H11B 0.9800 . ?
 C11 H11C 0.9800 . ?
 C12 H12A 0.9800 . ?
 C12 H12B 0.9800 . ?
 C12 H12C 0.9800 . ?
 C13 H13A 0.9800 . ?
 C13 H13B 0.9800 . ?
 C13 H13C 0.9800 . ?
 C14 H14A 0.9800 . ?
 C14 H14B 0.9800 . ?
 C14 H14C 0.9800 . ?
 C15 H15A 0.9800 . ?
 C15 H15B 0.9800 . ?
 C15 H15C 0.9800 . ?
 C16 H16A 0.9800 . ?
 C16 H16B 0.9800 . ?
 C16 H16C 0.9800 . ?
 Ge1 C1 1.987(7) . ?
 Ge1 C4 1.999(9) . ?
 Ge1 H1A 1.52(5) . ?
 Ge1 H1B 1.60(4) . ?
 C1 C2 1.566(6) . ?
 C2 H2A 0.9900 . ?
 C2 H2B 0.9900 . ?
 C2 C3 1.557(6) . ?
 C3 H3A 0.9900 . ?
 C3 H3B 0.9900 . ?
 C3 C4 1.550(8) . ?
 Ge2 C1A 1.993(8) . ?
 Ge2 C4A 2.004(10) . ?
 Ge2 H2C 1.50(6) . ?
 Ge2 H2D 1.63(8) . ?
 C1A C2A 1.562(9) . ?
 C2A H2AA 0.9900 . ?
 C2A H2AB 0.9900 . ?
 C2A C3A 1.557(8) . ?
 C3A H3AA 0.9900 . ?
 C3A H3AB 0.9900 . ?
 C3A C4A 1.577(12) . ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 C11 Si03 C12 106.28(13) . . ?
 C11 Si03 C4 115.2(3) . . ?
 C11 Si03 C4A 111.8(3) . . ?
 C12 Si03 C4 106.7(3) . . ?
 C12 Si03 C4A 116.0(4) . . ?
 C13 Si03 C11 103.54(13) . . ?
 C13 Si03 C12 109.03(16) . . ?
 C13 Si03 C4 115.6(3) . . ?
 C13 Si03 C4A 109.4(3) . . ?
 C14 Si04 C4 114.9(3) . . ?
 C14 Si04 C4A 105.7(4) . . ?
 C15 Si04 C14 106.3(2) . . ?
 C15 Si04 C16 104.51(17) . . ?
 C15 Si04 C4 112.8(2) . . ?
 C15 Si04 C4A 115.9(2) . . ?
 C16 Si04 C14 108.10(17) . . ?
 C16 Si04 C4 109.6(3) . . ?
 C16 Si04 C4A 115.8(3) . . ?
 C8 Si05 C9 109.23(15) . . ?
 C8 Si05 C10 104.78(16) . . ?
 C8 Si05 C1A 104.8(2) . . ?
 C9 Si05 C1A 117.0(3) . . ?
 C10 Si05 C9 105.44(17) . . ?
 C10 Si05 C1A 114.9(3) . . ?
 C1 Si05 C8 116.7(2) . . ?
 C1 Si05 C9 107.6(3) . . ?
 C1 Si05 C10 112.5(3) . . ?
 C5 Si06 C1 115.9(3) . . ?
 C6 Si06 C5 107.59(17) . . ?
 C6 Si06 C1 108.5(2) . . ?
 C7 Si06 C5 106.7(2) . . ?
 C7 Si06 C6 103.80(15) . . ?
 C7 Si06 C1 113.5(3) . . ?
 C1A Si06 C5 105.0(3) . . ?
 C1A Si06 C6 118.5(3) . . ?
 C1A Si06 C7 114.6(4) . . ?
 Si06 C5 H5A 109.5 . . ?
 Si06 C5 H5B 109.5 . . ?
 Si06 C5 H5C 109.5 . . ?
 H5A C5 H5B 109.5 . . ?
 H5A C5 H5C 109.5 . . ?
 H5B C5 H5C 109.5 . . ?
 Si06 C6 H6A 109.5 . . ?
 Si06 C6 H6B 109.5 . . ?
 Si06 C6 H6C 109.5 . . ?
 H6A C6 H6B 109.5 . . ?
 H6A C6 H6C 109.5 . . ?
 H6B C6 H6C 109.5 . . ?
 Si06 C7 H7A 109.5 . . ?
 Si06 C7 H7B 109.5 . . ?
 Si06 C7 H7C 109.5 . . ?
 H7A C7 H7B 109.5 . . ?
 H7A C7 H7C 109.5 . . ?
 H7B C7 H7C 109.5 . . ?
 Si05 C8 H8A 109.5 . . ?
 Si05 C8 H8B 109.5 . . ?
 Si05 C8 H8C 109.5 . . ?
 H8A C8 H8B 109.5 . . ?
 H8A C8 H8C 109.5 . . ?
 H8B C8 H8C 109.5 . . ?
 Si05 C9 H9A 109.5 . . ?
 Si05 C9 H9B 109.5 . . ?
 Si05 C9 H9C 109.5 . . ?
 H9A C9 H9B 109.5 . . ?
 H9A C9 H9C 109.5 . . ?
 H9B C9 H9C 109.5 . . ?
 Si05 C10 H10A 109.5 . . ?
 Si05 C10 H10B 109.5 . . ?
 Si05 C10 H10C 109.5 . . ?
 H10A C10 H10B 109.5 . . ?
 H10A C10 H10C 109.5 . . ?
 H10B C10 H10C 109.5 . . ?
 Si03 C11 H11A 109.5 . . ?
 Si03 C11 H11B 109.5 . . ?
 Si03 C11 H11C 109.5 . . ?
 H11A C11 H11B 109.5 . . ?
 H11A C11 H11C 109.5 . . ?
 H11B C11 H11C 109.5 . . ?
 Si03 C12 H12A 109.5 . . ?
 Si03 C12 H12B 109.5 . . ?
 Si03 C12 H12C 109.5 . . ?
 H12A C12 H12B 109.5 . . ?
 H12A C12 H12C 109.5 . . ?
 H12B C12 H12C 109.5 . . ?
 Si03 C13 H13A 109.5 . . ?
 Si03 C13 H13B 109.5 . . ?
 Si03 C13 H13C 109.5 . . ?
 H13A C13 H13B 109.5 . . ?
 H13A C13 H13C 109.5 . . ?
 H13B C13 H13C 109.5 . . ?
 Si04 C14 H14A 109.5 . . ?
 Si04 C14 H14B 109.5 . . ?
 Si04 C14 H14C 109.5 . . ?
 H14A C14 H14B 109.5 . . ?
 H14A C14 H14C 109.5 . . ?
 H14B C14 H14C 109.5 . . ?
 Si04 C15 H15A 109.5 . . ?
 Si04 C15 H15B 109.5 . . ?
 Si04 C15 H15C 109.5 . . ?
 H15A C15 H15B 109.5 . . ?
 H15A C15 H15C 109.5 . . ?
 H15B C15 H15C 109.5 . . ?
 Si04 C16 H16A 109.5 . . ?
 Si04 C16 H16B 109.5 . . ?
 Si04 C16 H16C 109.5 . . ?
 H16A C16 H16B 109.5 . . ?
 H16A C16 H16C 109.5 . . ?
 H16B C16 H16C 109.5 . . ?
 C1 Ge1 C4 96.7(3) . . ?
 C1 Ge1 H1A 108.8(18) . . ?
 C1 Ge1 H1B 112.8(16) . . ?
 C4 Ge1 H1A 119.3(19) . . ?
 C4 Ge1 H1B 111.2(16) . . ?
 H1A Ge1 H1B 108(2) . . ?
 Si05 C1 Si06 109.3(3) . . ?
 Si05 C1 Ge1 110.0(5) . . ?
 Ge1 C1 Si06 112.1(3) . . ?
 C2 C1 Si05 110.4(4) . . ?
 C2 C1 Si06 113.8(6) . . ?
 C2 C1 Ge1 100.9(4) . . ?
 C1 C2 H2A 109.4 . . ?
 C1 C2 H2B 109.4 . . ?
 H2A C2 H2B 108.0 . . ?
 C3 C2 C1 111.3(4) . . ?
 C3 C2 H2A 109.4 . . ?
 C3 C2 H2B 109.4 . . ?
 C2 C3 H3A 109.2 . . ?
 C2 C3 H3B 109.2 . . ?
 H3A C3 H3B 107.9 . . ?
 C4 C3 C2 112.2(4) . . ?
 C4 C3 H3A 109.2 . . ?
 C4 C3 H3B 109.2 . . ?
 Si03 C4 Si04 110.5(3) . . ?
 Si03 C4 Ge1 108.8(4) . . ?
 Si04 C4 Ge1 113.8(4) . . ?
 C3 C4 Si03 106.6(5) . . ?
 C3 C4 Si04 116.2(5) . . ?
 C3 C4 Ge1 100.3(4) . . ?
 C1A Ge2 C4A 97.0(4) . . ?
 C1A Ge2 H2C 115(3) . . ?
 C1A Ge2 H2D 113(3) . . ?
 C4A Ge2 H2C 112(2) . . ?
 C4A Ge2 H2D 105(3) . . ?
 H2C Ge2 H2D 113(4) . . ?
 Si06 C1A Si05 110.5(4) . . ?
 Si06 C1A Ge2 111.0(7) . . ?
 Ge2 C1A Si05 109.3(4) . . ?
 C2A C1A Si05 113.9(8) . . ?
 C2A C1A Si06 110.9(5) . . ?
 C2A C1A Ge2 100.8(4) . . ?
 C1A C2A H2AA 109.0 . . ?
 C1A C2A H2AB 109.0 . . ?
 H2AA C2A H2AB 107.8 . . ?
 C3A C2A C1A 112.7(5) . . ?
 C3A C2A H2AA 109.0 . . ?
 C3A C2A H2AB 109.0 . . ?
 C2A C3A H3AA 109.4 . . ?
 C2A C3A H3AB 109.4 . . ?
 C2A C3A C4A 111.1(5) . . ?
 H3AA C3A H3AB 108.0 . . ?
 C4A C3A H3AA 109.4 . . ?
 C4A C3A H3AB 109.4 . . ?
 Si03 C4A Si04 110.0(4) . . ?
 Si03 C4A Ge2 115.6(5) . . ?
 Si04 C4A Ge2 109.5(5) . . ?
 C3A C4A Si03 114.3(6) . . ?
 C3A C4A Si04 106.7(6) . . ?
 C3A C4A Ge2 100.0(4) . . ?

loop_
  _geom_torsion_atom_site_label_1
  _geom_torsion_atom_site_label_2
  _geom_torsion_atom_site_label_3
  _geom_torsion_atom_site_label_4
  _geom_torsion
  _geom_torsion_site_symmetry_1
  _geom_torsion_site_symmetry_2
  _geom_torsion_site_symmetry_3
  _geom_torsion_site_symmetry_4
  _geom_torsion_publ_flag
 Si05 C1 C2 C3 -150.3(4) . . . . ?
 Si05 C1A C2A C3A 84.3(5) . . . . ?
 Si06 C1 C2 C3 86.3(5) . . . . ?
 Si06 C1A C2A C3A -150.3(5) . . . . ?
 C5 Si06 C1A Si05 91.9(4) . . . . ?
 C5 Si06 C1A Ge2 -146.6(3) . . . . ?
 C5 Si06 C1A C2A -35.4(7) . . . . ?
 C6 Si06 C1A Si05 -28.2(6) . . . . ?
 C6 Si06 C1A Ge2 93.2(4) . . . . ?
 C6 Si06 C1A C2A -155.6(5) . . . . ?
 C7 Si06 C1A Si05 -151.4(3) . . . . ?
 C7 Si06 C1A Ge2 -29.9(5) . . . . ?
 C7 Si06 C1A C2A 81.3(7) . . . . ?
 C8 Si05 C1 Si06 -40.9(4) . . . . ?
 C8 Si05 C1 Ge1 82.7(3) . . . . ?
 C8 Si05 C1 C2 -166.8(4) . . . . ?
 C9 Si05 C1 Si06 82.2(3) . . . . ?
 C9 Si05 C1 Ge1 -154.2(2) . . . . ?
 C9 Si05 C1 C2 -43.7(5) . . . . ?
 C10 Si05 C1 Si06 -162.0(3) . . . . ?
 C10 Si05 C1 Ge1 -38.5(3) . . . . ?
 C10 Si05 C1 C2 72.0(5) . . . . ?
 C11 Si03 C4 Si04 -155.8(3) . . . . ?
 C11 Si03 C4 Ge1 -30.2(5) . . . . ?
 C11 Si03 C4 C3 77.2(5) . . . . ?
 C12 Si03 C4 Si04 86.5(4) . . . . ?
 C12 Si03 C4 Ge1 -147.9(3) . . . . ?
 C12 Si03 C4 C3 -40.5(5) . . . . ?
 C13 Si03 C4 Si04 -34.9(5) . . . . ?
 C13 Si03 C4 Ge1 90.7(4) . . . . ?
 C13 Si03 C4 C3 -162.0(4) . . . . ?
 Ge1 C1 C2 C3 -34.0(6) . . . . ?
 C1 C2 C3 C4 50.3(7) . . . . ?
 C2 C3 C4 Si03 -149.1(4) . . . . ?
 C2 C3 C4 Si04 87.4(5) . . . . ?
 C2 C3 C4 Ge1 -35.7(5) . . . . ?
 Ge2 C1A C2A C3A -32.6(8) . . . . ?
 C1A C2A C3A C4A 50.1(8) . . . . ?
 C2A C3A C4A Si03 87.5(6) . . . . ?
 C2A C3A C4A Si04 -150.7(4) . . . . ?
 C2A C3A C4A Ge2 -36.7(6) . . . . ?

_olex2_submission_special_instructions  'No special instructions were received'
