data_250925a_0m_a
_audit_creation_date               2025-10-18
_audit_creation_method
;
Olex2 1.5
(compiled 2022.04.07 svn.rca3783a0 for OlexSys, GUI svn.r6498)
;
_shelx_SHELXL_version_number       '2025/1'
_audit_contact_author_address      ?
_audit_contact_author_email        ?
_audit_contact_author_name         ''
_audit_contact_author_phone        ?
_publ_contact_author_id_orcid      ?
_publ_section_references
;
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.

Sheldrick, G.M. (2015). Acta Cryst. A71, 3-8.

Sheldrick, G.M. (2015). Acta Cryst. C71, 3-8.
;
_chemical_name_common              ?
_chemical_name_systematic          ?
_chemical_formula_moiety           'C32 H82 Ge2 K2 Si8'
_chemical_formula_sum              'C32 H82 Ge2 K2 Si8'
_chemical_formula_weight           915.07
_chemical_melting_point            ?
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Ge' 'Ge' 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'K' 'K' 0.2009 0.2494 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Si' 'Si' 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system        'triclinic'
_space_group_IT_number             2
_space_group_name_H-M_alt          'P -1'
_space_group_name_Hall             '-P 1'
loop_
  _space_group_symop_operation_xyz
 'x, y, z'
 '-x, -y, -z'

_cell_length_a                     12.0180(3)
_cell_length_b                     14.4718(4)
_cell_length_c                     16.6526(4)
_cell_angle_alpha                  113.7670(10)
_cell_angle_beta                   104.8720(10)
_cell_angle_gamma                  90.0800(10)
_cell_volume                       2543.78(11)
_cell_formula_units_Z              2
_cell_measurement_reflns_used      9853
_cell_measurement_temperature      173(2)
_cell_measurement_theta_max        30.17
_cell_measurement_theta_min        2.48
_shelx_estimated_absorpt_T_max     0.860
_shelx_estimated_absorpt_T_min     0.746
_exptl_absorpt_coefficient_mu      1.554
_exptl_absorpt_correction_T_max    0.7466
_exptl_absorpt_correction_T_min    0.6438
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1260 before and 0.0744 after correction.
The Ratio of minimum to maximum transmission is 0.8623.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details     ?
_exptl_crystal_colour              orange
_exptl_crystal_colour_primary      orange
_exptl_crystal_density_diffrn      1.195
_exptl_crystal_density_meas        ?
_exptl_crystal_density_method      'not measured'
_exptl_crystal_description         plate
_exptl_crystal_F_000               976
_exptl_crystal_mounting_method
;
 Crystals were removed from the crystallisation vial and immediately coated
 with PDMS (polydimethylsiloxane/Dimethicone, CAS: 9006-65-9 on a glass slide.
 A suitable single crystal was selected and mounted on a glass fiber using
 vacuum silicone grease as adhesive. The glass fiber with single crystal was
 mounted on copper pin with solid paraffin. Operator: DJ_Tokyo.
;
_exptl_crystal_size_max            0.2
_exptl_crystal_size_mid            0.1
_exptl_crystal_size_min            0.1
_exptl_transmission_factor_max     ?
_exptl_transmission_factor_min     ?
_diffrn_reflns_av_R_equivalents    0.0594
_diffrn_reflns_av_unetI/netI       0.0506
_diffrn_reflns_Laue_measured_fraction_full  0.998
_diffrn_reflns_Laue_measured_fraction_max  0.999
_diffrn_reflns_limit_h_max         15
_diffrn_reflns_limit_h_min         -12
_diffrn_reflns_limit_k_max         18
_diffrn_reflns_limit_k_min         -18
_diffrn_reflns_limit_l_max         21
_diffrn_reflns_limit_l_min         -21
_diffrn_reflns_number              50147
_diffrn_reflns_point_group_measured_fraction_full  0.998
_diffrn_reflns_point_group_measured_fraction_max  0.999
_diffrn_reflns_theta_full          25.242
_diffrn_reflns_theta_max           26.732
_diffrn_reflns_theta_min           2.206
_diffrn_ambient_temperature        173(2)
_diffrn_detector                   'Bruker PHOTON-II area detector'
_diffrn_detector_area_resol_mean   7.4
_diffrn_detector_type              'CMOS-PHOTONII area detector'
_diffrn_measured_fraction_theta_full  0.998
_diffrn_measured_fraction_theta_max  0.999
_diffrn_measurement_device         'three-circle diffractometer'
_diffrn_measurement_device_type    'Bruker PHOTON-II area detector'
_diffrn_measurement_method         'phi and omega scans'
_diffrn_radiation_monochromator    graphite
_diffrn_radiation_probe            X-ray
_diffrn_radiation_type             MoK\a
_diffrn_radiation_wavelength       0.71073
_diffrn_source                     'sealed X-ray tube'
_diffrn_source_target              Mo
_diffrn_standards_number           0
_reflns_Friedel_coverage           0.000
_reflns_Friedel_fraction_full      .
_reflns_Friedel_fraction_max       .
_reflns_number_gt                  8733
_reflns_number_total               10789
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression       'I > 2σ(I)'
_computing_cell_refinement         'SAINT V8.40B (Bruker, 2016)'
_computing_data_collection         'Bruker D8 Venture diffractometer'
_computing_data_reduction          'SAINT V8.40B (Bruker, 2016)'
_computing_molecular_graphics      'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement    'SHELXL 2025/1 (Sheldrick, 2015)'
_computing_structure_solution      'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max           0.441
_refine_diff_density_min           -0.550
_refine_diff_density_rms           0.108
_refine_ls_extinction_coef         .
_refine_ls_extinction_method       none
_refine_ls_goodness_of_fit_ref     1.121
_refine_ls_hydrogen_treatment      mixed
_refine_ls_matrix_type             full
_refine_ls_number_parameters       429
_refine_ls_number_reflns           10789
_refine_ls_number_restraints       0
_refine_ls_R_factor_all            0.0508
_refine_ls_R_factor_gt             0.0391
_refine_ls_restrained_S_all        1.121
_refine_ls_shift/su_max            0.001
_refine_ls_shift/su_mean           0.000
_refine_ls_structure_factor_coef   Fsqd
_refine_ls_weighting_details      
 'w=1/[σ²(Fo²)+(0.0493P)²] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme        calc
_refine_ls_wR_factor_gt            0.0969
_refine_ls_wR_factor_ref           0.1005
_refine_special_details            ?
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H,H) groups
 At 1.5 times of:
  All C(H) groups, All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C5(H5A,H5B), C6(H6A,H6B), C18(H18A,H18B), C19(H19A,H19B)
2.b Idealised Me refined as rotating group:
 C2(H2A,H2B,H2C), C3(H3A,H3B,H3C), C4(H4A,H4B,H4C), C8(H8A,H8B,H8C), C9(H9A,
 H9B,H9C), C10(H10A,H10B,H10C), C11(H11A,H11B,H11C), C12(H12A,H12B,H12C),
 C13(H13A,H13B,H13C), C14(H14A,H14B,H14C), C15(H15A,H15B,H15C), C16(H16A,H16B,
 H16C), C21(H21A,H21B,H21C), C22(H22A,H22B,H22C), C23(H23A,H23B,H23C), C24(H24A,
 H24B,H24C), C25(H25A,H25B,H25C), C26(H26A,H26B,H26C), C27(H27A,H27B,H27C),
 C28(H28A,H28B,H28C), C29(H29A,H29B,H29C), C30(H30A,H30B,H30C), C31(H31A,H31B,
 H31C), C32(H32A,H32B,H32C)
;
_atom_sites_solution_hydrogens     mixed
_atom_sites_solution_primary       dual
_atom_sites_solution_secondary     difmap
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_site_symmetry_order
  _atom_site_calc_flag
  _atom_site_refinement_flags_posn
  _atom_site_refinement_flags_adp
  _atom_site_refinement_flags_occupancy
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 Ge1 Ge 0.53020(2) 0.69456(2) 0.02414(2) 0.02291(8) Uani 1 1 d . . . . .
 Ge2 Ge 1.00047(2) 0.80162(2) 0.46861(2) 0.02617(8) Uani 1 1 d . . . . .
 K1 K 0.60529(6) 0.54160(4) 0.13342(4) 0.04224(16) Uani 1 1 d . . . . .
 K2 K 0.85669(6) 0.96382(5) 0.38706(4) 0.04795(18) Uani 1 1 d . . . . .
 Si1 Si 0.77286(6) 0.80974(5) 0.04004(5) 0.02721(15) Uani 1 1 d . . . . .
 Si2 Si 0.44237(6) 0.84606(5) 0.19637(5) 0.03088(16) Uani 1 1 d . . . . .
 Si3 Si 0.26446(6) 0.73144(6) 0.00502(5) 0.03461(18) Uani 1 1 d . . . . .
 Si4 Si 0.57323(6) 0.75411(6) -0.13679(5) 0.03125(16) Uani 1 1 d . . . . .
 Si5 Si 0.97496(6) 0.80205(6) 0.65658(5) 0.03260(17) Uani 1 1 d . . . . .
 Si6 Si 0.76239(6) 0.71465(6) 0.48516(5) 0.03109(16) Uani 1 1 d . . . . .
 Si7 Si 1.23399(6) 0.68448(6) 0.45708(5) 0.03661(18) Uani 1 1 d . . . . .
 Si8 Si 1.04061(6) 0.64618(5) 0.27899(5) 0.03068(16) Uani 1 1 d . . . . .
 C1 C 0.61145(19) 0.79564(17) -0.00881(15) 0.0226(5) Uani 1 1 d . . . . .
 C2 C 0.8211(2) 0.8511(2) 0.16740(17) 0.0368(6) Uani 1 1 d . . . . .
 H2A H 0.905703 0.854280 0.187886 0.055 Uiso 1 1 calc R U . . .
 H2B H 0.785124 0.802159 0.182929 0.055 Uiso 1 1 calc R U . . .
 H2C H 0.797780 0.918437 0.197744 0.055 Uiso 1 1 calc R U . . .
 C3 C 0.8505(2) 0.9170(2) 0.0310(2) 0.0453(7) Uani 1 1 d . . . . .
 H3A H 0.856368 0.895127 -0.031516 0.068 Uiso 1 1 calc R U . . .
 H3B H 0.928395 0.935575 0.073836 0.068 Uiso 1 1 calc R U . . .
 H3C H 0.806954 0.975944 0.045867 0.068 Uiso 1 1 calc R U . . .
 C4 C 0.8330(2) 0.6872(2) -0.0119(2) 0.0448(7) Uani 1 1 d . . . . .
 H4A H 0.824156 0.670222 -0.076590 0.067 Uiso 1 1 calc R U . . .
 H4B H 0.790910 0.632905 -0.006487 0.067 Uiso 1 1 calc R U . . .
 H4C H 0.915369 0.694316 0.020224 0.067 Uiso 1 1 calc R U . . .
 C5 C 0.56553(19) 0.89788(17) 0.04054(16) 0.0227(5) Uani 1 1 d . . . . .
 H5A H 0.614964 0.931815 0.104450 0.027 Uiso 1 1 calc R U . . .
 H5B H 0.572137 0.942906 0.009890 0.027 Uiso 1 1 calc R U . . .
 C6 C 0.4388(2) 0.88420(17) 0.04098(16) 0.0240(5) Uani 1 1 d . . . . .
 H6A H 0.387128 0.868362 -0.020873 0.029 Uiso 1 1 calc R U . . .
 H6B H 0.420010 0.948791 0.083875 0.029 Uiso 1 1 calc R U . . .
 C7 C 0.4153(2) 0.79717(17) 0.06987(16) 0.0246(5) Uani 1 1 d . . . . .
 C8 C 0.3282(3) 0.9245(2) 0.2383(2) 0.0558(9) Uani 1 1 d . . . . .
 H8A H 0.320563 0.979071 0.217334 0.084 Uiso 1 1 calc R U . . .
 H8B H 0.350445 0.954041 0.305241 0.084 Uiso 1 1 calc R U . . .
 H8C H 0.253978 0.881255 0.214130 0.084 Uiso 1 1 calc R U . . .
 C9 C 0.5809(3) 0.9315(2) 0.26455(18) 0.0487(8) Uani 1 1 d . . . . .
 H9A H 0.590477 0.951344 0.329803 0.058 Uiso 1 1 calc R U . . .
 H9B H 0.578928 0.992385 0.252357 0.058 Uiso 1 1 calc R U . . .
 H9C H 0.645970 0.895601 0.247313 0.073 Uiso 1 1 calc R U . . .
 C10 C 0.4507(3) 0.7426(2) 0.2379(2) 0.0512(8) Uani 1 1 d . . . . .
 H10A H 0.398164 0.682341 0.191482 0.077 Uiso 1 1 calc R U . . .
 H10B H 0.427907 0.766250 0.294786 0.077 Uiso 1 1 calc R U . . .
 H10C H 0.530248 0.725114 0.249179 0.077 Uiso 1 1 calc R U . . .
 C11 C 0.1491(3) 0.8181(3) 0.0200(3) 0.0671(10) Uani 1 1 d . . . . .
 H11A H 0.168453 0.876015 0.007683 0.101 Uiso 1 1 calc R U . . .
 H11B H 0.143675 0.842747 0.082792 0.101 Uiso 1 1 calc R U . . .
 H11C H 0.074532 0.781020 -0.022772 0.101 Uiso 1 1 calc R U . . .
 C12 C 0.2408(3) 0.6740(2) -0.12254(19) 0.0474(8) Uani 1 1 d . . . . .
 H12A H 0.173322 0.622096 -0.152196 0.071 Uiso 1 1 calc R U . . .
 H12B H 0.309639 0.642761 -0.136882 0.071 Uiso 1 1 calc R U . . .
 H12C H 0.227298 0.727305 -0.144884 0.071 Uiso 1 1 calc R U . . .
 C13 C 0.2254(3) 0.6252(2) 0.0339(2) 0.0506(8) Uani 1 1 d . . . . .
 H13A H 0.150887 0.587487 -0.008414 0.076 Uiso 1 1 calc R U . . .
 H13B H 0.219205 0.653424 0.096666 0.076 Uiso 1 1 calc R U . . .
 H13C H 0.285574 0.579263 0.028523 0.076 Uiso 1 1 calc R U . . .
 C14 C 0.5484(3) 0.6123(2) -0.2024(2) 0.0582(9) Uani 1 1 d . . . . .
 H14A H 0.469002 0.587603 -0.209344 0.087 Uiso 1 1 calc R U . . .
 H14B H 0.603395 0.581133 -0.169187 0.087 Uiso 1 1 calc R U . . .
 H14C H 0.559792 0.594098 -0.262888 0.087 Uiso 1 1 calc R U . . .
 C15 C 0.4428(2) 0.8065(2) -0.18382(18) 0.0417(7) Uani 1 1 d . . . . .
 H15A H 0.436116 0.791643 -0.247831 0.063 Uiso 1 1 calc R U . . .
 H15B H 0.450734 0.880212 -0.148227 0.063 Uiso 1 1 calc R U . . .
 H15C H 0.373195 0.774961 -0.180057 0.063 Uiso 1 1 calc R U . . .
 C16 C 0.6858(3) 0.7976(3) -0.1779(2) 0.0616(10) Uani 1 1 d . . . . .
 H16A H 0.657588 0.775517 -0.244226 0.092 Uiso 1 1 calc R U . . .
 H16B H 0.757424 0.768097 -0.163110 0.092 Uiso 1 1 calc R U . . .
 H16C H 0.701321 0.871961 -0.147795 0.092 Uiso 1 1 calc R U . . .
 C17 C 1.0729(2) 0.67162(17) 0.40307(16) 0.0255(5) Uani 1 1 d . . . . .
 C18 C 1.0036(2) 0.58648(17) 0.41163(16) 0.0263(5) Uani 1 1 d . . . . .
 H18A H 0.931079 0.561385 0.360874 0.032 Uiso 1 1 calc R U . . .
 H18B H 1.050122 0.528846 0.405526 0.032 Uiso 1 1 calc R U . . .
 C19 C 0.9734(2) 0.62318(18) 0.50303(16) 0.0285(5) Uani 1 1 d . . . . .
 H19A H 1.043807 0.628833 0.552005 0.034 Uiso 1 1 calc R U . . .
 H19B H 0.915086 0.571926 0.499054 0.034 Uiso 1 1 calc R U . . .
 C20 C 0.9244(2) 0.72839(18) 0.52922(16) 0.0256(5) Uani 1 1 d . . . . .
 C21 C 1.1356(2) 0.8431(2) 0.70228(19) 0.0431(7) Uani 1 1 d . . . . .
 H21A H 1.176485 0.785305 0.704719 0.065 Uiso 1 1 calc R U . . .
 H21B H 1.152986 0.898054 0.763876 0.065 Uiso 1 1 calc R U . . .
 H21C H 1.161170 0.867319 0.662041 0.065 Uiso 1 1 calc R U . . .
 C22 C 0.9039(3) 0.9212(2) 0.6973(2) 0.0591(9) Uani 1 1 d . . . . .
 H22A H 0.916289 0.962787 0.665587 0.089 Uiso 1 1 calc R U . . .
 H22B H 0.937755 0.959718 0.763339 0.089 Uiso 1 1 calc R U . . .
 H22C H 0.820535 0.903324 0.684354 0.089 Uiso 1 1 calc R U . . .
 C23 C 0.9511(3) 0.7249(3) 0.71915(19) 0.0516(8) Uani 1 1 d . . . . .
 H23A H 0.868470 0.700539 0.700775 0.077 Uiso 1 1 calc R U . . .
 H23B H 0.976671 0.767157 0.785138 0.077 Uiso 1 1 calc R U . . .
 H23C H 0.995695 0.666650 0.704286 0.077 Uiso 1 1 calc R U . . .
 C24 C 0.7037(2) 0.6120(2) 0.36683(18) 0.0443(7) Uani 1 1 d . . . . .
 H24A H 0.732818 0.628845 0.323957 0.066 Uiso 1 1 calc R U . . .
 H24B H 0.618831 0.606169 0.349018 0.066 Uiso 1 1 calc R U . . .
 H24C H 0.728863 0.547136 0.365649 0.066 Uiso 1 1 calc R U . . .
 C25 C 0.6843(3) 0.6786(3) 0.5549(2) 0.0540(8) Uani 1 1 d . . . . .
 H25A H 0.600619 0.666972 0.525290 0.081 Uiso 1 1 calc R U . . .
 H25B H 0.700817 0.733787 0.616315 0.081 Uiso 1 1 calc R U . . .
 H25C H 0.710767 0.616385 0.559297 0.081 Uiso 1 1 calc R U . . .
 C26 C 0.7057(3) 0.8344(2) 0.4812(2) 0.0569(9) Uani 1 1 d . . . . .
 H26A H 0.699636 0.833452 0.421074 0.085 Uiso 1 1 calc R U . . .
 H26B H 0.758862 0.893538 0.528674 0.085 Uiso 1 1 calc R U . . .
 H26C H 0.628929 0.838435 0.491826 0.085 Uiso 1 1 calc R U . . .
 C27 C 1.3046(3) 0.8185(3) 0.5063(3) 0.0733(11) Uani 1 1 d . . . . .
 H27A H 1.276613 0.848349 0.462429 0.110 Uiso 1 1 calc R U . . .
 H27B H 1.388903 0.818776 0.518817 0.110 Uiso 1 1 calc R U . . .
 H27C H 1.285271 0.858538 0.563231 0.110 Uiso 1 1 calc R U . . .
 C28 C 1.2718(3) 0.6374(2) 0.5497(2) 0.0525(8) Uani 1 1 d . . . . .
 H28A H 1.235122 0.567529 0.525720 0.079 Uiso 1 1 calc R U . . .
 H28B H 1.243978 0.681175 0.601219 0.079 Uiso 1 1 calc R U . . .
 H28C H 1.356178 0.639049 0.570280 0.079 Uiso 1 1 calc R U . . .
 C29 C 1.3197(3) 0.6079(3) 0.3782(2) 0.0571(9) Uani 1 1 d . . . . .
 H29A H 1.287648 0.536118 0.349674 0.086 Uiso 1 1 calc R U . . .
 H29B H 1.400829 0.615238 0.413211 0.086 Uiso 1 1 calc R U . . .
 H29C H 1.315148 0.632479 0.330705 0.086 Uiso 1 1 calc R U . . .
 C30 C 0.8813(2) 0.6252(2) 0.21866(18) 0.0391(6) Uani 1 1 d . . . . .
 H30A H 0.870320 0.620091 0.156579 0.059 Uiso 1 1 calc R U . . .
 H30B H 0.843721 0.682378 0.252330 0.059 Uiso 1 1 calc R U . . .
 H30C H 0.846677 0.562038 0.215605 0.059 Uiso 1 1 calc R U . . .
 C31 C 1.1074(3) 0.7539(2) 0.2652(2) 0.0474(8) Uani 1 1 d . . . . .
 H31A H 1.084785 0.741326 0.200500 0.071 Uiso 1 1 calc R U . . .
 H31B H 1.192072 0.759327 0.287375 0.071 Uiso 1 1 calc R U . . .
 H31C H 1.080463 0.817456 0.300639 0.071 Uiso 1 1 calc R U . . .
 C32 C 1.0868(3) 0.5242(2) 0.2048(2) 0.0538(8) Uani 1 1 d . . . . .
 H32A H 1.046855 0.506714 0.140447 0.081 Uiso 1 1 calc R U . . .
 H32B H 1.066871 0.469505 0.220938 0.081 Uiso 1 1 calc R U . . .
 H32C H 1.170804 0.532974 0.214467 0.081 Uiso 1 1 calc R U . . .
 H1 H 0.609(3) 0.719(3) 0.118(3) 0.090(12) Uiso 1 1 d . . . . .
 H2 H 0.890(3) 0.785(3) 0.384(2) 0.080(11) Uiso 1 1 d . . . . .


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 Ge1 K1 3.4322(6) 2_665 ?
 Ge1 K1 3.3815(6) . ?
 Ge1 C1 2.077(2) . ?
 Ge1 C7 2.080(2) . ?
 Ge1 H1 1.51(4) . ?
 Ge2 K2 3.3964(7) 2_776 ?
 Ge2 K2 3.4230(6) . ?
 Ge2 C17 2.080(2) . ?
 Ge2 C20 2.076(2) . ?
 Ge2 H2 1.61(3) . ?
 K1 K1 4.1840(12) 2_665 ?
 K1 C24 3.463(3) . ?
 K1 C30 3.266(3) . ?
 K1 H1 2.68(4) . ?
 K2 K2 4.1562(12) 2_776 ?
 K2 C2 3.257(3) . ?
 K2 C9 3.335(3) . ?
 K2 H2 2.60(3) . ?
 Si1 C1 1.877(2) . ?
 Si1 C2 1.881(3) . ?
 Si1 C3 1.886(3) . ?
 Si1 C4 1.872(3) . ?
 Si2 C7 1.868(2) . ?
 Si2 C8 1.874(3) . ?
 Si2 C9 1.866(3) . ?
 Si2 C10 1.880(3) . ?
 Si3 C7 1.876(2) . ?
 Si3 C11 1.868(3) . ?
 Si3 C12 1.884(3) . ?
 Si3 C13 1.878(3) . ?
 Si4 C1 1.892(2) . ?
 Si4 C14 1.875(3) . ?
 Si4 C15 1.870(3) . ?
 Si4 C16 1.875(3) . ?
 Si5 C20 1.876(2) . ?
 Si5 C21 1.881(3) . ?
 Si5 C22 1.877(3) . ?
 Si5 C23 1.872(3) . ?
 Si6 C20 1.876(2) . ?
 Si6 C24 1.874(3) . ?
 Si6 C25 1.883(3) . ?
 Si6 C26 1.882(3) . ?
 Si7 C17 1.887(2) . ?
 Si7 C27 1.874(3) . ?
 Si7 C28 1.880(3) . ?
 Si7 C29 1.881(3) . ?
 Si8 C17 1.879(2) . ?
 Si8 C30 1.880(3) . ?
 Si8 C31 1.873(3) . ?
 Si8 C32 1.883(3) . ?
 C1 C5 1.557(3) . ?
 C2 H2A 0.9800 . ?
 C2 H2B 0.9800 . ?
 C2 H2C 0.9800 . ?
 C3 H3A 0.9800 . ?
 C3 H3B 0.9800 . ?
 C3 H3C 0.9800 . ?
 C4 H4A 0.9800 . ?
 C4 H4B 0.9800 . ?
 C4 H4C 0.9800 . ?
 C5 H5A 0.9900 . ?
 C5 H5B 0.9900 . ?
 C5 C6 1.538(3) . ?
 C6 H6A 0.9900 . ?
 C6 H6B 0.9900 . ?
 C6 C7 1.567(3) . ?
 C8 H8A 0.9800 . ?
 C8 H8B 0.9800 . ?
 C8 H8C 0.9800 . ?
 C9 H9A 0.9800 . ?
 C9 H9B 0.9800 . ?
 C9 H9C 0.9800 . ?
 C10 H10A 0.9800 . ?
 C10 H10B 0.9800 . ?
 C10 H10C 0.9800 . ?
 C11 H11A 0.9800 . ?
 C11 H11B 0.9800 . ?
 C11 H11C 0.9800 . ?
 C12 H12A 0.9800 . ?
 C12 H12B 0.9800 . ?
 C12 H12C 0.9800 . ?
 C13 H13A 0.9800 . ?
 C13 H13B 0.9800 . ?
 C13 H13C 0.9800 . ?
 C14 H14A 0.9800 . ?
 C14 H14B 0.9800 . ?
 C14 H14C 0.9800 . ?
 C15 H15A 0.9800 . ?
 C15 H15B 0.9800 . ?
 C15 H15C 0.9800 . ?
 C16 H16A 0.9800 . ?
 C16 H16B 0.9800 . ?
 C16 H16C 0.9800 . ?
 C17 C18 1.559(3) . ?
 C18 H18A 0.9900 . ?
 C18 H18B 0.9900 . ?
 C18 C19 1.538(3) . ?
 C19 H19A 0.9900 . ?
 C19 H19B 0.9900 . ?
 C19 C20 1.566(3) . ?
 C21 H21A 0.9800 . ?
 C21 H21B 0.9800 . ?
 C21 H21C 0.9800 . ?
 C22 H22A 0.9800 . ?
 C22 H22B 0.9800 . ?
 C22 H22C 0.9800 . ?
 C23 H23A 0.9800 . ?
 C23 H23B 0.9800 . ?
 C23 H23C 0.9800 . ?
 C24 H24A 0.9800 . ?
 C24 H24B 0.9800 . ?
 C24 H24C 0.9800 . ?
 C25 H25A 0.9800 . ?
 C25 H25B 0.9800 . ?
 C25 H25C 0.9800 . ?
 C26 H26A 0.9800 . ?
 C26 H26B 0.9800 . ?
 C26 H26C 0.9800 . ?
 C27 H27A 0.9800 . ?
 C27 H27B 0.9800 . ?
 C27 H27C 0.9800 . ?
 C28 H28A 0.9800 . ?
 C28 H28B 0.9800 . ?
 C28 H28C 0.9800 . ?
 C29 H29A 0.9800 . ?
 C29 H29B 0.9800 . ?
 C29 H29C 0.9800 . ?
 C30 H30A 0.9800 . ?
 C30 H30B 0.9800 . ?
 C30 H30C 0.9800 . ?
 C31 H31A 0.9800 . ?
 C31 H31B 0.9800 . ?
 C31 H31C 0.9800 . ?
 C32 H32A 0.9800 . ?
 C32 H32B 0.9800 . ?
 C32 H32C 0.9800 . ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 K1 Ge1 K1 75.764(16) . 2_665 ?
 K1 Ge1 H1 50.2(14) . . ?
 K1 Ge1 H1 125.9(14) 2_665 . ?
 C1 Ge1 K1 123.39(6) . 2_665 ?
 C1 Ge1 K1 138.33(6) . . ?
 C1 Ge1 C7 91.31(9) . . ?
 C1 Ge1 H1 99.6(14) . . ?
 C7 Ge1 K1 116.11(6) . . ?
 C7 Ge1 K1 113.28(7) . 2_665 ?
 C7 Ge1 H1 95.0(15) . . ?
 K2 Ge2 K2 75.102(17) 2_776 . ?
 K2 Ge2 H2 46.8(12) . . ?
 K2 Ge2 H2 121.9(12) 2_776 . ?
 C17 Ge2 K2 130.49(6) . . ?
 C17 Ge2 K2 127.04(7) . 2_776 ?
 C17 Ge2 H2 96.8(13) . . ?
 C20 Ge2 K2 114.90(7) . 2_776 ?
 C20 Ge2 K2 121.23(7) . . ?
 C20 Ge2 C17 91.16(9) . . ?
 C20 Ge2 H2 97.6(12) . . ?
 Ge1 K1 Ge1 104.236(16) . 2_665 ?
 Ge1 K1 K1 51.570(13) 2_665 2_665 ?
 Ge1 K1 K1 52.666(13) . 2_665 ?
 Ge1 K1 C24 124.58(5) 2_665 . ?
 Ge1 K1 C24 127.68(5) . . ?
 Ge1 K1 H1 129.8(8) 2_665 . ?
 Ge1 K1 H1 25.6(8) . . ?
 K1 K1 H1 78.2(8) 2_665 . ?
 C24 K1 K1 163.65(6) . 2_665 ?
 C24 K1 H1 103.8(8) . . ?
 C30 K1 Ge1 129.82(6) . 2_665 ?
 C30 K1 Ge1 97.34(5) . . ?
 C30 K1 K1 128.94(5) . 2_665 ?
 C30 K1 C24 66.83(7) . . ?
 C30 K1 H1 78.5(8) . . ?
 Ge2 K2 Ge2 104.899(17) 2_776 . ?
 Ge2 K2 K2 52.740(14) 2_776 2_776 ?
 Ge2 K2 K2 52.159(13) . 2_776 ?
 Ge2 K2 H2 26.8(8) . . ?
 Ge2 K2 H2 131.7(8) 2_776 . ?
 K2 K2 H2 78.9(8) 2_776 . ?
 C2 K2 Ge2 126.60(5) . 2_776 ?
 C2 K2 Ge2 103.86(5) . . ?
 C2 K2 K2 133.20(6) . 2_776 ?
 C2 K2 C9 66.87(7) . . ?
 C2 K2 H2 84.8(8) . . ?
 C9 K2 Ge2 127.97(6) . . ?
 C9 K2 Ge2 121.85(6) . 2_776 ?
 C9 K2 K2 159.69(6) . 2_776 ?
 C9 K2 H2 103.2(8) . . ?
 C1 Si1 C2 113.79(11) . . ?
 C1 Si1 C3 112.99(11) . . ?
 C2 Si1 C3 100.19(13) . . ?
 C4 Si1 C1 111.25(12) . . ?
 C4 Si1 C2 106.77(13) . . ?
 C4 Si1 C3 111.24(14) . . ?
 C7 Si2 C8 112.65(13) . . ?
 C7 Si2 C10 113.38(12) . . ?
 C8 Si2 C10 106.93(14) . . ?
 C9 Si2 C7 114.35(12) . . ?
 C9 Si2 C8 104.14(15) . . ?
 C9 Si2 C10 104.55(15) . . ?
 C7 Si3 C12 112.51(12) . . ?
 C7 Si3 C13 113.41(12) . . ?
 C11 Si3 C7 114.02(14) . . ?
 C11 Si3 C12 102.46(16) . . ?
 C11 Si3 C13 107.37(16) . . ?
 C13 Si3 C12 106.21(13) . . ?
 C14 Si4 C1 112.85(12) . . ?
 C15 Si4 C1 114.10(11) . . ?
 C15 Si4 C14 107.41(15) . . ?
 C15 Si4 C16 101.58(14) . . ?
 C16 Si4 C1 114.92(13) . . ?
 C16 Si4 C14 104.93(16) . . ?
 C20 Si5 C21 113.60(12) . . ?
 C20 Si5 C22 112.59(12) . . ?
 C22 Si5 C21 106.00(14) . . ?
 C23 Si5 C20 112.56(13) . . ?
 C23 Si5 C21 102.93(13) . . ?
 C23 Si5 C22 108.49(15) . . ?
 C20 Si6 C25 113.71(12) . . ?
 C20 Si6 C26 113.04(13) . . ?
 C24 Si6 C20 113.38(12) . . ?
 C24 Si6 C25 103.72(14) . . ?
 C24 Si6 C26 106.21(14) . . ?
 C26 Si6 C25 105.96(15) . . ?
 C27 Si7 C17 112.75(13) . . ?
 C27 Si7 C28 107.93(16) . . ?
 C27 Si7 C29 104.64(17) . . ?
 C28 Si7 C17 113.28(13) . . ?
 C28 Si7 C29 101.84(14) . . ?
 C29 Si7 C17 115.42(13) . . ?
 C17 Si8 C30 113.57(12) . . ?
 C17 Si8 C32 115.16(12) . . ?
 C30 Si8 C32 100.09(14) . . ?
 C31 Si8 C17 110.91(13) . . ?
 C31 Si8 C30 107.87(12) . . ?
 C31 Si8 C32 108.54(15) . . ?
 Si1 C1 Ge1 110.69(10) . . ?
 Si1 C1 Si4 110.04(11) . . ?
 Si4 C1 Ge1 111.45(11) . . ?
 C5 C1 Ge1 103.10(13) . . ?
 C5 C1 Si1 108.98(15) . . ?
 C5 C1 Si4 112.39(15) . . ?
 K2 C2 H2A 81.5 . . ?
 K2 C2 H2B 74.4 . . ?
 K2 C2 H2C 56.6 . . ?
 Si1 C2 K2 165.34(13) . . ?
 Si1 C2 H2A 109.5 . . ?
 Si1 C2 H2B 109.5 . . ?
 Si1 C2 H2C 109.5 . . ?
 H2A C2 H2B 109.5 . . ?
 H2A C2 H2C 109.5 . . ?
 H2B C2 H2C 109.5 . . ?
 Si1 C3 H3A 109.5 . . ?
 Si1 C3 H3B 109.5 . . ?
 Si1 C3 H3C 109.5 . . ?
 H3A C3 H3B 109.5 . . ?
 H3A C3 H3C 109.5 . . ?
 H3B C3 H3C 109.5 . . ?
 Si1 C4 H4A 109.5 . . ?
 Si1 C4 H4B 109.5 . . ?
 Si1 C4 H4C 109.5 . . ?
 H4A C4 H4B 109.5 . . ?
 H4A C4 H4C 109.5 . . ?
 H4B C4 H4C 109.5 . . ?
 C1 C5 H5A 109.0 . . ?
 C1 C5 H5B 109.0 . . ?
 H5A C5 H5B 107.8 . . ?
 C6 C5 C1 113.12(18) . . ?
 C6 C5 H5A 109.0 . . ?
 C6 C5 H5B 109.0 . . ?
 C5 C6 H6A 109.2 . . ?
 C5 C6 H6B 109.2 . . ?
 C5 C6 C7 112.20(18) . . ?
 H6A C6 H6B 107.9 . . ?
 C7 C6 H6A 109.2 . . ?
 C7 C6 H6B 109.2 . . ?
 Si2 C7 Ge1 111.31(11) . . ?
 Si2 C7 Si3 112.64(12) . . ?
 Si3 C7 Ge1 107.60(11) . . ?
 C6 C7 Ge1 104.07(14) . . ?
 C6 C7 Si2 111.56(16) . . ?
 C6 C7 Si3 109.24(15) . . ?
 Si2 C8 H8A 109.5 . . ?
 Si2 C8 H8B 109.5 . . ?
 Si2 C8 H8C 109.5 . . ?
 H8A C8 H8B 109.5 . . ?
 H8A C8 H8C 109.5 . . ?
 H8B C8 H8C 109.5 . . ?
 K2 C9 H9A 66.4 . . ?
 K2 C9 H9B 100.3 . . ?
 K2 C9 H9C 50.4 . . ?
 Si2 C9 K2 149.07(15) . . ?
 Si2 C9 H9A 109.5 . . ?
 Si2 C9 H9B 109.5 . . ?
 Si2 C9 H9C 109.5 . . ?
 H9A C9 H9B 109.5 . . ?
 H9A C9 H9C 109.5 . . ?
 H9B C9 H9C 109.5 . . ?
 Si2 C10 H10A 109.5 . . ?
 Si2 C10 H10B 109.5 . . ?
 Si2 C10 H10C 109.5 . . ?
 H10A C10 H10B 109.5 . . ?
 H10A C10 H10C 109.5 . . ?
 H10B C10 H10C 109.5 . . ?
 Si3 C11 H11A 109.5 . . ?
 Si3 C11 H11B 109.5 . . ?
 Si3 C11 H11C 109.5 . . ?
 H11A C11 H11B 109.5 . . ?
 H11A C11 H11C 109.5 . . ?
 H11B C11 H11C 109.5 . . ?
 Si3 C12 H12A 109.5 . . ?
 Si3 C12 H12B 109.5 . . ?
 Si3 C12 H12C 109.5 . . ?
 H12A C12 H12B 109.5 . . ?
 H12A C12 H12C 109.5 . . ?
 H12B C12 H12C 109.5 . . ?
 Si3 C13 H13A 109.5 . . ?
 Si3 C13 H13B 109.5 . . ?
 Si3 C13 H13C 109.5 . . ?
 H13A C13 H13B 109.5 . . ?
 H13A C13 H13C 109.5 . . ?
 H13B C13 H13C 109.5 . . ?
 Si4 C14 H14A 109.5 . . ?
 Si4 C14 H14B 109.5 . . ?
 Si4 C14 H14C 109.5 . . ?
 H14A C14 H14B 109.5 . . ?
 H14A C14 H14C 109.5 . . ?
 H14B C14 H14C 109.5 . . ?
 Si4 C15 H15A 109.5 . . ?
 Si4 C15 H15B 109.5 . . ?
 Si4 C15 H15C 109.5 . . ?
 H15A C15 H15B 109.5 . . ?
 H15A C15 H15C 109.5 . . ?
 H15B C15 H15C 109.5 . . ?
 Si4 C16 H16A 109.5 . . ?
 Si4 C16 H16B 109.5 . . ?
 Si4 C16 H16C 109.5 . . ?
 H16A C16 H16B 109.5 . . ?
 H16A C16 H16C 109.5 . . ?
 H16B C16 H16C 109.5 . . ?
 Si7 C17 Ge2 111.89(12) . . ?
 Si8 C17 Ge2 108.41(11) . . ?
 Si8 C17 Si7 111.03(12) . . ?
 C18 C17 Ge2 103.15(15) . . ?
 C18 C17 Si7 113.04(16) . . ?
 C18 C17 Si8 108.94(16) . . ?
 C17 C18 H18A 109.0 . . ?
 C17 C18 H18B 109.0 . . ?
 H18A C18 H18B 107.8 . . ?
 C19 C18 C17 112.81(19) . . ?
 C19 C18 H18A 109.0 . . ?
 C19 C18 H18B 109.0 . . ?
 C18 C19 H19A 109.0 . . ?
 C18 C19 H19B 109.0 . . ?
 C18 C19 C20 112.74(18) . . ?
 H19A C19 H19B 107.8 . . ?
 C20 C19 H19A 109.0 . . ?
 C20 C19 H19B 109.0 . . ?
 Si5 C20 Ge2 109.03(11) . . ?
 Si6 C20 Ge2 110.23(11) . . ?
 Si6 C20 Si5 111.49(12) . . ?
 C19 C20 Ge2 104.48(15) . . ?
 C19 C20 Si5 108.95(15) . . ?
 C19 C20 Si6 112.39(16) . . ?
 Si5 C21 H21A 109.5 . . ?
 Si5 C21 H21B 109.5 . . ?
 Si5 C21 H21C 109.5 . . ?
 H21A C21 H21B 109.5 . . ?
 H21A C21 H21C 109.5 . . ?
 H21B C21 H21C 109.5 . . ?
 Si5 C22 H22A 109.5 . . ?
 Si5 C22 H22B 109.5 . . ?
 Si5 C22 H22C 109.5 . . ?
 H22A C22 H22B 109.5 . . ?
 H22A C22 H22C 109.5 . . ?
 H22B C22 H22C 109.5 . . ?
 Si5 C23 H23A 109.5 . . ?
 Si5 C23 H23B 109.5 . . ?
 Si5 C23 H23C 109.5 . . ?
 H23A C23 H23B 109.5 . . ?
 H23A C23 H23C 109.5 . . ?
 H23B C23 H23C 109.5 . . ?
 K1 C24 H24A 46.5 . . ?
 K1 C24 H24B 71.4 . . ?
 K1 C24 H24C 98.6 . . ?
 Si6 C24 K1 149.03(14) . . ?
 Si6 C24 H24A 109.5 . . ?
 Si6 C24 H24B 109.5 . . ?
 Si6 C24 H24C 109.5 . . ?
 H24A C24 H24B 109.5 . . ?
 H24A C24 H24C 109.5 . . ?
 H24B C24 H24C 109.5 . . ?
 Si6 C25 H25A 109.5 . . ?
 Si6 C25 H25B 109.5 . . ?
 Si6 C25 H25C 109.5 . . ?
 H25A C25 H25B 109.5 . . ?
 H25A C25 H25C 109.5 . . ?
 H25B C25 H25C 109.5 . . ?
 Si6 C26 H26A 109.5 . . ?
 Si6 C26 H26B 109.5 . . ?
 Si6 C26 H26C 109.5 . . ?
 H26A C26 H26B 109.5 . . ?
 H26A C26 H26C 109.5 . . ?
 H26B C26 H26C 109.5 . . ?
 Si7 C27 H27A 109.5 . . ?
 Si7 C27 H27B 109.5 . . ?
 Si7 C27 H27C 109.5 . . ?
 H27A C27 H27B 109.5 . . ?
 H27A C27 H27C 109.5 . . ?
 H27B C27 H27C 109.5 . . ?
 Si7 C28 H28A 109.5 . . ?
 Si7 C28 H28B 109.5 . . ?
 Si7 C28 H28C 109.5 . . ?
 H28A C28 H28B 109.5 . . ?
 H28A C28 H28C 109.5 . . ?
 H28B C28 H28C 109.5 . . ?
 Si7 C29 H29A 109.5 . . ?
 Si7 C29 H29B 109.5 . . ?
 Si7 C29 H29C 109.5 . . ?
 H29A C29 H29B 109.5 . . ?
 H29A C29 H29C 109.5 . . ?
 H29B C29 H29C 109.5 . . ?
 K1 C30 H30A 80.7 . . ?
 K1 C30 H30B 76.2 . . ?
 K1 C30 H30C 55.6 . . ?
 Si8 C30 K1 164.79(12) . . ?
 Si8 C30 H30A 109.5 . . ?
 Si8 C30 H30B 109.5 . . ?
 Si8 C30 H30C 109.5 . . ?
 H30A C30 H30B 109.5 . . ?
 H30A C30 H30C 109.5 . . ?
 H30B C30 H30C 109.5 . . ?
 Si8 C31 H31A 109.5 . . ?
 Si8 C31 H31B 109.5 . . ?
 Si8 C31 H31C 109.5 . . ?
 H31A C31 H31B 109.5 . . ?
 H31A C31 H31C 109.5 . . ?
 H31B C31 H31C 109.5 . . ?
 Si8 C32 H32A 109.5 . . ?
 Si8 C32 H32B 109.5 . . ?
 Si8 C32 H32C 109.5 . . ?
 H32A C32 H32B 109.5 . . ?
 H32A C32 H32C 109.5 . . ?
 H32B C32 H32C 109.5 . . ?

loop_
  _geom_torsion_atom_site_label_1
  _geom_torsion_atom_site_label_2
  _geom_torsion_atom_site_label_3
  _geom_torsion_atom_site_label_4
  _geom_torsion
  _geom_torsion_site_symmetry_1
  _geom_torsion_site_symmetry_2
  _geom_torsion_site_symmetry_3
  _geom_torsion_site_symmetry_4
  _geom_torsion_publ_flag
 Ge1 C1 C5 C6 -35.6(2) . . . . ?
 Ge2 C17 C18 C19 -36.2(2) . . . . ?
 Si1 C1 C5 C6 -153.22(15) . . . . ?
 Si4 C1 C5 C6 84.53(19) . . . . ?
 Si7 C17 C18 C19 84.8(2) . . . . ?
 Si8 C17 C18 C19 -151.26(17) . . . . ?
 C1 Si1 C2 K2 -45.1(5) . . . . ?
 C1 C5 C6 C7 47.0(3) . . . . ?
 C2 Si1 C1 Ge1 -56.45(15) . . . . ?
 C2 Si1 C1 Si4 179.92(11) . . . . ?
 C2 Si1 C1 C5 56.27(18) . . . . ?
 C3 Si1 C1 Ge1 -169.84(12) . . . . ?
 C3 Si1 C1 Si4 66.53(16) . . . . ?
 C3 Si1 C1 C5 -57.12(18) . . . . ?
 C3 Si1 C2 K2 75.7(5) . . . . ?
 C4 Si1 C1 Ge1 64.20(15) . . . . ?
 C4 Si1 C1 Si4 -59.43(15) . . . . ?
 C4 Si1 C1 C5 176.92(15) . . . . ?
 C4 Si1 C2 K2 -168.3(5) . . . . ?
 C5 C6 C7 Ge1 -30.8(2) . . . . ?
 C5 C6 C7 Si2 89.3(2) . . . . ?
 C5 C6 C7 Si3 -145.47(17) . . . . ?
 C7 Si2 C9 K2 -101.0(2) . . . . ?
 C8 Si2 C7 Ge1 -172.02(13) . . . . ?
 C8 Si2 C7 Si3 -51.06(17) . . . . ?
 C8 Si2 C7 C6 72.2(2) . . . . ?
 C8 Si2 C9 K2 135.6(2) . . . . ?
 C9 Si2 C7 Ge1 69.34(16) . . . . ?
 C9 Si2 C7 Si3 -169.71(14) . . . . ?
 C9 Si2 C7 C6 -46.4(2) . . . . ?
 C10 Si2 C7 Ge1 -50.40(16) . . . . ?
 C10 Si2 C7 Si3 70.55(17) . . . . ?
 C10 Si2 C7 C6 -166.18(17) . . . . ?
 C10 Si2 C9 K2 23.6(3) . . . . ?
 C11 Si3 C7 Ge1 -168.94(14) . . . . ?
 C11 Si3 C7 Si2 68.01(18) . . . . ?
 C11 Si3 C7 C6 -56.5(2) . . . . ?
 C12 Si3 C7 Ge1 -52.82(15) . . . . ?
 C12 Si3 C7 Si2 -175.87(13) . . . . ?
 C12 Si3 C7 C6 59.57(19) . . . . ?
 C13 Si3 C7 Ge1 67.76(16) . . . . ?
 C13 Si3 C7 Si2 -55.29(17) . . . . ?
 C13 Si3 C7 C6 -179.85(17) . . . . ?
 C14 Si4 C1 Ge1 -32.37(17) . . . . ?
 C14 Si4 C1 Si1 90.82(17) . . . . ?
 C14 Si4 C1 C5 -147.53(18) . . . . ?
 C15 Si4 C1 Ge1 90.60(14) . . . . ?
 C15 Si4 C1 Si1 -146.21(13) . . . . ?
 C15 Si4 C1 C5 -24.56(19) . . . . ?
 C16 Si4 C1 Ge1 -152.63(15) . . . . ?
 C16 Si4 C1 Si1 -29.45(18) . . . . ?
 C16 Si4 C1 C5 92.2(2) . . . . ?
 C17 Si8 C30 K1 -56.1(6) . . . . ?
 C17 C18 C19 C20 45.9(3) . . . . ?
 C18 C19 C20 Ge2 -28.7(2) . . . . ?
 C18 C19 C20 Si5 -145.13(18) . . . . ?
 C18 C19 C20 Si6 90.8(2) . . . . ?
 C20 Si6 C24 K1 -96.9(3) . . . . ?
 C21 Si5 C20 Ge2 -45.51(15) . . . . ?
 C21 Si5 C20 Si6 -167.44(12) . . . . ?
 C21 Si5 C20 C19 67.95(19) . . . . ?
 C22 Si5 C20 Ge2 75.00(17) . . . . ?
 C22 Si5 C20 Si6 -46.94(18) . . . . ?
 C22 Si5 C20 C19 -171.54(19) . . . . ?
 C23 Si5 C20 Ge2 -161.99(12) . . . . ?
 C23 Si5 C20 Si6 76.08(16) . . . . ?
 C23 Si5 C20 C19 -48.5(2) . . . . ?
 C24 Si6 C20 Ge2 75.78(15) . . . . ?
 C24 Si6 C20 Si5 -162.98(13) . . . . ?
 C24 Si6 C20 C19 -40.3(2) . . . . ?
 C25 Si6 C20 Ge2 -166.05(14) . . . . ?
 C25 Si6 C20 Si5 -44.81(18) . . . . ?
 C25 Si6 C20 C19 77.8(2) . . . . ?
 C25 Si6 C24 K1 139.3(2) . . . . ?
 C26 Si6 C20 Ge2 -45.17(17) . . . . ?
 C26 Si6 C20 Si5 76.07(16) . . . . ?
 C26 Si6 C20 C19 -161.28(18) . . . . ?
 C26 Si6 C24 K1 27.9(3) . . . . ?
 C27 Si7 C17 Ge2 -31.71(19) . . . . ?
 C27 Si7 C17 Si8 89.57(18) . . . . ?
 C27 Si7 C17 C18 -147.6(2) . . . . ?
 C28 Si7 C17 Ge2 91.25(15) . . . . ?
 C28 Si7 C17 Si8 -147.48(14) . . . . ?
 C28 Si7 C17 C18 -24.7(2) . . . . ?
 C29 Si7 C17 Ge2 -151.89(14) . . . . ?
 C29 Si7 C17 Si8 -30.62(18) . . . . ?
 C29 Si7 C17 C18 92.2(2) . . . . ?
 C30 Si8 C17 Ge2 -59.92(15) . . . . ?
 C30 Si8 C17 Si7 176.78(12) . . . . ?
 C30 Si8 C17 C18 51.65(19) . . . . ?
 C31 Si8 C17 Ge2 61.75(15) . . . . ?
 C31 Si8 C17 Si7 -61.55(16) . . . . ?
 C31 Si8 C17 C18 173.32(16) . . . . ?
 C31 Si8 C30 K1 -179.5(5) . . . . ?
 C32 Si8 C17 Ge2 -174.51(13) . . . . ?
 C32 Si8 C17 Si7 62.20(17) . . . . ?
 C32 Si8 C17 C18 -62.9(2) . . . . ?
 C32 Si8 C30 K1 67.1(5) . . . . ?

_olex2_submission_special_instructions  'No special instructions were received'
