data_6-Eu
_audit_creation_date               2025-06-08
_audit_creation_method
;
Olex2 1.5
(compiled 2025.05.31 svn.r86d253d1 for OlexSys, GUI svn.r7254)
;
_shelx_SHELXL_version_number       '2019/3'
loop_
  _audit_author_name
  _audit_author_email
  _audit_author_address
 'LU, Z.' luzh365@126.com
;
University of Chinese Academy of Sciences
China
;

_audit_contact_author_address      ?
_audit_contact_author_email        ?
_audit_contact_author_name         ''
_audit_contact_author_phone        ?
_publ_contact_author_id_orcid      ?
_publ_section_references
;
D. Kratzert, I. Krossing, (2018), J. Appl. Cryst. 51, 928-934. 

Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.

Kratzert, D., Holstein, J.J. & Krossing, I. (2015). J. Appl. Cryst. 48, 933-938.

Sheldrick, G.M. (2015). Acta Cryst. A71, 3-8.

Sheldrick, G.M. (2015). Acta Cryst. C71, 3-8.
;
_chemical_name_common              ?
_chemical_name_systematic          ?
_chemical_formula_moiety          
 'C30 H37 Eu2 Mo12 N6 O55 P9, 2(H3 O), 9(H2 O), 4(C5 H6 N)'
_chemical_formula_sum              'C50 H85 Eu2 Mo12 N10 O66 P9'
_chemical_formula_weight           3616.21
_chemical_melting_point            ?
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Eu' 'Eu' -0.1578 3.6682
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Mo' 'Mo' -1.6832 0.6857
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N' 'N' 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'O' 'O' 0.0106 0.0060 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'P' 'P' 0.1023 0.0942 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system        'hexagonal'
_space_group_IT_number             176
_space_group_name_H-M_alt          'P 63/m'
_space_group_name_Hall             '-P 6c'
loop_
  _space_group_symop_operation_xyz
 'x, y, z'
 'x-y, x, z+1/2'
 'y, -x+y, z+1/2'
 '-y, x-y, z'
 '-x+y, -x, z'
 '-x, -y, z+1/2'
 '-x, -y, -z'
 '-x+y, -x, -z-1/2'
 '-y, x-y, -z-1/2'
 'y, -x+y, -z'
 'x-y, x, -z'
 'x, y, -z-1/2'

_cell_length_a                     15.8467(5)
_cell_length_b                     15.8467(5)
_cell_length_c                     32.3939(10)
_cell_angle_alpha                  90
_cell_angle_beta                   90
_cell_angle_gamma                  120
_cell_volume                       7044.8(5)
_cell_formula_units_Z              2
_cell_measurement_reflns_used      7338
_cell_measurement_temperature      140.01
_cell_measurement_theta_max        29.32
_cell_measurement_theta_min        2.40
_shelx_estimated_absorpt_T_max     ?
_shelx_estimated_absorpt_T_min     ?
_exptl_absorpt_coefficient_mu      2.085
_exptl_absorpt_correction_T_max    0.0984
_exptl_absorpt_correction_T_min    0.0596
_exptl_absorpt_correction_type     none
_exptl_absorpt_process_details
;
SADABS-2016/2 (Bruker,2016/2) was used for absorption correction.
wR2(int) was 0.1136 before and 0.0647 after correction.
The Ratio of minimum to maximum transmission is 0.6057.
The λ/2 correction factor is Not present.
;
_exptl_absorpt_special_details     ?
_exptl_crystal_colour              'dark red'
_exptl_crystal_colour_modifier     dark
_exptl_crystal_colour_primary      red
_exptl_crystal_density_diffrn      1.705
_exptl_crystal_density_meas        ?
_exptl_crystal_density_method      ?
_exptl_crystal_description         plate
_exptl_crystal_F_000               3496
_exptl_crystal_size_max            0.1
_exptl_crystal_size_mid            0.1
_exptl_crystal_size_min            0.03
_exptl_transmission_factor_max     ?
_exptl_transmission_factor_min     ?
_diffrn_reflns_av_R_equivalents    0.1031
_diffrn_reflns_av_unetI/netI       0.0779
_diffrn_reflns_Laue_measured_fraction_full  0.996
_diffrn_reflns_Laue_measured_fraction_max  0.997
_diffrn_reflns_limit_h_max         22
_diffrn_reflns_limit_h_min         -19
_diffrn_reflns_limit_k_max         16
_diffrn_reflns_limit_k_min         -22
_diffrn_reflns_limit_l_max         44
_diffrn_reflns_limit_l_min         -45
_diffrn_reflns_number              41329
_diffrn_reflns_point_group_measured_fraction_full  0.996
_diffrn_reflns_point_group_measured_fraction_max  0.997
_diffrn_reflns_theta_full          25.242
_diffrn_reflns_theta_max           29.693
_diffrn_reflns_theta_min           2.400
_diffrn_ambient_temperature        140.01
_diffrn_detector_area_resol_mean   ?
_diffrn_measured_fraction_theta_full  0.996
_diffrn_measured_fraction_theta_max  0.997
_diffrn_measurement_device_type    'Bruker APEX-II CCD'
_diffrn_measurement_method         'φ and ω scans'
_diffrn_radiation_type             MoK\a
_diffrn_radiation_wavelength       0.71073
_diffrn_source                     ?
_diffrn_source_current             1.4
_diffrn_source_power               0.07
_diffrn_source_voltage             50.0
_diffrn_standards_number           0
_reflns_Friedel_coverage           0.000
_reflns_Friedel_fraction_full      .
_reflns_Friedel_fraction_max       .
_reflns_number_gt                  3915
_reflns_number_total               6766
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression       'I > 2σ(I)'
_computing_cell_refinement         'SAINT V8.38A (Bruker, 2018)'
_computing_data_collection         ?
_computing_data_reduction          'SAINT V8.38A (Bruker, 2018)'
_computing_molecular_graphics      'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement    'SHELXL 2019/3 (Sheldrick, 2015)'
_computing_structure_solution      'SHELXT 2014/5 (Sheldrick, 2014)'
_refine_diff_density_max           2.681
_refine_diff_density_min           -1.863
_refine_diff_density_rms           0.247
_refine_ls_extinction_coef         .
_refine_ls_extinction_method       none
_refine_ls_goodness_of_fit_ref     1.051
_refine_ls_hydrogen_treatment      constr
_refine_ls_matrix_type             full
_refine_ls_number_parameters       522
_refine_ls_number_reflns           6766
_refine_ls_number_restraints       786
_refine_ls_R_factor_all            0.1415
_refine_ls_R_factor_gt             0.0825
_refine_ls_restrained_S_all        1.000
_refine_ls_shift/su_max            0.002
_refine_ls_shift/su_mean           0.000
_refine_ls_structure_factor_coef   Fsqd
_refine_ls_weighting_details      
 'w=1/[σ²(Fo²)+(0.1015P)²+125.8137P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme        calc
_refine_ls_wR_factor_gt            0.2228
_refine_ls_wR_factor_ref           0.2578
_refine_special_details            ?
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All N(H) groups, All P(H) groups
 At 1.5 times of:
  All O(H,H) groups, All O(H,H,H) groups
2. Restrained distances
 N2-C6 = N2-C10
 1.33 with sigma of 0.02
 N6-C26 = N6-C30
 1.33 with sigma of 0.02
 N1-C5 = N1-C1
 1.33 with sigma of 0.02
 N4-C16 = N4-C20
 1.33 with sigma of 0.02
 N5-C25 = N5-C21
 1.33 with sigma of 0.02
 C5-C4 = C2-C1
 1.38 with sigma of 0.02
 C4-C3 = C3-C2
 1.37 with sigma of 0.02
 C26-C27 = C29-C30
 1.38 with sigma of 0.02
 Mo2-N2
 2.2 with sigma of 0.01
 N3-C15 = N3-C11
 1.33 with sigma of 0.02
 C27-C28 = C28-C29
 1.37 with sigma of 0.02
 N2-O5
 3 with sigma of 0.01
 N2-O4_$1
 3 with sigma of 0.01
 C16-C17 = C19-C20
 1.38 with sigma of 0.02
 C17-C18 = C18-C19
 1.37 with sigma of 0.02
 C25-C24 = C22-C21
 1.38 with sigma of 0.02
 C24-C23 = C23-C22
 1.37 with sigma of 0.02
 C15-C14 = C12-C11
 1.38 with sigma of 0.02
 C14-C13 = C13-C12
 1.37 with sigma of 0.02
 C6-C7 = C9-C10
 1.38 with sigma of 0.02
 C7-C8 = C8-C9
 1.37 with sigma of 0.02
 Mo2-C8
 4.972 with sigma of 0.01
 C10-Mo2
 3.1 with sigma of 0.01
 O2-Mo1_$1
 1.118 with sigma of 0.01
 Mo2-O2
 1.925 with sigma of 0.01
 Mo2_$1-O2
 1.925 with sigma of 0.01
 O1-Mo2
 1.152 with sigma of 0.01
 O2_$2-Mo1
 1.164 with sigma of 0.01
 N1-C4
 2.4 with sigma of 0.04
 N1-C2
 2.39 with sigma of 0.04
 N6-C27
 2.4 with sigma of 0.04
 N2-C7
 2.4 with sigma of 0.04
 N2-C9
 2.39 with sigma of 0.04
 N6-C29
 2.39 with sigma of 0.04
 C5-C3
 2.36 with sigma of 0.04
 N4-C17
 2.4 with sigma of 0.04
 C4-C2
 2.35 with sigma of 0.04
 C3-C1
 2.37 with sigma of 0.04
 C26-C28
 2.36 with sigma of 0.04
 N4-C19
 2.39 with sigma of 0.04
 C27-C29
 2.35 with sigma of 0.04
 C28-C30
 2.37 with sigma of 0.04
 N5-C24
 2.4 with sigma of 0.04
 C16-C18
 2.36 with sigma of 0.04
 N5-C22
 2.39 with sigma of 0.04
 N3-C14
 2.4 with sigma of 0.04
 C17-C19
 2.35 with sigma of 0.04
 C18-C20
 2.37 with sigma of 0.04
 C25-C23
 2.36 with sigma of 0.04
 C15-C13
 2.36 with sigma of 0.04
 C24-C22
 2.35 with sigma of 0.04
 C23-C21
 2.37 with sigma of 0.04
 N3-C12
 2.39 with sigma of 0.04
 C14-C12
 2.35 with sigma of 0.04
 C13-C11
 2.37 with sigma of 0.04
 C6-C8
 2.36 with sigma of 0.04
 C7-C9
 2.35 with sigma of 0.04
 C8-C10
 2.37 with sigma of 0.04
 N2-C9 \\sim N2-C7
 with sigma of 0.04
 N1-C2 \\sim N1-C4
 with sigma of 0.04
 C3-C1 \\sim C3-C5 \\sim C2-C4 \\sim C1-C5
 with sigma of 0.04
 N6-C29 \\sim N6-C27
 with sigma of 0.04
 C28-C30 \\sim C28-C26 \\sim C29-C27 \\sim C30-C26
 with sigma of 0.04
 N4-C19 \\sim N4-C17
 with sigma of 0.04
 C18-C20 \\sim C18-C16 \\sim C19-C17 \\sim C20-C16
 with sigma of 0.04
 N5-C22 \\sim N5-C24
 with sigma of 0.04
 C23-C21 \\sim C23-C25 \\sim C22-C24 \\sim C21-C25
 with sigma of 0.04
 C13-C11 \\sim C13-C15 \\sim C12-C14 \\sim C11-C15
 with sigma of 0.04
 N3-C12 \\sim N3-C14
 with sigma of 0.04
 C8-C10 \\sim C8-C6 \\sim C9-C7 \\sim C10-C6
 with sigma of 0.04
3. Restrained planarity
 Mo2, N2, C6, C7, C8, C9, C10
 with sigma of 0.01
 N2, C6, C7, C8, C9, C10
 with sigma of 0.1
 N1, C1, C2, C3, C4, C5
 with sigma of 0.1
 N6, C26, C27, C28, C29, C30
 with sigma of 0.03
 N4, C16, C17, C18, C19, C20
 with sigma of 0.1
 N5, C21, C22, C23, C24, C25
 with sigma of 0.1
 N3, C11, C12, C13, C14, C15
 with sigma of 0.03
4. Uiso/Uaniso restraints and constraints
P1 \\sim O10: within 2A with sigma of 0.01 and sigma for terminal atoms of 0.02
within 2A
N1 \\sim N2 \\sim C1 \\sim C2 \\sim C3 \\sim C4 \\sim C5 \\sim C6 \\sim C7
\\sim C8 \\sim C9 \\sim C10: within 2A with sigma of 0.01 and sigma for
terminal atoms of 0.02 within 2A
N2 \\sim C6 \\sim C7 \\sim C8 \\sim C9 \\sim C10: within 2A with sigma of 0.04
and sigma for terminal atoms of 0.08 within 2A
Mo2 \\sim N2: within 2A with sigma of 0.01 and sigma for terminal atoms of 0.02
within 2A
N1 \\sim C1 \\sim C2 \\sim C3 \\sim C4 \\sim C5: within 2A with sigma of 0.04
and sigma for terminal atoms of 0.08 within 2A
N6 \\sim C26 \\sim C27 \\sim C28 \\sim C29 \\sim C30: within 2A with sigma of
0.04 and sigma for terminal atoms of 0.08 within 2A
N4 \\sim C16 \\sim C17 \\sim C18 \\sim C19 \\sim C20: within 2A with sigma of
0.04 and sigma for terminal atoms of 0.08 within 2A
N5 \\sim C21 \\sim C22 \\sim C23 \\sim C24 \\sim C25: within 2A with sigma of
0.04 and sigma for terminal atoms of 0.08 within 2A
N3 \\sim C11 \\sim C12 \\sim C13 \\sim C14 \\sim C15: within 2A with sigma of
0.01 and sigma for terminal atoms of 0.02 within 2A
O1 \\sim O2: within 2A with sigma of 0.01 and sigma for terminal atoms of 0.02
within 2A
Uanis(O10) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(C6) \\sim Ueq, Uanis(C7) \\sim Ueq, Uanis(C8) \\sim Ueq, Uanis(C9) \\sim
Ueq, Uanis(C10) \\sim Ueq, Uanis(N2) \\sim Ueq: with sigma of 0.001 and sigma
for terminal atoms of 0.002
Uanis(N6) \\sim Ueq, Uanis(C30) \\sim Ueq, Uanis(C29) \\sim Ueq, Uanis(C28)
\\sim Ueq, Uanis(C27) \\sim Ueq, Uanis(C26) \\sim Ueq: with sigma of 0.02 and
sigma for terminal atoms of 0.04
Uanis(N4) \\sim Ueq, Uanis(C20) \\sim Ueq, Uanis(C19) \\sim Ueq, Uanis(C18)
\\sim Ueq, Uanis(C17) \\sim Ueq, Uanis(C16) \\sim Ueq: with sigma of 0.01 and
sigma for terminal atoms of 0.02
Uanis(N5) \\sim Ueq, Uanis(C25) \\sim Ueq, Uanis(C24) \\sim Ueq, Uanis(C23)
\\sim Ueq, Uanis(C22) \\sim Ueq, Uanis(C21) \\sim Ueq: with sigma of 0.03 and
sigma for terminal atoms of 0.06
Uanis(C15) \\sim Ueq, Uanis(C14) \\sim Ueq, Uanis(C13) \\sim Ueq, Uanis(C12)
\\sim Ueq, Uanis(C11) \\sim Ueq: with sigma of 0.001 and sigma for terminal
atoms of 0.02
Uanis(N3) \\sim Ueq: with sigma of 0.005 and sigma for terminal atoms of 0.01
Uanis(O14) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
Uanis(O2) \\sim Ueq: with sigma of 0.001 and sigma for terminal atoms of 0.002
Uanis(Mo2) \\sim Ueq: with sigma of 0.01 and sigma for terminal atoms of 0.02
5. Rigid body (RIGU) restrains
 N2, C6, C7, C8, C9, C10
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
 N1, C1, C2, C3, C4, C5
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
 N6, C26, C27, C28, C29, C30
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
 N4, C16, C17, C18, C19, C20
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
 N3, C11, C12, C13, C14, C15
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
 N5, C21, C22, C23, C24, C25
 with sigma for 1-2 distances of 0.004 and sigma for 1-3 distances of 0.004
6. Others
 1*[Sof(Mo1)+Sof(O1)+Sof(N1)+Sof(C1)+Sof(H1A)+Sof(C2)+Sof(H2A)+Sof(C3)+
 Sof(H3A)+Sof(C4)+Sof(H4)+Sof(C5)+Sof(H5)]+1*[Sof(Mo2)+Sof(O2)+Sof(N2)+Sof(C6)+
 Sof(H6)+Sof(C7)+Sof(H7)+Sof(C8)+Sof(H8)+Sof(C9)+Sof(H9)+Sof(C10)+Sof(H10)]=1
 with esd of 0.0001
 Sof(Mo1)=Sof(O1)=Sof(N1)=Sof(C1)=Sof(H1A)=Sof(C2)=Sof(H2A)=Sof(C3)=Sof(H3A)=
 Sof(C4)=Sof(H4)=Sof(C5)=Sof(H5)=FVAR(1)
 Sof(Mo2)=Sof(O2)=Sof(N2)=Sof(C6)=Sof(H6)=Sof(C7)=Sof(H7)=Sof(C8)=Sof(H8)=
 Sof(C9)=Sof(H9)=Sof(C10)=Sof(H10)=FVAR(2)
 Fixed Sof: H1(0.666667) P2(0.25) H2(0.25) P3(0.25) H3(0.25) O10(0.333333)
 O13(0.333333) H13A(0.333333) H13B(0.333333) H13C(0.333333) O14(0.083333)
 H14A(0.083333) H14B(0.083333) O15(0.5) H15A(0.5) H15B(0.5) O16(0.5) H16A(0.5)
 H16B(0.5) O17(0.416667) H17A(0.416667) H17B(0.416667) N3(0.333333)
 H3B(0.333333) C11(0.333333) H11(0.333333) C12(0.333333) H12(0.333333)
 C13(0.333333) H13(0.333333) C14(0.333333) H14(0.333333) C15(0.333333)
 H15(0.333333) N4(0.125) H4A(0.125) C16(0.125) H16(0.125) C17(0.125) H17(0.125)
 C18(0.125) H18(0.125) C19(0.125) H19(0.125) C20(0.125) H20(0.125) N5(0.125)
 H5A(0.125) C21(0.125) H21(0.125) C22(0.125) H22(0.125) C23(0.125) H23(0.125)
 C24(0.125) H24(0.125) C25(0.125) H25(0.125) N6(0.083333) H6A(0.083333)
 C26(0.083333) H26(0.083333) C27(0.083333) H27(0.083333) C28(0.083333)
 H28(0.083333) C29(0.083333) H29(0.083333) C30(0.083333) H30(0.083333)
7.a Riding coordinates:
 P1(H1), P2(H2), P3(H3), O13(H13A,H13B,H13C), O14(H14A,H14B), O15(H15A,H15B),
 O16(H16A,H16B), O17(H17A,H17B)
7.b Aromatic/amide H refined with riding coordinates:
 C1(H1A), C2(H2A), C3(H3A), C4(H4), C5(H5), C6(H6), C7(H7), C8(H8), C9(H9),
 C10(H10), N3(H3B), C11(H11), C12(H12), C13(H13), C14(H14), C15(H15), N4(H4A),
 C16(H16), C17(H17), C18(H18), C19(H19), C20(H20), N5(H5A), C21(H21), C22(H22),
 C23(H23), C24(H24), C25(H25), N6(H6A), C26(H26), C27(H27), C28(H28), C29(H29),
 C30(H30)
;
_atom_sites_solution_hydrogens     mixed
_atom_sites_solution_primary       dual
_atom_sites_solution_secondary     ?
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_site_symmetry_order
  _atom_site_calc_flag
  _atom_site_refinement_flags_posn
  _atom_site_refinement_flags_adp
  _atom_site_refinement_flags_occupancy
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 Eu1 Eu 0.333333 0.666667 0.69249(3) 0.0378(3) Uani 1 3 d S T P A .
 Mo1 Mo 0.41846(7) 0.65430(7) 0.56789(2) 0.0326(3) Uani 0.983(2) 1 d . . P A 1
 Mo2 Mo 0.336(3) 0.577(3) 0.5680(13) 0.033(13) Uani 0.017(2) 1 d D U P A 2
 Mo3 Mo 0.44554(8) 0.50474(8) 0.64907(3) 0.0388(3) Uani 1 1 d . . . . .
 P1 P 0.5450(2) 0.7539(2) 0.65061(8) 0.0394(7) Uani 1 1 d . U . . .
 H1 H 0.640510 0.807048 0.664569 0.047 Uiso 0.6667 1 d R U P B .
 P2 P 0.3873(8) 0.5006(7) 0.750000 0.0320(17) Uani 0.5 2 d S T P A 2
 H2 H 0.291971 0.423275 0.750000 0.038 Uiso 0.5 2 d R U P A 2
 P3 P 0.4525(8) 0.5558(8) 0.750000 0.0366(19) Uani 0.5 2 d S T P A 1
 H3 H 0.545830 0.636551 0.750000 0.044 Uiso 0.5 2 d R U P A 1
 O1 O 0.3198(6) 0.5571(6) 0.5328(2) 0.0342(16) Uani 0.983(2) 1 d . U P A 1
 O2 O 0.232(14) 0.562(14) 0.532(6) 0.034(6) Uani 0.017(2) 1 d D U P A 2
 O3 O 0.333333 0.666667 0.6139(4) 0.030(3) Uani 1 3 d S T P . .
 O4 O 0.5463(6) 0.7502(6) 0.6034(2) 0.0390(18) Uani 1 1 d . . . . .
 O5 O 0.4294(6) 0.5504(6) 0.6003(2) 0.0372(17) Uani 1 1 d D . . . .
 O6 O 0.4887(7) 0.8021(6) 0.6676(2) 0.0424(19) Uani 1 1 d . . . . .
 O7 O 0.4939(8) 0.6556(7) 0.6713(2) 0.054(2) Uani 1 1 d . . . . .
 O8 O 0.3736(8) 0.3813(7) 0.6422(3) 0.058(3) Uani 1 1 d . . . . .
 O9 O 0.5621(8) 0.5266(10) 0.6457(3) 0.067(3) Uani 1 1 d . . . . .
 O10 O 0.647(3) 0.803(3) 0.6607(11) 0.087(9) Uani 0.3333 1 d . U P B 2
 O11 O 0.4427(7) 0.4935(7) 0.7128(2) 0.043(2) Uani 1 1 d . . . . .
 O12 O 0.3814(8) 0.5980(9) 0.750000 0.037(2) Uani 1 2 d S T P . .
 N1 N 0.5174(7) 0.6417(7) 0.5239(3) 0.0381(18) Uani 0.983(2) 1 d D U P A 1
 N2 N 0.3072(10) 0.458(3) 0.5251(5) 0.092(10) Uani 0.017(2) 1 d D U P A 2
 C1 C 0.5112(8) 0.6591(8) 0.4835(3) 0.042(2) Uani 0.983(2) 1 d D U P A 1
 H1A H 0.466720 0.679422 0.475007 0.051 Uiso 0.983(2) 1 calc R U P A 1
 C2 C 0.5683(9) 0.6481(9) 0.4543(3) 0.045(2) Uani 0.983(2) 1 d D U P A 1
 H2A H 0.563141 0.660889 0.426040 0.054 Uiso 0.983(2) 1 calc R U P A 1
 C3 C 0.6327(9) 0.6185(10) 0.4662(3) 0.047(2) Uani 0.983(2) 1 d D U P A 1
 H3A H 0.671124 0.609145 0.446251 0.057 Uiso 0.983(2) 1 calc R U P A 1
 C4 C 0.6409(9) 0.6027(9) 0.5070(3) 0.044(2) Uani 0.983(2) 1 d D U P A 1
 H4 H 0.686575 0.584420 0.516044 0.053 Uiso 0.983(2) 1 calc R U P A 1
 C5 C 0.5811(8) 0.6139(9) 0.5349(3) 0.043(2) Uani 0.983(2) 1 d D U P A 1
 H5 H 0.585579 0.601279 0.563197 0.051 Uiso 0.983(2) 1 calc R U P A 1
 C6 C 0.338(4) 0.475(5) 0.4856(9) 0.092(10) Uani 0.017(2) 1 d D U P A 2
 H6 H 0.373926 0.540259 0.476076 0.111 Uiso 0.017(2) 1 calc R U P A 2
 C7 C 0.321(5) 0.400(6) 0.4587(15) 0.092(10) Uani 0.017(2) 1 d D U P A 2
 H7 H 0.343433 0.414155 0.431076 0.111 Uiso 0.017(2) 1 calc R U P A 2
 C8 C 0.270(4) 0.306(5) 0.472(2) 0.092(10) Uani 0.017(2) 1 d D U P A 2
 H8 H 0.256587 0.253659 0.454189 0.111 Uiso 0.017(2) 1 calc R U P A 2
 C9 C 0.238(6) 0.288(4) 0.512(2) 0.092(10) Uani 0.017(2) 1 d D U P A 2
 H9 H 0.201995 0.222879 0.522132 0.111 Uiso 0.017(2) 1 calc R U P A 2
 C10 C 0.257(5) 0.365(3) 0.5381(15) 0.092(10) Uani 0.017(2) 1 d D U P A 2
 H10 H 0.234524 0.351777 0.565857 0.111 Uiso 0.017(2) 1 calc R U P A 2
 O13 O 0.195(2) 0.195(2) 0.6244(9) 0.053(7) Uani 0.3333 1 d . . P . .
 H13A H 0.215274 0.221225 0.649230 0.080 Uiso 0.3333 1 d R U P . .
 H13B H 0.234866 0.252870 0.614739 0.080 Uiso 0.3333 1 d R U P . .
 H13C H 0.242559 0.184223 0.626983 0.080 Uiso 0.3333 1 d R U P . .
 O14 O 0.727(7) 0.688(7) 0.704(3) 0.033(19) Uani 0.0833 1 d . U P . .
 H14A H 0.775242 0.681191 0.694947 0.050 Uiso 0.0833 1 d R U P . .
 H14B H 0.675220 0.637040 0.694947 0.050 Uiso 0.0833 1 d R U P . .
 O15 O 0.0949(12) 0.2030(13) 0.4977(5) 0.045(4) Uani 0.5 1 d . . P . .
 H15A H 0.127293 0.171995 0.496550 0.067 Uiso 0.5 1 d R U P . .
 H15B H 0.114460 0.225048 0.472566 0.067 Uiso 0.5 1 d R U P . .
 O16 O 0.7390(9) 0.8345(10) 0.5759(4) 0.029(3) Uani 0.5 1 d . . P . .
 H16A H 0.749043 0.861342 0.551608 0.043 Uiso 0.5 1 d R U P . .
 H16B H 0.742754 0.881222 0.590570 0.043 Uiso 0.5 1 d R U P . .
 O17 O 0.8281(13) 0.7206(13) 0.5800(6) 0.035(4) Uani 0.4167 1 d . . P . .
 H17A H 0.800746 0.756439 0.578650 0.053 Uiso 0.4167 1 d R U P . .
 H17B H 0.781447 0.663657 0.587760 0.053 Uiso 0.4167 1 d R U P . .
 N3 N 0.4821(18) 0.1933(18) 0.6048(8) 0.046(5) Uani 0.3333 1 d D U P C -1
 H3B H 0.430832 0.135424 0.600706 0.055 Uiso 0.3333 1 calc R U P C -1
 C11 C 0.561(2) 0.228(2) 0.5806(9) 0.063(5) Uani 0.3333 1 d D U P C -1
 H11 H 0.559963 0.187470 0.558739 0.075 Uiso 0.3333 1 calc R U P C -1
 C12 C 0.646(2) 0.320(3) 0.5851(8) 0.060(5) Uani 0.3333 1 d D U P C -1
 H12 H 0.700509 0.341225 0.567194 0.072 Uiso 0.3333 1 calc R U P C -1
 C13 C 0.644(2) 0.375(2) 0.6170(10) 0.070(5) Uani 0.3333 1 d D U P C -1
 H13 H 0.699352 0.438057 0.621525 0.084 Uiso 0.3333 1 calc R U P C -1
 C14 C 0.565(2) 0.343(2) 0.6427(10) 0.071(5) Uani 0.3333 1 d D U P C -1
 H14 H 0.565656 0.382592 0.664814 0.086 Uiso 0.3333 1 calc R U P C -1
 C15 C 0.485(2) 0.252(2) 0.6357(9) 0.068(5) Uani 0.3333 1 d D U P C -1
 H15 H 0.430451 0.229410 0.653399 0.082 Uiso 0.3333 1 calc R U P C -1
 N4 N 0.099(6) 0.260(7) 0.743(4) 0.10(2) Uani 0.125 1 d D U P D -1
 H4A H 0.046147 0.266182 0.743868 0.120 Uiso 0.125 1 calc R U P D -1
 C16 C 0.114(7) 0.218(7) 0.710(3) 0.10(2) Uani 0.125 1 d D U P D -1
 H16 H 0.068010 0.194270 0.688024 0.119 Uiso 0.125 1 calc R U P D -1
 C17 C 0.196(8) 0.208(8) 0.707(3) 0.10(2) Uani 0.125 1 d D U P D -1
 H17 H 0.205258 0.176606 0.684382 0.117 Uiso 0.125 1 calc R U P D -1
 C18 C 0.262(6) 0.244(8) 0.739(3) 0.10(2) Uani 0.125 1 d D U P D -1
 H18 H 0.319923 0.240675 0.736636 0.118 Uiso 0.125 1 calc R U P D -1
 C19 C 0.245(7) 0.284(9) 0.773(3) 0.10(2) Uani 0.125 1 d D U P D -1
 H19 H 0.288696 0.303977 0.795354 0.119 Uiso 0.125 1 calc R U P D -1
 C20 C 0.164(8) 0.294(8) 0.774(3) 0.10(2) Uani 0.125 1 d D U P D -1
 H20 H 0.153771 0.325818 0.796340 0.122 Uiso 0.125 1 calc R U P D -1
 N5 N 0.519(7) 0.333(6) 0.722(3) 0.09(2) Uani 0.125 1 d D U P E -1
 H5A H 0.533510 0.382615 0.706037 0.102 Uiso 0.125 1 calc R U P E -1
 C21 C 0.530(7) 0.259(7) 0.709(3) 0.09(2) Uani 0.125 1 d D U P E -1
 H21 H 0.551616 0.260293 0.681028 0.103 Uiso 0.125 1 calc R U P E -1
 C22 C 0.510(8) 0.181(6) 0.734(4) 0.09(2) Uani 0.125 1 d D U P E -1
 H22 H 0.519740 0.129874 0.724258 0.110 Uiso 0.125 1 calc R U P E -1
 C23 C 0.477(8) 0.179(6) 0.773(3) 0.09(2) Uani 0.125 1 d D U P E -1
 H23 H 0.456851 0.123294 0.789705 0.113 Uiso 0.125 1 calc R U P E -1
 C24 C 0.471(9) 0.257(8) 0.788(3) 0.09(2) Uani 0.125 1 d D U P E -1
 H24 H 0.457420 0.260173 0.815884 0.112 Uiso 0.125 1 calc R U P E -1
 C25 C 0.487(8) 0.331(6) 0.761(3) 0.09(2) Uani 0.125 1 d D U P E -1
 H25 H 0.474618 0.380630 0.769379 0.109 Uiso 0.125 1 calc R U P E -1
 N6 N -0.032(6) -0.015(7) 0.670(3) 0.07(2) Uani 0.0833 1 d D U P F -1
 H6A H -0.080154 -0.058388 0.685462 0.079 Uiso 0.0833 1 calc R U P F -1
 C26 C -0.005(7) 0.080(8) 0.673(3) 0.06(2) Uani 0.0833 1 d D U P F -1
 H26 H -0.039385 0.098896 0.691905 0.078 Uiso 0.0833 1 calc R U P F -1
 C27 C 0.071(8) 0.150(6) 0.650(4) 0.07(2) Uani 0.0833 1 d D U P F -1
 H27 H 0.088428 0.216928 0.652807 0.081 Uiso 0.0833 1 calc R U P F -1
 C28 C 0.119(7) 0.122(7) 0.624(3) 0.07(2) Uani 0.0833 1 d D U P F -1
 H28 H 0.171896 0.169796 0.608111 0.079 Uiso 0.0833 1 calc R U P F -1
 C29 C 0.093(8) 0.026(8) 0.621(4) 0.07(2) Uani 0.0833 1 d D U P F -1
 H29 H 0.126123 0.006638 0.602423 0.081 Uiso 0.0833 1 calc R U P F -1
 C30 C 0.016(8) -0.042(6) 0.644(4) 0.06(2) Uani 0.0833 1 d D U P F -1
 H30 H -0.002103 -0.108749 0.642356 0.077 Uiso 0.0833 1 calc R U P F -1


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 Eu1 P1 3.219(3) . ?
 Eu1 P1 3.219(3) 4_665 ?
 Eu1 O3 2.545(12) . ?
 Eu1 O6 2.457(9) 5_565 ?
 Eu1 O6 2.457(9) 4_665 ?
 Eu1 O6 2.457(9) . ?
 Eu1 O7 2.724(11) . ?
 Eu1 O7 2.724(11) 5_565 ?
 Eu1 O7 2.724(11) 4_665 ?
 Eu1 O12 2.462(8) . ?
 Eu1 O12 2.462(8) 9_667 ?
 Eu1 O12 2.462(8) 8_567 ?
 Mo1 Mo1 2.5234(17) 5_565 ?
 Mo1 Mo1 2.5234(17) 4_665 ?
 Mo1 O1 1.931(8) 4_665 ?
 Mo1 O1 1.924(8) . ?
 Mo1 O3 2.084(8) . ?
 Mo1 O4 2.159(8) . ?
 Mo1 O5 2.032(8) . ?
 Mo1 N1 2.199(9) . ?
 Mo2 Mo2 2.49(8) 5_565 ?
 Mo2 Mo2 2.49(8) 4_665 ?
 Mo2 O2 1.925(10) . ?
 Mo2 O2 1.926(11) 4_665 ?
 Mo2 O3 2.07(3) . ?
 Mo2 O4 2.33(4) 5_565 ?
 Mo2 O5 2.03(5) . ?
 Mo2 N2 2.203(10) . ?
 Mo3 O5 1.807(7) . ?
 Mo3 O6 2.229(8) 5_565 ?
 Mo3 O7 2.234(9) . ?
 Mo3 O8 1.716(10) . ?
 Mo3 O9 1.703(10) . ?
 Mo3 O11 2.072(7) . ?
 P1 H1 1.3898 . ?
 P1 O4 1.530(7) . ?
 P1 O6 1.538(9) . ?
 P1 O7 1.507(10) . ?
 P1 O10 1.44(4) . ?
 P2 H2 1.3902 . ?
 P2 O11 1.527(9) . ?
 P2 O11 1.527(9) 12_557 ?
 P2 O12 1.594(14) . ?
 P3 H3 1.3901 . ?
 P3 O11 1.515(10) 12_557 ?
 P3 O11 1.515(10) . ?
 P3 O12 1.574(14) . ?
 O10 H1 0.1935 . ?
 N1 C1 1.353(11) . ?
 N1 C5 1.335(12) . ?
 N2 C6 1.349(18) . ?
 N2 C10 1.346(18) . ?
 C1 H1A 0.9500 . ?
 C1 C2 1.378(12) . ?
 C2 H2A 0.9500 . ?
 C2 C3 1.375(13) . ?
 C3 H3A 0.9500 . ?
 C3 C4 1.362(13) . ?
 C4 H4 0.9500 . ?
 C4 C5 1.384(12) . ?
 C5 H5 0.9500 . ?
 C6 H6 0.9500 . ?
 C6 C7 1.380(18) . ?
 C7 H7 0.9500 . ?
 C7 C8 1.368(19) . ?
 C8 H8 0.9500 . ?
 C8 C9 1.367(19) . ?
 C9 H9 0.9500 . ?
 C9 C10 1.382(18) . ?
 C10 H10 0.9500 . ?
 O13 H13A 0.8875 . ?
 O13 H13B 0.8671 . ?
 O13 H13C 0.8659 . ?
 O14 H14A 0.8700 . ?
 O14 H14B 0.8700 . ?
 O15 H15A 0.8700 . ?
 O15 H15B 0.8794 . ?
 O16 H16A 0.8700 . ?
 O16 H16B 0.8562 . ?
 O17 H17A 0.8700 . ?
 O17 H17B 0.8700 . ?
 N3 H3B 0.8800 . ?
 N3 C11 1.341(18) . ?
 N3 C15 1.347(18) . ?
 C11 H11 0.9500 . ?
 C11 C12 1.409(18) . ?
 C12 H12 0.9500 . ?
 C12 C13 1.370(18) . ?
 C13 H13 0.9500 . ?
 C13 C14 1.369(18) . ?
 C14 H14 0.9500 . ?
 C14 C15 1.387(18) . ?
 C15 H15 0.9500 . ?
 N4 H4A 0.8800 . ?
 N4 C16 1.344(19) . ?
 N4 C20 1.341(19) . ?
 C16 H16 0.9500 . ?
 C16 C17 1.380(19) . ?
 C17 H17 0.9500 . ?
 C17 C18 1.357(19) . ?
 C18 H18 0.9500 . ?
 C18 C19 1.361(19) . ?
 C19 H19 0.9500 . ?
 C19 C20 1.380(19) . ?
 C20 H20 0.9500 . ?
 N5 H5A 0.8800 . ?
 N5 C21 1.338(19) . ?
 N5 C25 1.338(19) . ?
 C21 H21 0.9500 . ?
 C21 C22 1.380(19) . ?
 C22 H22 0.9500 . ?
 C22 C23 1.365(19) . ?
 C23 H23 0.9500 . ?
 C23 C24 1.362(19) . ?
 C24 H24 0.9500 . ?
 C24 C25 1.380(19) . ?
 C25 H25 0.9500 . ?
 N6 H6A 0.8800 . ?
 N6 C26 1.342(19) . ?
 N6 C30 1.345(19) . ?
 C26 H26 0.9500 . ?
 C26 C27 1.379(19) . ?
 C27 H27 0.9500 . ?
 C27 C28 1.363(19) . ?
 C28 H28 0.9500 . ?
 C28 C29 1.364(19) . ?
 C29 H29 0.9500 . ?
 C29 C30 1.381(19) . ?
 C30 H30 0.9500 . ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 P1 Eu1 P1 103.50(6) 4_665 . ?
 O3 Eu1 P1 65.07(5) . . ?
 O3 Eu1 P1 65.07(5) . 4_665 ?
 O3 Eu1 O7 75.44(16) . . ?
 O3 Eu1 O7 75.44(16) . 5_565 ?
 O3 Eu1 O7 75.44(16) . 4_665 ?
 O6 Eu1 P1 126.59(19) 4_665 . ?
 O6 Eu1 P1 82.9(2) 5_565 . ?
 O6 Eu1 P1 27.5(2) 4_665 4_665 ?
 O6 Eu1 P1 126.59(19) 5_565 4_665 ?
 O6 Eu1 P1 82.9(2) . 4_665 ?
 O6 Eu1 P1 27.5(2) . . ?
 O6 Eu1 O3 70.83(18) 4_665 . ?
 O6 Eu1 O3 70.83(18) . . ?
 O6 Eu1 O3 70.83(18) 5_565 . ?
 O6 Eu1 O6 109.77(18) . 5_565 ?
 O6 Eu1 O6 109.77(18) . 4_665 ?
 O6 Eu1 O6 109.77(18) 4_665 5_565 ?
 O6 Eu1 O7 60.6(3) 4_665 5_565 ?
 O6 Eu1 O7 146.1(2) 5_565 4_665 ?
 O6 Eu1 O7 60.6(3) 5_565 . ?
 O6 Eu1 O7 54.1(3) . . ?
 O6 Eu1 O7 146.1(2) 4_665 . ?
 O6 Eu1 O7 60.6(3) . 4_665 ?
 O6 Eu1 O7 54.1(3) 5_565 5_565 ?
 O6 Eu1 O7 54.1(3) 4_665 4_665 ?
 O6 Eu1 O7 146.1(2) . 5_565 ?
 O6 Eu1 O12 103.8(3) 5_565 8_567 ?
 O6 Eu1 O12 73.7(3) 4_665 8_567 ?
 O6 Eu1 O12 73.7(3) 5_565 . ?
 O6 Eu1 O12 73.7(3) . 9_667 ?
 O6 Eu1 O12 142.0(3) 4_665 . ?
 O6 Eu1 O12 142.0(3) 5_565 9_667 ?
 O6 Eu1 O12 103.8(3) 4_665 9_667 ?
 O6 Eu1 O12 103.8(3) . . ?
 O6 Eu1 O12 142.0(3) . 8_567 ?
 O7 Eu1 P1 27.8(2) . . ?
 O7 Eu1 P1 86.1(2) 5_565 4_665 ?
 O7 Eu1 P1 129.38(19) . 4_665 ?
 O7 Eu1 P1 27.8(2) 4_665 4_665 ?
 O7 Eu1 P1 129.38(19) 5_565 . ?
 O7 Eu1 P1 86.1(2) 4_665 . ?
 O7 Eu1 O7 113.90(13) . 4_665 ?
 O7 Eu1 O7 113.90(13) 5_565 4_665 ?
 O7 Eu1 O7 113.90(13) . 5_565 ?
 O12 Eu1 P1 91.3(3) . . ?
 O12 Eu1 P1 91.3(3) 9_667 . ?
 O12 Eu1 P1 155.7(2) . 4_665 ?
 O12 Eu1 P1 91.3(3) 8_567 4_665 ?
 O12 Eu1 P1 91.3(3) 9_667 4_665 ?
 O12 Eu1 P1 155.7(2) 8_567 . ?
 O12 Eu1 O3 139.2(2) . . ?
 O12 Eu1 O3 139.2(2) 8_567 . ?
 O12 Eu1 O3 139.2(2) 9_667 . ?
 O12 Eu1 O7 69.9(3) . . ?
 O12 Eu1 O7 138.7(3) 9_667 5_565 ?
 O12 Eu1 O7 99.4(3) . 5_565 ?
 O12 Eu1 O7 99.4(3) 8_567 4_665 ?
 O12 Eu1 O7 138.7(3) 8_567 . ?
 O12 Eu1 O7 99.4(3) 9_667 . ?
 O12 Eu1 O7 69.9(3) 9_667 4_665 ?
 O12 Eu1 O7 69.9(3) 8_567 5_565 ?
 O12 Eu1 O7 138.7(3) . 4_665 ?
 O12 Eu1 O12 69.0(3) 9_667 8_567 ?
 O12 Eu1 O12 69.0(3) 9_667 . ?
 O12 Eu1 O12 69.0(3) 8_567 . ?
 Mo1 Mo1 Mo1 60.0 4_665 5_565 ?
 O1 Mo1 Mo1 94.8(2) . 4_665 ?
 O1 Mo1 Mo1 94.6(2) 4_665 5_565 ?
 O1 Mo1 Mo1 49.2(2) . 5_565 ?
 O1 Mo1 Mo1 49.0(2) 4_665 4_665 ?
 O1 Mo1 O1 94.9(5) . 4_665 ?
 O1 Mo1 O3 100.9(3) 4_665 . ?
 O1 Mo1 O3 101.1(3) . . ?
 O1 Mo1 O4 89.3(3) 4_665 . ?
 O1 Mo1 O4 168.4(3) . . ?
 O1 Mo1 O5 164.8(3) 4_665 . ?
 O1 Mo1 O5 91.2(3) . . ?
 O1 Mo1 N1 82.8(3) . . ?
 O1 Mo1 N1 82.2(3) 4_665 . ?
 O3 Mo1 Mo1 52.75(18) . 4_665 ?
 O3 Mo1 Mo1 52.75(18) . 5_565 ?
 O3 Mo1 O4 88.6(3) . . ?
 O3 Mo1 N1 174.7(3) . . ?
 O4 Mo1 Mo1 96.1(2) . 4_665 ?
 O4 Mo1 Mo1 141.2(2) . 5_565 ?
 O4 Mo1 N1 87.1(3) . . ?
 O5 Mo1 Mo1 144.3(2) . 4_665 ?
 O5 Mo1 Mo1 99.9(2) . 5_565 ?
 O5 Mo1 O3 91.6(3) . . ?
 O5 Mo1 O4 82.2(3) . . ?
 O5 Mo1 N1 84.7(3) . . ?
 N1 Mo1 Mo1 131.7(2) . 5_565 ?
 N1 Mo1 Mo1 130.9(2) . 4_665 ?
 O2 Mo2 O3 102(3) . . ?
 O2 Mo2 O3 102(3) 4_665 . ?
 O2 Mo2 O4 173(6) 4_665 5_565 ?
 O2 Mo2 O4 81(9) . 5_565 ?
 O2 Mo2 O5 93(8) 4_665 . ?
 O2 Mo2 O5 163(5) . . ?
 O2 Mo2 N2 91(3) 4_665 . ?
 O2 Mo2 N2 74(2) . . ?
 O3 Mo2 Mo2 53.0(11) . 5_565 ?
 O3 Mo2 Mo2 53.0(12) . 4_665 ?
 O3 Mo2 O4 84.5(14) . 5_565 ?
 O3 Mo2 N2 167(2) . . ?
 O4 Mo2 Mo2 135.7(15) 5_565 4_665 ?
 O4 Mo2 Mo2 86(2) 5_565 5_565 ?
 O5 Mo2 Mo2 145.2(10) . 5_565 ?
 O5 Mo2 Mo2 102(2) . 4_665 ?
 O5 Mo2 O3 92.2(16) . . ?
 O5 Mo2 O4 91(2) . 5_565 ?
 O5 Mo2 N2 90.2(14) . . ?
 N2 Mo2 O4 82.9(10) . 5_565 ?
 O5 Mo3 O6 83.8(3) . 5_565 ?
 O5 Mo3 O7 84.0(3) . . ?
 O5 Mo3 O11 154.7(3) . . ?
 O6 Mo3 O7 72.0(4) 5_565 . ?
 O8 Mo3 O5 101.4(4) . . ?
 O8 Mo3 O6 89.1(5) . 5_565 ?
 O8 Mo3 O7 159.8(5) . . ?
 O8 Mo3 O11 93.3(4) . . ?
 O9 Mo3 O5 102.7(4) . . ?
 O9 Mo3 O6 162.8(5) . 5_565 ?
 O9 Mo3 O7 92.6(5) . . ?
 O9 Mo3 O8 105.0(6) . . ?
 O9 Mo3 O11 93.2(4) . . ?
 O11 Mo3 O6 75.8(3) . 5_565 ?
 O11 Mo3 O7 75.6(3) . . ?
 Eu1 P1 H1 135.1 . . ?
 O4 P1 Eu1 115.9(3) . . ?
 O4 P1 H1 108.4 . . ?
 O4 P1 O6 113.5(5) . . ?
 O6 P1 Eu1 47.5(3) . . ?
 O6 P1 H1 108.0 . . ?
 O7 P1 Eu1 57.5(4) . . ?
 O7 P1 H1 109.9 . . ?
 O7 P1 O4 114.6(5) . . ?
 O7 P1 O6 102.1(5) . . ?
 O10 P1 Eu1 141.7(15) . . ?
 O10 P1 H1 7.6 . . ?
 O10 P1 O4 102.3(15) . . ?
 O10 P1 O6 115.2(18) . . ?
 O10 P1 O7 109.5(17) . . ?
 O11 P2 H2 110.3 12_557 . ?
 O11 P2 H2 110.3 . . ?
 O11 P2 O11 104.1(8) 12_557 . ?
 O11 P2 O12 112.7(6) 12_557 . ?
 O11 P2 O12 112.7(6) . . ?
 O12 P2 H2 106.8 . . ?
 O11 P3 H3 108.4 . . ?
 O11 P3 H3 108.4 12_557 . ?
 O11 P3 O11 105.3(9) 12_557 . ?
 O11 P3 O12 114.5(6) 12_557 . ?
 O11 P3 O12 114.5(6) . . ?
 O12 P3 H3 105.5 . . ?
 Mo1 O1 Mo1 81.8(3) . 5_565 ?
 Mo1 O3 Eu1 135.7(2) 5_565 . ?
 Mo1 O3 Eu1 135.7(2) 4_665 . ?
 Mo1 O3 Eu1 135.7(2) . . ?
 Mo1 O3 Mo1 74.5(4) 5_565 . ?
 Mo1 O3 Mo1 74.5(4) 4_665 . ?
 Mo1 O3 Mo1 74.5(4) 4_665 5_565 ?
 Mo2 O3 Eu1 136.0(15) 4_665 . ?
 Mo2 O3 Eu1 136.0(15) 5_565 . ?
 Mo2 O3 Eu1 136.0(15) . . ?
 Mo2 O3 Mo1 45.9(12) . 5_565 ?
 Mo2 O3 Mo1 88.1(15) 4_665 5_565 ?
 Mo2 O3 Mo1 35.5(11) 5_565 5_565 ?
 Mo2 O3 Mo2 74(2) 5_565 . ?
 Mo2 O3 Mo2 74(2) 4_665 . ?
 Mo1 O4 Mo2 42.1(12) . 4_665 ?
 P1 O4 Mo1 122.2(5) . . ?
 P1 O4 Mo2 117.5(10) . 4_665 ?
 Mo3 O5 Mo1 149.6(4) . . ?
 Mo3 O5 Mo2 143.2(12) . . ?
 Mo3 O6 Eu1 118.8(4) 4_665 . ?
 P1 O6 Eu1 105.1(4) . . ?
 P1 O6 Mo3 129.8(5) . 4_665 ?
 Mo3 O7 Eu1 108.6(4) . . ?
 P1 O7 Eu1 94.7(5) . . ?
 P1 O7 Mo3 133.0(5) . . ?
 P1 O10 H1 72.1 . . ?
 P2 O11 Mo3 140.2(6) . . ?
 P3 O11 Mo3 138.2(6) . . ?
 Eu1 O12 Eu1 98.4(4) 8_567 . ?
 P2 O12 Eu1 127.5(3) . . ?
 P3 O12 Eu1 129.3(3) . 8_567 ?
 P3 O12 Eu1 129.3(3) . . ?
 C1 N1 Mo1 118.8(7) . . ?
 C5 N1 Mo1 123.3(7) . . ?
 C5 N1 C1 117.9(9) . . ?
 C6 N2 Mo2 121.9(19) . . ?
 C10 N2 Mo2 119.9(13) . . ?
 C10 N2 C6 118.2(17) . . ?
 N1 C1 H1A 119.4 . . ?
 N1 C1 C2 121.3(10) . . ?
 C2 C1 H1A 119.4 . . ?
 C1 C2 H2A 120.1 . . ?
 C3 C2 C1 119.8(9) . . ?
 C3 C2 H2A 120.1 . . ?
 C2 C3 H3A 120.3 . . ?
 C4 C3 C2 119.4(10) . . ?
 C4 C3 H3A 120.3 . . ?
 C3 C4 H4 120.9 . . ?
 C3 C4 C5 118.3(10) . . ?
 C5 C4 H4 120.9 . . ?
 N1 C5 C4 123.3(10) . . ?
 N1 C5 H5 118.3 . . ?
 C4 C5 H5 118.3 . . ?
 N2 C6 H6 119.0 . . ?
 N2 C6 C7 122.0(19) . . ?
 C7 C6 H6 119.0 . . ?
 C6 C7 H7 120.3 . . ?
 C8 C7 C6 119.3(17) . . ?
 C8 C7 H7 120.3 . . ?
 C7 C8 H8 120.4 . . ?
 C9 C8 C7 119.1(14) . . ?
 C9 C8 H8 120.4 . . ?
 C8 C9 H9 120.2 . . ?
 C8 C9 C10 119.7(17) . . ?
 C10 C9 H9 120.2 . . ?
 N2 C10 C9 121.7(19) . . ?
 N2 C10 H10 119.2 . . ?
 C9 C10 H10 119.2 . . ?
 H13A O13 H13B 86.3 . . ?
 H13A O13 H13C 81.3 . . ?
 H13B O13 H13C 89.5 . . ?
 H14A O14 H14B 104.5 . . ?
 H15A O15 H15B 89.7 . . ?
 H16A O16 H16B 99.4 . . ?
 H17A O17 H17B 104.5 . . ?
 C11 N3 H3B 121.7 . . ?
 C11 N3 C15 117(2) . . ?
 C15 N3 H3B 121.7 . . ?
 N3 C11 H11 117.4 . . ?
 N3 C11 C12 125.3(19) . . ?
 C12 C11 H11 117.4 . . ?
 C11 C12 H12 122.4 . . ?
 C13 C12 C11 115.2(16) . . ?
 C13 C12 H12 122.4 . . ?
 C12 C13 H13 119.1 . . ?
 C14 C13 C12 121.8(16) . . ?
 C14 C13 H13 119.1 . . ?
 C13 C14 H14 120.7 . . ?
 C13 C14 C15 118.6(16) . . ?
 C15 C14 H14 120.7 . . ?
 N3 C15 C14 123(2) . . ?
 N3 C15 H15 118.7 . . ?
 C14 C15 H15 118.7 . . ?
 C16 N4 H4A 120.3 . . ?
 C20 N4 H4A 120.3 . . ?
 C20 N4 C16 119(3) . . ?
 N4 C16 H16 119.3 . . ?
 N4 C16 C17 121(2) . . ?
 C17 C16 H16 119.3 . . ?
 C16 C17 H17 120.7 . . ?
 C18 C17 C16 118.6(17) . . ?
 C18 C17 H17 120.7 . . ?
 C17 C18 H18 119.7 . . ?
 C17 C18 C19 120.5(18) . . ?
 C19 C18 H18 119.7 . . ?
 C18 C19 H19 120.6 . . ?
 C18 C19 C20 118.9(17) . . ?
 C20 C19 H19 120.6 . . ?
 N4 C20 C19 121(2) . . ?
 N4 C20 H20 119.5 . . ?
 C19 C20 H20 119.5 . . ?
 C21 N5 H5A 119.9 . . ?
 C21 N5 C25 120(3) . . ?
 C25 N5 H5A 119.9 . . ?
 N5 C21 H21 119.6 . . ?
 N5 C21 C22 121(2) . . ?
 C22 C21 H21 119.6 . . ?
 C21 C22 H22 120.5 . . ?
 C23 C22 C21 118.9(17) . . ?
 C23 C22 H22 120.5 . . ?
 C22 C23 H23 119.9 . . ?
 C24 C23 C22 120.2(18) . . ?
 C24 C23 H23 119.9 . . ?
 C23 C24 H24 120.7 . . ?
 C23 C24 C25 118.5(18) . . ?
 C25 C24 H24 120.7 . . ?
 N5 C25 C24 121(2) . . ?
 N5 C25 H25 119.6 . . ?
 C24 C25 H25 119.6 . . ?
 C26 N6 H6A 120.2 . . ?
 C26 N6 C30 120(3) . . ?
 C30 N6 H6A 120.2 . . ?
 N6 C26 H26 119.2 . . ?
 N6 C26 C27 122(2) . . ?
 C27 C26 H26 119.2 . . ?
 C26 C27 H27 120.6 . . ?
 C28 C27 C26 118.8(17) . . ?
 C28 C27 H27 120.6 . . ?
 C27 C28 H28 120.0 . . ?
 C27 C28 C29 120.0(17) . . ?
 C29 C28 H28 120.0 . . ?
 C28 C29 H29 120.2 . . ?
 C28 C29 C30 119.5(17) . . ?
 C30 C29 H29 120.2 . . ?
 N6 C30 C29 121(2) . . ?
 N6 C30 H30 119.7 . . ?
 C29 C30 H30 119.7 . . ?

loop_
  _geom_torsion_atom_site_label_1
  _geom_torsion_atom_site_label_2
  _geom_torsion_atom_site_label_3
  _geom_torsion_atom_site_label_4
  _geom_torsion
  _geom_torsion_site_symmetry_1
  _geom_torsion_site_symmetry_2
  _geom_torsion_site_symmetry_3
  _geom_torsion_site_symmetry_4
  _geom_torsion_publ_flag
 Eu1 P1 O4 Mo1 -19.0(7) . . . . ?
 Eu1 P1 O4 Mo2 29.6(14) . . . 4_665 ?
 Eu1 P1 O6 Mo3 -151.1(8) . . . 4_665 ?
 Eu1 P1 O7 Mo3 120.8(9) . . . . ?
 Mo1 N1 C1 C2 -177.1(8) . . . . ?
 Mo1 N1 C5 C4 177.7(10) . . . . ?
 Mo2 N2 C6 C7 180.0(2) . . . . ?
 Mo2 N2 C10 C9 180.0(3) . . . . ?
 O4 P1 O6 Eu1 104.3(5) . . . . ?
 O4 P1 O6 Mo3 -46.8(8) . . . 4_665 ?
 O4 P1 O7 Eu1 -106.1(4) . . . . ?
 O4 P1 O7 Mo3 14.7(10) . . . . ?
 O6 Mo3 O5 Mo1 57.8(9) 5_565 . . . ?
 O6 Mo3 O5 Mo2 -10.0(16) 5_565 . . . ?
 O6 P1 O4 Mo1 -71.6(7) . . . . ?
 O6 P1 O4 Mo2 -22.9(14) . . . 4_665 ?
 O6 P1 O7 Eu1 17.1(4) . . . . ?
 O6 P1 O7 Mo3 137.9(8) . . . . ?
 O7 Mo3 O5 Mo1 -14.7(9) . . . . ?
 O7 Mo3 O5 Mo2 -82.5(17) . . . . ?
 O7 P1 O4 Mo1 45.2(8) . . . . ?
 O7 P1 O4 Mo2 93.8(14) . . . 4_665 ?
 O7 P1 O6 Eu1 -19.6(5) . . . . ?
 O7 P1 O6 Mo3 -170.7(6) . . . 4_665 ?
 O8 Mo3 O5 Mo1 145.6(10) . . . . ?
 O8 Mo3 O5 Mo2 77.8(17) . . . . ?
 O9 Mo3 O5 Mo1 -106.0(10) . . . . ?
 O9 Mo3 O5 Mo2 -173.8(17) . . . . ?
 O10 P1 O4 Mo2 -148(2) . . . 4_665 ?
 O10 P1 O6 Eu1 -138.2(17) . . . . ?
 O10 P1 O6 Mo3 70.7(18) . . . 4_665 ?
 O10 P1 O7 Eu1 139.6(17) . . . . ?
 O10 P1 O7 Mo3 -99.6(19) . . . . ?
 O11 Mo3 O5 Mo1 21.4(16) . . . . ?
 O11 Mo3 O5 Mo2 -46(2) . . . . ?
 O11 P2 O11 Mo3 -173.6(4) 12_557 . . . ?
 O11 P2 O12 Eu1 48.6(12) . . . . ?
 O11 P2 O12 Eu1 166.1(7) 12_557 . . . ?
 O11 P2 O12 Eu1 -166.1(6) . . . 8_567 ?
 O11 P2 O12 Eu1 -48.6(12) 12_557 . . 8_567 ?
 O11 P3 O11 Mo3 -179.3(3) 12_557 . . . ?
 O11 P3 O12 Eu1 41.0(14) 12_557 . . 8_567 ?
 O11 P3 O12 Eu1 162.9(7) . . . 8_567 ?
 O11 P3 O12 Eu1 -41.0(14) . . . . ?
 O11 P3 O12 Eu1 -162.9(7) 12_557 . . . ?
 O12 P2 O11 Mo3 -51.1(14) . . . . ?
 O12 P3 O11 Mo3 53.9(14) . . . . ?
 N1 C1 C2 C3 0.2(14) . . . . ?
 N2 C6 C7 C8 0.0(4) . . . . ?
 C1 N1 C5 C4 0.3(18) . . . . ?
 C1 C2 C3 C4 -1.6(18) . . . . ?
 C2 C3 C4 C5 2(2) . . . . ?
 C3 C4 C5 N1 -2(2) . . . . ?
 C5 N1 C1 C2 0.5(13) . . . . ?
 C6 N2 C10 C9 0.0(5) . . . . ?
 C6 C7 C8 C9 0.0(6) . . . . ?
 C7 C8 C9 C10 0.0(6) . . . . ?
 C8 C9 C10 N2 0.0(6) . . . . ?
 C10 N2 C6 C7 0.0(3) . . . . ?
 N3 C11 C12 C13 0.0(9) . . . . ?
 C11 N3 C15 C14 0(2) . . . . ?
 C11 C12 C13 C14 0(2) . . . . ?
 C12 C13 C14 C15 0(3) . . . . ?
 C13 C14 C15 N3 0(3) . . . . ?
 C15 N3 C11 C12 -0.1(9) . . . . ?
 N4 C16 C17 C18 -1(3) . . . . ?
 C16 N4 C20 C19 -2(7) . . . . ?
 C16 C17 C18 C19 4(7) . . . . ?
 C17 C18 C19 C20 -5(9) . . . . ?
 C18 C19 C20 N4 4(9) . . . . ?
 C20 N4 C16 C17 0(3) . . . . ?
 N5 C21 C22 C23 2(3) . . . . ?
 C21 N5 C25 C24 5(7) . . . . ?
 C21 C22 C23 C24 -6(7) . . . . ?
 C22 C23 C24 C25 9(9) . . . . ?
 C23 C24 C25 N5 -9(9) . . . . ?
 C25 N5 C21 C22 -1(3) . . . . ?
 N6 C26 C27 C28 -0.1(9) . . . . ?
 C26 N6 C30 C29 0(2) . . . . ?
 C26 C27 C28 C29 0(2) . . . . ?
 C27 C28 C29 C30 0(3) . . . . ?
 C28 C29 C30 N6 0(3) . . . . ?
 C30 N6 C26 C27 0.0(10) . . . . ?

_olex2_submission_special_instructions  'No special instructions were received'
