      Table 1.  Crystal data and structure refinement for t. 
  
  
      Identification code               20250508sl-r-rh_auto 
  
      Empirical formula                 C37 H36 Cl4 N3 O Rh 
  
      Formula weight                    783.40 
  
      Temperature                       109(1) K 
  
      Wavelength                        1.54184 A 
  
      Crystal system, space group       Orthorhombic,  P2(1)2(1)2(1) 
  
      Unit cell dimensions              a = 12.14900(10) A   alpha = 90 deg. 
                                        b = 12.33480(10) A    beta = 90 deg. 
                                        c = 22.9651(2) A   gamma = 90 deg. 
  
      Volume                            3441.45(5) A^3 
  
      Z, Calculated density             4,  1.512 Mg/m^3 
  
      Absorption coefficient            7.140 mm^-1 
  
      F(000)                            1600 
  
      Crystal size                      0.2 x 0.18 x 0.15 mm 
  
      Theta range for data collection   4.068 to 75.633 deg. 
  
      Limiting indices                  -13<=h<=15, -14<=k<=15, -28<=l<=27 
  
      Reflections collected / unique    23221 / 6757 [R(int) = 0.0255] 
  
      Completeness to theta = 67.684    99.8 % 
  
      Absorption correction             Semi-empirical from equivalents 
  
      Max. and min. transmission        1.00000 and 0.26421 
  
      Refinement method                 Full-matrix least-squares on F^2 
  
      Data / restraints / parameters    6757 / 0 / 417 
  
      Goodness-of-fit on F^2            1.021 
  
      Final R indices [I>2sigma(I)]     R1 = 0.0309, wR2 = 0.0764 
  
      R indices (all data)              R1 = 0.0311, wR2 = 0.0766 
  
      Absolute structure parameter      -0.011(4) 
  
      Extinction coefficient            n/a 
  
      Largest diff. peak and hole       1.039 and -1.066 e.A^-3 
  
         Table 2.  Atomic coordinates ( x 10^4) and equivalent isotropic 
         displacement parameters (A^2 x 10^3) for t. 
         U(eq) is defined as one third of the trace of the orthogonalized 
         Uij tensor. 
  
         ________________________________________________________________ 
  
                         x             y             z           U(eq) 
         ________________________________________________________________ 
  
          C(3)         3601(3)       4038(3)       7042(2)       16(1) 
          N(3)         5948(3)       4585(3)       6047(2)       15(1) 
          Cl(3)        6685(3)       8150(2)       5307(1)      106(1) 
          C(27)        9666(3)       5485(4)       8333(2)       18(1) 
          C(8)         2500(4)       4402(4)       6938(2)       23(1) 
          C(33)        8588(4)       2652(4)       7260(2)       23(1) 
          C(1)         5615(3)       4036(3)       6596(2)       14(1) 
          N(1)         7496(3)       3085(3)       7105(1)       15(1) 
          O(1)         5156(3)       5555(3)       5296(1)       24(1) 
          Rh(1)        8261(1)       4984(1)       7783(1)       14(1) 
          Cl(1)        9120(1)       5678(1)       6925(1)       21(1) 
          C(21)        5111(4)       2164(4)       6239(2)       19(1) 
          C(11)        4117(3)       4920(4)       6134(2)       18(1) 
          C(2)         4396(3)       4328(3)       6616(2)       15(1) 
          N(2)         6243(3)       4490(3)       7088(1)       14(1) 
          Cl(2)        4499(3)       8167(2)       5791(1)      146(2) 
          C(4)         3823(4)       3417(4)       7547(2)       22(1) 
          Cl(4)        4850(3)       8787(2)       4580(2)      159(2) 
          C(15)        7222(3)       4098(3)       7276(2)       14(1) 
          C(14)        7586(4)       3641(4)       5624(2)       19(1) 
          C(13)        7091(3)       4686(3)       5850(2)       18(1) 
          C(18)        7027(4)       1293(3)       6713(2)       20(1) 
          C(31)        8945(3)       6348(3)       8273(2)       18(1) 
          C(17)        6784(4)       2393(3)       6794(2)       15(1) 
          C(16)        6982(4)       2916(3)       5288(2)       19(1) 
          C(22)        5817(3)       2823(3)       6556(2)       15(1) 
          C(5)         2992(4)       3150(4)       7920(2)       28(1) 
          C(12)        5096(3)       5077(4)       5768(2)       18(1) 
          C(24)        7994(4)       3910(4)       8486(2)       19(1) 
          C(23)        7463(5)       1955(4)       5088(2)       28(1) 
          C(7)         1665(4)       4106(4)       7337(2)       30(1) 
          C(10)        3029(4)       5288(4)       6038(2)       26(1) 
          C(6)         1900(4)       3489(4)       7816(2)       32(1) 
          C(19)        6331(4)        652(4)       6384(2)       22(1) 
          C(30)        8073(4)       6686(4)       8707(2)       21(1) 
          C(32)        8536(5)       1718(4)       5217(2)       33(1) 
          C(28)        7300(3)       4824(4)       8553(2)       20(1) 
          C(9)         2246(3)       5027(5)       6433(2)       29(1) 
          C(36)        8682(4)       3404(4)       5745(2)       25(1) 
          C(35)        9154(4)       2450(5)       5541(2)       33(1) 
          C(34)        5921(4)       5597(3)       7256(2)       18(1) 
          C(20)        5378(4)       1084(4)       6141(2)       21(1) 
          C(29)        7513(4)       5713(4)       8996(2)       21(1) 
          C(26)        9786(4)       4754(3)       8860(2)       22(1) 
          C(25)        9042(4)       3736(4)       8823(2)       24(1) 
          C(37)        5269(8)       7969(5)       5159(3)       69(3) 
         ________________________________________________________________ 
  
           Table 3.  Bond lengths [A] and angles [deg] for t. 
           _____________________________________________________________ 
  
            C(3)-C(8)                     1.430(6) 
            C(3)-C(2)                     1.421(6) 
            C(3)-C(4)                     1.418(6) 
            N(3)-C(1)                     1.487(5) 
            N(3)-C(13)                    1.466(5) 
            N(3)-C(12)                    1.360(5) 
            Cl(3)-C(37)                   1.768(10) 
            C(27)-H(27)                   1.0000 
            C(27)-Rh(1)                   2.212(4) 
            C(27)-C(31)                   1.385(6) 
            C(27)-C(26)                   1.515(6) 
            C(8)-C(7)                     1.415(7) 
            C(8)-C(9)                     1.425(7) 
            C(33)-H(33A)                  0.9800 
            C(33)-H(33B)                  0.9800 
            C(33)-H(33C)                  0.9800 
            C(33)-N(1)                    1.474(5) 
            C(1)-C(2)                     1.525(6) 
            C(1)-N(2)                     1.474(5) 
            C(1)-C(22)                    1.520(5) 
            N(1)-C(15)                    1.352(5) 
            N(1)-C(17)                    1.409(5) 
            O(1)-C(12)                    1.236(5) 
            Rh(1)-Cl(1)                   2.3891(10) 
            Rh(1)-C(15)                   2.035(4) 
            Rh(1)-C(31)                   2.187(4) 
            Rh(1)-C(24)                   2.113(4) 
            Rh(1)-C(28)                   2.127(4) 
            C(21)-H(21)                   0.9500 
            C(21)-C(22)                   1.387(6) 
            C(21)-C(20)                   1.390(6) 
            C(11)-C(2)                    1.368(6) 
            C(11)-C(12)                   1.469(6) 
            C(11)-C(10)                   1.415(6) 
            N(2)-C(15)                    1.355(5) 
            N(2)-C(34)                    1.472(5) 
            Cl(2)-C(37)                   1.744(6) 
            C(4)-H(4)                     0.9500 
            C(4)-C(5)                     1.364(6) 
            Cl(4)-C(37)                   1.746(9) 
            C(14)-C(13)                   1.513(6) 
            C(14)-C(16)                   1.391(6) 
            C(14)-C(36)                   1.391(6) 
            C(13)-H(13A)                  0.9900 
            C(13)-H(13B)                  0.9900 
            C(18)-H(18)                   0.9500 
            C(18)-C(17)                   1.401(6) 
            C(18)-C(19)                   1.382(6) 
            C(31)-H(31)                   1.0000 
            C(31)-C(30)                   1.513(6) 
            C(17)-C(22)                   1.399(6) 
            C(16)-H(16)                   0.9500 
            C(16)-C(23)                   1.399(6) 
            C(5)-H(5)                     0.9500 
            C(5)-C(6)                     1.411(7) 
            C(24)-H(24)                   1.0000 
            C(24)-C(28)                   1.416(6) 
            C(24)-C(25)                   1.505(6) 
            C(23)-H(23)                   0.9500 
            C(23)-C(32)                   1.368(8) 
            C(7)-H(7)                     0.9500 
            C(7)-C(6)                     1.368(8) 
            C(10)-H(10)                   0.9500 
            C(10)-C(9)                    1.354(7) 
            C(6)-H(6)                     0.9500 
            C(19)-H(19)                   0.9500 
            C(19)-C(20)                   1.392(6) 
            C(30)-H(30A)                  0.9900 
            C(30)-H(30B)                  0.9900 
            C(30)-C(29)                   1.531(6) 
            C(32)-H(32)                   0.9500 
            C(32)-C(35)                   1.390(8) 
            C(28)-H(28)                   1.0000 
            C(28)-C(29)                   1.519(6) 
            C(9)-H(9)                     0.9500 
            C(36)-H(36)                   0.9500 
            C(36)-C(35)                   1.391(7) 
            C(35)-H(35)                   0.9500 
            C(34)-H(34A)                  0.9800 
            C(34)-H(34B)                  0.9800 
            C(34)-H(34C)                  0.9800 
            C(20)-H(20)                   0.9500 
            C(29)-H(29A)                  0.9900 
            C(29)-H(29B)                  0.9900 
            C(26)-H(26A)                  0.9900 
            C(26)-H(26B)                  0.9900 
            C(26)-C(25)                   1.549(6) 
            C(25)-H(25A)                  0.9900 
            C(25)-H(25B)                  0.9900 
            C(37)-H(37)                   1.0000 
  
            C(2)-C(3)-C(8)              116.2(4) 
            C(4)-C(3)-C(8)              119.0(4) 
            C(4)-C(3)-C(2)              124.8(4) 
            C(13)-N(3)-C(1)             123.9(3) 
            C(12)-N(3)-C(1)             113.3(3) 
            C(12)-N(3)-C(13)            122.5(3) 
            Rh(1)-C(27)-H(27)           113.4 
            C(31)-C(27)-H(27)           113.4 
            C(31)-C(27)-Rh(1)            70.7(2) 
            C(31)-C(27)-C(26)           126.7(4) 
            C(26)-C(27)-H(27)           113.4 
            C(26)-C(27)-Rh(1)           111.3(3) 
            C(7)-C(8)-C(3)              118.8(5) 
            C(7)-C(8)-C(9)              120.7(4) 
            C(9)-C(8)-C(3)              120.5(4) 
            H(33A)-C(33)-H(33B)         109.5 
            H(33A)-C(33)-H(33C)         109.5 
            H(33B)-C(33)-H(33C)         109.5 
            N(1)-C(33)-H(33A)           109.5 
            N(1)-C(33)-H(33B)           109.5 
            N(1)-C(33)-H(33C)           109.5 
            N(3)-C(1)-C(2)              100.5(3) 
            N(3)-C(1)-C(22)             110.6(3) 
            N(2)-C(1)-N(3)              109.7(3) 
            N(2)-C(1)-C(2)              113.0(3) 
            N(2)-C(1)-C(22)             109.7(3) 
            C(22)-C(1)-C(2)             113.1(3) 
            C(15)-N(1)-C(33)            119.1(3) 
            C(15)-N(1)-C(17)            123.8(4) 
            C(17)-N(1)-C(33)            117.1(3) 
            C(27)-Rh(1)-Cl(1)            91.97(12) 
            C(15)-Rh(1)-C(27)           162.80(16) 
            C(15)-Rh(1)-Cl(1)            89.49(11) 
            C(15)-Rh(1)-C(31)           160.50(16) 
            C(15)-Rh(1)-C(24)            90.29(17) 
            C(15)-Rh(1)-C(28)            94.87(16) 
            C(31)-Rh(1)-C(27)            36.70(16) 
            C(31)-Rh(1)-Cl(1)            89.05(12) 
            C(24)-Rh(1)-C(27)            81.79(17) 
            C(24)-Rh(1)-Cl(1)           157.17(13) 
            C(24)-Rh(1)-C(31)            98.48(16) 
            C(24)-Rh(1)-C(28)            39.00(17) 
            C(28)-Rh(1)-C(27)            88.57(15) 
            C(28)-Rh(1)-Cl(1)           163.48(13) 
            C(28)-Rh(1)-C(31)            81.53(16) 
            C(22)-C(21)-H(21)           119.9 
            C(22)-C(21)-C(20)           120.1(4) 
            C(20)-C(21)-H(21)           119.9 
            C(2)-C(11)-C(12)            109.4(4) 
            C(2)-C(11)-C(10)            121.9(4) 
            C(10)-C(11)-C(12)           128.6(4) 
            C(3)-C(2)-C(1)              128.4(4) 
            C(11)-C(2)-C(3)             121.5(4) 
            C(11)-C(2)-C(1)             110.0(4) 
            C(15)-N(2)-C(1)             124.3(3) 
            C(15)-N(2)-C(34)            118.7(4) 
            C(34)-N(2)-C(1)             114.6(3) 
            C(3)-C(4)-H(4)              119.9 
            C(5)-C(4)-C(3)              120.3(4) 
            C(5)-C(4)-H(4)              119.9 
            N(1)-C(15)-Rh(1)            120.7(3) 
            N(1)-C(15)-N(2)             116.9(4) 
            N(2)-C(15)-Rh(1)            122.4(3) 
            C(16)-C(14)-C(13)           121.9(4) 
            C(36)-C(14)-C(13)           119.4(4) 
            C(36)-C(14)-C(16)           118.7(4) 
            N(3)-C(13)-C(14)            114.2(3) 
            N(3)-C(13)-H(13A)           108.7 
            N(3)-C(13)-H(13B)           108.7 
            C(14)-C(13)-H(13A)          108.7 
            C(14)-C(13)-H(13B)          108.7 
            H(13A)-C(13)-H(13B)         107.6 
            C(17)-C(18)-H(18)           120.1 
            C(19)-C(18)-H(18)           120.1 
            C(19)-C(18)-C(17)           119.9(4) 
            C(27)-C(31)-Rh(1)            72.6(2) 
            C(27)-C(31)-H(31)           114.3 
            C(27)-C(31)-C(30)           126.1(4) 
            Rh(1)-C(31)-H(31)           114.3 
            C(30)-C(31)-Rh(1)           106.6(3) 
            C(30)-C(31)-H(31)           114.3 
            C(18)-C(17)-N(1)            121.6(4) 
            C(22)-C(17)-N(1)            119.0(4) 
            C(22)-C(17)-C(18)           119.4(4) 
            C(14)-C(16)-H(16)           119.8 
            C(14)-C(16)-C(23)           120.4(4) 
            C(23)-C(16)-H(16)           119.8 
            C(21)-C(22)-C(1)            120.5(4) 
            C(21)-C(22)-C(17)           120.2(4) 
            C(17)-C(22)-C(1)            119.0(4) 
            C(4)-C(5)-H(5)              119.4 
            C(4)-C(5)-C(6)              121.1(5) 
            C(6)-C(5)-H(5)              119.4 
            N(3)-C(12)-C(11)            106.7(3) 
            O(1)-C(12)-N(3)             125.5(4) 
            O(1)-C(12)-C(11)            127.8(4) 
            Rh(1)-C(24)-H(24)           114.3 
            C(28)-C(24)-Rh(1)            71.0(2) 
            C(28)-C(24)-H(24)           114.3 
            C(28)-C(24)-C(25)           124.2(4) 
            C(25)-C(24)-Rh(1)           110.6(3) 
            C(25)-C(24)-H(24)           114.3 
            C(16)-C(23)-H(23)           119.7 
            C(32)-C(23)-C(16)           120.5(5) 
            C(32)-C(23)-H(23)           119.7 
            C(8)-C(7)-H(7)              119.5 
            C(6)-C(7)-C(8)              121.0(5) 
            C(6)-C(7)-H(7)              119.5 
            C(11)-C(10)-H(10)           120.8 
            C(9)-C(10)-C(11)            118.3(4) 
            C(9)-C(10)-H(10)            120.8 
            C(5)-C(6)-H(6)              120.1 
            C(7)-C(6)-C(5)              119.8(4) 
            C(7)-C(6)-H(6)              120.1 
            C(18)-C(19)-H(19)           119.7 
            C(18)-C(19)-C(20)           120.6(4) 
            C(20)-C(19)-H(19)           119.7 
            C(31)-C(30)-H(30A)          109.1 
            C(31)-C(30)-H(30B)          109.1 
            C(31)-C(30)-C(29)           112.3(4) 
            H(30A)-C(30)-H(30B)         107.9 
            C(29)-C(30)-H(30A)          109.1 
            C(29)-C(30)-H(30B)          109.1 
            C(23)-C(32)-H(32)           120.3 
            C(23)-C(32)-C(35)           119.5(5) 
            C(35)-C(32)-H(32)           120.3 
            Rh(1)-C(28)-H(28)           114.3 
            C(24)-C(28)-Rh(1)            70.0(2) 
            C(24)-C(28)-H(28)           114.3 
            C(24)-C(28)-C(29)           123.1(4) 
            C(29)-C(28)-Rh(1)           113.3(3) 
            C(29)-C(28)-H(28)           114.3 
            C(8)-C(9)-H(9)              119.3 
            C(10)-C(9)-C(8)             121.5(4) 
            C(10)-C(9)-H(9)             119.3 
            C(14)-C(36)-H(36)           119.9 
            C(35)-C(36)-C(14)           120.3(5) 
            C(35)-C(36)-H(36)           119.9 
            C(32)-C(35)-C(36)           120.5(5) 
            C(32)-C(35)-H(35)           119.7 
            C(36)-C(35)-H(35)           119.7 
            N(2)-C(34)-H(34A)           109.5 
            N(2)-C(34)-H(34B)           109.5 
            N(2)-C(34)-H(34C)           109.5 
            H(34A)-C(34)-H(34B)         109.5 
            H(34A)-C(34)-H(34C)         109.5 
            H(34B)-C(34)-H(34C)         109.5 
            C(21)-C(20)-C(19)           119.8(4) 
            C(21)-C(20)-H(20)           120.1 
            C(19)-C(20)-H(20)           120.1 
            C(30)-C(29)-H(29A)          109.5 
            C(30)-C(29)-H(29B)          109.5 
            C(28)-C(29)-C(30)           110.6(4) 
            C(28)-C(29)-H(29A)          109.5 
            C(28)-C(29)-H(29B)          109.5 
            H(29A)-C(29)-H(29B)         108.1 
            C(27)-C(26)-H(26A)          109.1 
            C(27)-C(26)-H(26B)          109.1 
            C(27)-C(26)-C(25)           112.5(3) 
            H(26A)-C(26)-H(26B)         107.8 
            C(25)-C(26)-H(26A)          109.1 
            C(25)-C(26)-H(26B)          109.1 
            C(24)-C(25)-C(26)           113.9(4) 
            C(24)-C(25)-H(25A)          108.8 
            C(24)-C(25)-H(25B)          108.8 
            C(26)-C(25)-H(25A)          108.8 
            C(26)-C(25)-H(25B)          108.8 
            H(25A)-C(25)-H(25B)         107.7 
            Cl(3)-C(37)-H(37)           107.4 
            Cl(2)-C(37)-Cl(3)           110.1(5) 
            Cl(2)-C(37)-Cl(4)           113.3(5) 
            Cl(2)-C(37)-H(37)           107.4 
            Cl(4)-C(37)-Cl(3)           110.9(4) 
            Cl(4)-C(37)-H(37)           107.4 
           _____________________________________________________________ 
  
           Symmetry transformations used to generate equivalent atoms: 
            
  
    Table 4.  Anisotropic displacement parameters (A^2 x 10^3) for t. 
    The anisotropic displacement factor exponent takes the form: 
    -2 pi^2 [ h^2 a*^2 U11 + ... + 2 h k a* b* U12 ] 
  
    _______________________________________________________________________ 
  
              U11        U22        U33        U23        U13        U12 
    _______________________________________________________________________ 
  
    C(3)     15(2)      13(2)      21(2)      -8(2)       2(2)      -1(2) 
    N(3)     16(2)      15(2)      15(2)       1(1)      -2(1)       0(1) 
    Cl(3)   144(2)     113(2)      62(1)     -34(1)      51(2)     -69(2) 
    C(27)    12(2)      21(2)      20(2)      -2(2)      -4(2)      -3(2) 
    C(8)     15(2)      21(2)      33(2)     -14(2)      -1(2)       1(2) 
    C(33)    17(2)      25(2)      26(2)      -6(2)      -8(2)       8(2) 
    C(1)     14(2)      11(2)      15(2)       1(2)      -3(2)       1(1) 
    N(1)     14(2)      17(2)      16(2)      -2(1)      -2(1)       3(1) 
    O(1)     35(2)      20(2)      18(1)       1(1)      -4(1)       4(1) 
    Rh(1)    12(1)      16(1)      13(1)       0(1)      -1(1)      -1(1) 
    Cl(1)    19(1)      26(1)      18(1)       1(1)       2(1)      -4(1) 
    C(21)    18(2)      19(2)      21(2)      -3(2)       3(2)       3(2) 
    C(11)    21(2)      15(2)      20(2)      -4(2)      -5(2)       1(2) 
    C(2)     16(2)      12(2)      19(2)      -4(2)      -4(2)       2(2) 
    N(2)     13(2)      13(2)      15(2)      -2(1)      -2(1)       1(1) 
    Cl(2)   227(4)      63(1)     149(2)     -68(2)     161(3)     -70(2) 
    C(4)     22(2)      15(2)      28(2)      -4(2)       6(2)      -1(2) 
    Cl(4)   166(3)      98(2)     213(4)     112(2)     125(3)      89(2) 
    C(15)    15(2)      15(2)      13(2)      -1(2)       2(2)      -1(2) 
    C(14)    19(2)      23(2)      15(2)       3(2)       2(2)       0(2) 
    C(13)    18(2)      20(2)      18(2)       1(2)       2(2)      -3(2) 
    C(18)    21(2)      16(2)      22(2)       3(2)      -2(2)       3(2) 
    C(31)    16(2)      18(2)      20(2)      -3(2)      -2(2)      -4(2) 
    C(17)    15(2)      15(2)      15(2)       1(1)       2(2)      -1(2) 
    C(16)    22(2)      21(2)      14(2)       4(2)       0(2)       3(2) 
    C(22)    19(2)      12(2)      13(2)       2(2)       1(2)       1(2) 
    C(5)     36(3)      15(2)      32(3)      -3(2)      14(2)      -2(2) 
    C(12)    26(2)      12(2)      17(2)      -2(2)      -6(2)       3(2) 
    C(24)    22(2)      19(2)      16(2)       4(2)       1(2)      -4(2) 
    C(23)    42(3)      26(2)      14(2)      -2(2)       3(2)       4(2) 
    C(7)     16(2)      27(2)      46(3)     -19(2)       7(2)      -1(2) 
    C(10)    25(2)      25(2)      28(2)      -5(2)     -12(2)      10(2) 
    C(6)     28(3)      25(2)      41(3)     -14(2)      19(2)      -8(2) 
    C(19)    24(2)      14(2)      29(2)      -2(2)       1(2)       2(2) 
    C(30)    19(2)      20(2)      23(2)      -4(2)       0(2)       1(2) 
    C(32)    43(3)      37(3)      19(2)      -1(2)       6(2)      18(2) 
    C(28)    15(2)      27(3)      18(2)       2(2)       2(2)      -4(2) 
    C(9)     17(2)      30(2)      40(2)     -13(3)     -10(2)      10(2) 
    C(36)    16(2)      38(3)      20(2)      -1(2)      -1(2)       1(2) 
    C(35)    24(3)      51(3)      23(2)       2(2)       3(2)      14(2) 
    C(34)    18(2)      13(2)      22(2)      -4(2)      -5(2)       1(2) 
    C(20)    17(2)      17(2)      30(2)      -5(2)       3(2)      -4(2) 
    C(29)    16(2)      28(2)      20(2)      -1(2)       2(2)       2(2) 
    C(26)    18(2)      26(3)      22(2)      -1(2)      -6(2)       2(2) 
    C(25)    26(2)      22(2)      24(2)       4(2)      -8(2)       3(2) 
    C(37)   117(7)      23(3)      65(4)      -6(3)      63(5)      -4(4) 
    _______________________________________________________________________ 
  
         Table 5.  Hydrogen coordinates ( x 10^4) and isotropic 
         displacement parameters (A^2 x 10^3) for t. 
  
         ________________________________________________________________ 
  
                         x             y             z           U(eq) 
         ________________________________________________________________ 
  
          H(27)       10366          5581          8110          21 
          H(33A)       9041          3233          7426          34 
          H(33B)       8947          2364          6910          34 
          H(33C)       8503          2070          7547          34 
          H(21)        4444          2453          6089          23 
          H(4)         4553          3185          7627          26 
          H(13A)       7545          4951          6178          22 
          H(13B)       7124          5238          5537          22 
          H(18)        7669           989          6883          24 
          H(31)        9229          6953          8025          22 
          H(16)        6238          3074          5193          23 
          H(5)         3151          2729          8256          33 
          H(24)        7600          3227          8378          23 
          H(23)        7041          1462          4862          33 
          H(7)          931          4339          7271          36 
          H(10)        2852          5708          5704          32 
          H(6)         1330          3289          8078          38 
          H(19)        6504           -90          6324          27 
          H(30A)       7510          7128          8506          25 
          H(30B)       8415          7144          9011          25 
          H(32)        8857          1060          5085          39 
          H(28)        6503          4673          8481          24 
          H(9)         1512          5266          6374          35 
          H(36)        9110          3896          5969          30 
          H(35)        9904          2297          5624          39 
          H(34A)       5806          6035          6906          27 
          H(34B)       6506          5923          7493          27 
          H(34C)       5238          5570          7483          27 
          H(20)        4911           643          5909          25 
          H(29A)       7989          5429          9311          25 
          H(29B)       6808          5945          9172          25 
          H(26A)       9595          5168          9215          26 
          H(26B)      10563          4522          8894          26 
          H(25A)       9463          3142          8637          29 
          H(25B)       8853          3501          9222          29 
          H(37)        5164          7197          5036          82 
         ________________________________________________________________ 
  
         Table 6.  Torsion angles [deg] for t. 
         ________________________________________________________________ 
  
          C(3)-C(8)-C(7)-C(6)                                   0.4(6) 
          C(3)-C(8)-C(9)-C(10)                                  0.5(7) 
          C(3)-C(4)-C(5)-C(6)                                  -0.4(7) 
          N(3)-C(1)-C(2)-C(3)                                 179.8(4) 
          N(3)-C(1)-C(2)-C(11)                                  1.7(4) 
          N(3)-C(1)-N(2)-C(15)                                -90.4(4) 
          N(3)-C(1)-N(2)-C(34)                                 71.9(4) 
          N(3)-C(1)-C(22)-C(21)                               -76.4(5) 
          N(3)-C(1)-C(22)-C(17)                                97.3(4) 
          C(27)-C(31)-C(30)-C(29)                             -38.1(6) 
          C(27)-C(26)-C(25)-C(24)                             -30.0(5) 
          C(8)-C(3)-C(2)-C(1)                                -178.1(4) 
          C(8)-C(3)-C(2)-C(11)                                 -0.2(6) 
          C(8)-C(3)-C(4)-C(5)                                   1.5(6) 
          C(8)-C(7)-C(6)-C(5)                                   0.8(7) 
          C(33)-N(1)-C(15)-Rh(1)                               -3.6(5) 
          C(33)-N(1)-C(15)-N(2)                               175.3(4) 
          C(33)-N(1)-C(17)-C(18)                                9.6(6) 
          C(33)-N(1)-C(17)-C(22)                             -169.7(4) 
          C(1)-N(3)-C(13)-C(14)                                73.3(5) 
          C(1)-N(3)-C(12)-O(1)                               -177.6(4) 
          C(1)-N(3)-C(12)-C(11)                                 2.1(5) 
          C(1)-N(2)-C(15)-N(1)                                -17.4(6) 
          C(1)-N(2)-C(15)-Rh(1)                               161.5(3) 
          N(1)-C(17)-C(22)-C(1)                                 5.1(6) 
          N(1)-C(17)-C(22)-C(21)                              178.9(4) 
          Rh(1)-C(27)-C(31)-C(30)                              98.1(4) 
          Rh(1)-C(27)-C(26)-C(25)                              10.2(5) 
          Rh(1)-C(31)-C(30)-C(29)                              42.2(4) 
          Rh(1)-C(24)-C(28)-C(29)                            -105.4(4) 
          Rh(1)-C(24)-C(25)-C(26)                              35.3(5) 
          Rh(1)-C(28)-C(29)-C(30)                              18.3(4) 
          C(11)-C(10)-C(9)-C(8)                                 0.3(7) 
          C(2)-C(3)-C(8)-C(7)                                 177.9(4) 
          C(2)-C(3)-C(8)-C(9)                                  -0.6(6) 
          C(2)-C(3)-C(4)-C(5)                                -177.8(4) 
          C(2)-C(1)-N(2)-C(15)                                158.4(4) 
          C(2)-C(1)-N(2)-C(34)                                -39.3(4) 
          C(2)-C(1)-C(22)-C(21)                                35.4(5) 
          C(2)-C(1)-C(22)-C(17)                              -150.9(4) 
          C(2)-C(11)-C(12)-N(3)                                -0.8(5) 
          C(2)-C(11)-C(12)-O(1)                               178.8(4) 
          C(2)-C(11)-C(10)-C(9)                                -1.1(7) 
          N(2)-C(1)-C(2)-C(3)                                 -63.4(5) 
          N(2)-C(1)-C(2)-C(11)                                118.5(4) 
          N(2)-C(1)-C(22)-C(21)                               162.5(4) 
          N(2)-C(1)-C(22)-C(17)                               -23.8(5) 
          C(4)-C(3)-C(8)-C(7)                                  -1.5(6) 
          C(4)-C(3)-C(8)-C(9)                                -179.9(4) 
          C(4)-C(3)-C(2)-C(1)                                   1.3(7) 
          C(4)-C(3)-C(2)-C(11)                                179.2(4) 
          C(4)-C(5)-C(6)-C(7)                                  -0.7(7) 
          C(15)-N(1)-C(17)-C(18)                             -168.8(4) 
          C(15)-N(1)-C(17)-C(22)                               11.9(6) 
          C(14)-C(16)-C(23)-C(32)                              -0.5(7) 
          C(14)-C(36)-C(35)-C(32)                              -0.4(8) 
          C(13)-N(3)-C(1)-C(2)                                171.8(3) 
          C(13)-N(3)-C(1)-N(2)                                 52.6(5) 
          C(13)-N(3)-C(1)-C(22)                               -68.5(5) 
          C(13)-N(3)-C(12)-O(1)                                 8.2(7) 
          C(13)-N(3)-C(12)-C(11)                             -172.2(4) 
          C(13)-C(14)-C(16)-C(23)                            -179.7(4) 
          C(13)-C(14)-C(36)-C(35)                            -179.9(4) 
          C(18)-C(17)-C(22)-C(1)                             -174.2(4) 
          C(18)-C(17)-C(22)-C(21)                              -0.4(6) 
          C(18)-C(19)-C(20)-C(21)                              -1.4(7) 
          C(31)-C(27)-C(26)-C(25)                              91.5(5) 
          C(31)-C(30)-C(29)-C(28)                             -40.9(5) 
          C(17)-N(1)-C(15)-Rh(1)                              174.7(3) 
          C(17)-N(1)-C(15)-N(2)                                -6.3(6) 
          C(17)-C(18)-C(19)-C(20)                              -1.2(7) 
          C(16)-C(14)-C(13)-N(3)                               39.3(6) 
          C(16)-C(14)-C(36)-C(35)                              -1.0(7) 
          C(16)-C(23)-C(32)-C(35)                              -0.9(7) 
          C(22)-C(1)-C(2)-C(3)                                 61.9(5) 
          C(22)-C(1)-C(2)-C(11)                              -116.2(4) 
          C(22)-C(1)-N(2)-C(15)                                31.3(5) 
          C(22)-C(1)-N(2)-C(34)                              -166.4(3) 
          C(22)-C(21)-C(20)-C(19)                               3.0(7) 
          C(12)-N(3)-C(1)-C(2)                                 -2.3(4) 
          C(12)-N(3)-C(1)-N(2)                               -121.5(4) 
          C(12)-N(3)-C(1)-C(22)                               117.4(4) 
          C(12)-N(3)-C(13)-C(14)                             -113.0(4) 
          C(12)-C(11)-C(2)-C(3)                              -178.9(4) 
          C(12)-C(11)-C(2)-C(1)                                -0.6(5) 
          C(12)-C(11)-C(10)-C(9)                              178.8(5) 
          C(24)-C(28)-C(29)-C(30)                              98.9(5) 
          C(23)-C(32)-C(35)-C(36)                               1.4(8) 
          C(7)-C(8)-C(9)-C(10)                               -177.9(4) 
          C(10)-C(11)-C(2)-C(3)                                 1.0(7) 
          C(10)-C(11)-C(2)-C(1)                               179.3(4) 
          C(10)-C(11)-C(12)-N(3)                              179.3(4) 
          C(10)-C(11)-C(12)-O(1)                               -1.1(8) 
          C(19)-C(18)-C(17)-N(1)                             -177.2(4) 
          C(19)-C(18)-C(17)-C(22)                               2.1(6) 
          C(28)-C(24)-C(25)-C(26)                             -45.3(6) 
          C(9)-C(8)-C(7)-C(6)                                 178.8(4) 
          C(36)-C(14)-C(13)-N(3)                             -141.9(4) 
          C(36)-C(14)-C(16)-C(23)                               1.5(6) 
          C(34)-N(2)-C(15)-N(1)                              -179.0(3) 
          C(34)-N(2)-C(15)-Rh(1)                                0.0(5) 
          C(20)-C(21)-C(22)-C(1)                              171.6(4) 
          C(20)-C(21)-C(22)-C(17)                              -2.1(6) 
          C(26)-C(27)-C(31)-Rh(1)                            -102.7(4) 
          C(26)-C(27)-C(31)-C(30)                              -4.6(7) 
          C(25)-C(24)-C(28)-Rh(1)                             102.5(4) 
          C(25)-C(24)-C(28)-C(29)                              -2.9(7) 
         ________________________________________________________________ 
  
         Symmetry transformations used to generate equivalent atoms: 
          
  
 Table 7.  Hydrogen bonds for t [A and deg.]. 
 ____________________________________________________________________________ 
  
 D-H...A                      d(D-H)      d(H...A)    d(D...A)    <(DHA) 
  
