data_5
_audit_creation_date               2025-06-08
_audit_creation_method
;
Olex2 1.5
(compiled 2024.02.16 svn.r378c4104 for OlexSys, GUI svn.r6928)
;
_shelx_SHELXL_version_number       '2019/3'
_audit_contact_author_address      ?
_audit_contact_author_email        ?
_audit_contact_author_name         ''
_audit_contact_author_phone        ?
_publ_contact_author_id_orcid      ?
_publ_section_references
;
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.

Sheldrick, G.M. (2015). Acta Cryst. A71, 3-8.

Sheldrick, G.M. (2015). Acta Cryst. C71, 3-8.
;
_chemical_name_common              ?
_chemical_name_systematic          ?
_chemical_formula_moiety           'C78 H97 Ge N Si, C6 H14'
_chemical_formula_sum              'C84 H111 Ge N Si'
_chemical_formula_weight           1235.41
_chemical_melting_point            ?
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Ge' 'Ge' 0.1547 1.8001 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N' 'N' 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Si' 'Si' 0.0817 0.0704 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system        'triclinic'
_space_group_IT_number             2
_space_group_name_H-M_alt          'P -1'
_space_group_name_Hall             '-P 1'
loop_
  _space_group_symop_operation_xyz
 'x, y, z'
 '-x, -y, -z'

_cell_length_a                     14.6976(3)
_cell_length_b                     15.2150(3)
_cell_length_c                     17.4355(4)
_cell_angle_alpha                  84.988(2)
_cell_angle_beta                   75.453(2)
_cell_angle_gamma                  72.888(2)
_cell_volume                       3606.55(14)
_cell_formula_units_Z              2
_cell_measurement_reflns_used      13208
_cell_measurement_temperature      150.00(10)
_cell_measurement_theta_max        28.5210
_cell_measurement_theta_min        1.8870
_shelx_estimated_absorpt_T_max     0.944
_shelx_estimated_absorpt_T_min     0.926
_exptl_absorpt_coefficient_mu      0.485
_exptl_absorpt_correction_T_max    1.00000
_exptl_absorpt_correction_T_min    0.89260
_exptl_absorpt_correction_type     none
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.43.136a (Rigaku Oxford Diffraction, 2024)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details     ?
_exptl_crystal_colour              yellow
_exptl_crystal_colour_primary      yellow
_exptl_crystal_density_diffrn      1.138
_exptl_crystal_density_meas        ?
_exptl_crystal_density_method      ?
_exptl_crystal_description         block
_exptl_crystal_F_000               1336
_exptl_crystal_size_max            0.16
_exptl_crystal_size_mid            0.14
_exptl_crystal_size_min            0.12
_exptl_transmission_factor_max     ?
_exptl_transmission_factor_min     ?
_diffrn_reflns_av_R_equivalents    0.0415
_diffrn_reflns_av_unetI/netI       0.0508
_diffrn_reflns_Laue_measured_fraction_full  0.999
_diffrn_reflns_Laue_measured_fraction_max  0.974
_diffrn_reflns_limit_h_max         18
_diffrn_reflns_limit_h_min         -18
_diffrn_reflns_limit_k_max         19
_diffrn_reflns_limit_k_min         -19
_diffrn_reflns_limit_l_max         22
_diffrn_reflns_limit_l_min         -22
_diffrn_reflns_number              45565
_diffrn_reflns_point_group_measured_fraction_full  0.999
_diffrn_reflns_point_group_measured_fraction_max  0.974
_diffrn_reflns_theta_full          25.242
_diffrn_reflns_theta_max           27.481
_diffrn_reflns_theta_min           1.887
_diffrn_ambient_temperature        150.15
_diffrn_detector_area_resol_mean   10.0000
_diffrn_detector_type              HyPix
_diffrn_measured_fraction_theta_full  0.999
_diffrn_measured_fraction_theta_max  0.974
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
--------------------------------------------------------------------------
  1  ω    -65.00  13.00   0.50    3.90    --    2.84 -38.00-180.00  156
  2  ω    -61.00  14.00   0.50    3.90    --    2.84 -38.00 -60.00  150
  3  ω     -4.00  31.00   0.50    3.90    --    2.84 -99.00  30.00   70
  4  ω    -53.00  14.00   0.50    3.90    --    2.84 -38.00  60.00  134
  5  ω     -4.00  22.00   0.50    3.90    --    2.84  38.00  90.00   52
  6  ω     36.00  62.00   0.50    3.90    --    2.84  38.00  90.00   52
  7  ω    -18.00   9.00   0.50    3.90    --   -4.01 -99.00-120.00   54
  8  ω     -5.00  23.00   0.50    3.90    --   -4.01 -99.00-180.00   56
;
_diffrn_measurement_device         'four-circle diffractometer'
_diffrn_measurement_device_type    'Bruker APEX-II CCD'
_diffrn_measurement_method         'ω scans'
_diffrn_radiation_type             MoK\a
_diffrn_radiation_wavelength       0.71073
_diffrn_source                     ?
_diffrn_standards_number           0
_reflns_Friedel_coverage           0.000
_reflns_Friedel_fraction_full      .
_reflns_Friedel_fraction_max       .
_reflns_number_gt                  12374
_reflns_number_total               16107
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression       'I > 2σ(I)'
_computing_cell_refinement         'CrysAlisPro 1.171.43.136a (Rigaku OD, 2024)'
_computing_data_collection        
 'CrysAlisPro system (CCD 43.136a 64-bit (release 23-08-2024))'
_computing_data_reduction          'CrysAlisPro 1.171.43.136a (Rigaku OD, 2024)'
_computing_molecular_graphics      'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement    'SHELXL 2019/3 (Sheldrick, 2015)'
_computing_structure_solution      'SHELXT  (Sheldrick, 2015)'
_refine_diff_density_max           1.739
_refine_diff_density_min           -1.556
_refine_diff_density_rms           0.105
_refine_ls_extinction_coef         .
_refine_ls_extinction_method       none
_refine_ls_goodness_of_fit_ref     1.020
_refine_ls_hydrogen_treatment      mixed
_refine_ls_matrix_type             full
_refine_ls_number_parameters       871
_refine_ls_number_reflns           16107
_refine_ls_number_restraints       226
_refine_ls_R_factor_all            0.0980
_refine_ls_R_factor_gt             0.0758
_refine_ls_restrained_S_all        1.020
_refine_ls_shift/su_max            0.001
_refine_ls_shift/su_mean           0.000
_refine_ls_structure_factor_coef   Fsqd
_refine_ls_weighting_details      
 'w=1/[σ²(Fo²)+(0.1142P)²+8.6991P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme        calc
_refine_ls_wR_factor_gt            0.2092
_refine_ls_wR_factor_ref           0.2225
_refine_special_details           
 'In the refinement of 5, SIMU instruction was applied to C1, N1 and Ge1 to make their anisotropic displacement parameters reasonable, n-hexane solvent (C79 to C84) exhibit a positional disorder, they were separated using PART instruction and refined using a free variable (FVAR). SAME, RIGU and SIMU instructions were applied make the shape, position and anisotropic displacement parameters in a reasonable range, the final occupancies of 0.825(7):0.175(7) have been determined for PART 1 and PART 2, respectively.'
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups, All Si(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 Ge1-H1
 1.45 with sigma of 0.02
3. Uiso/Uaniso restraints and constraints
N1 \\sim C1: within 2A with sigma of 0.002 and sigma for terminal atoms of
0.004 within 2A
C79 \\sim C80 \\sim C81 \\sim C82 \\sim C83 \\sim C84 \\sim C79A \\sim C80A
\\sim C81A \\sim C82A \\sim C83A \\sim C84A: within 2A with sigma of 0.01 and
sigma for terminal atoms of 0.02 within 2A
Si1 \\sim N1: within 2A with sigma of 0.001 and sigma for terminal atoms of
0.002 within 2A
4. Rigid body (RIGU) restrains
 C79, C80, C81, C82, C83, C84, C79A, C80A, C81A, C82A, C83A, C84A
 with sigma for 1-2 distances of 0.002 and sigma for 1-3 distances of 0.002
5. Same fragment restrains
{C79A, C80A, C81A, C82A, C83A, C84A} sigma for 1-2: 0.01, 1-3: 0.02
as in
{C79, C80, C81, C82, C83, C84}
6. Others
 Sof(C79A)=Sof(H79D)=Sof(H79E)=Sof(H79F)=Sof(C80A)=Sof(H80C)=Sof(H80D)=
 Sof(C81A)=Sof(H81C)=Sof(H81D)=Sof(C82A)=Sof(H82C)=Sof(H82D)=Sof(C83A)=
 Sof(H83C)=Sof(H83D)=Sof(C84A)=Sof(H84D)=Sof(H84E)=Sof(H84F)=1-FVAR(1)
 Sof(C79)=Sof(H79A)=Sof(H79B)=Sof(H79C)=Sof(C80)=Sof(H80A)=Sof(H80B)=Sof(C81)=
 Sof(H81A)=Sof(H81B)=Sof(C82)=Sof(H82A)=Sof(H82B)=Sof(C83)=Sof(H83A)=Sof(H83B)=
 Sof(C84)=Sof(H84A)=Sof(H84B)=Sof(H84C)=FVAR(1)
7.a Riding coordinates:
 C84A(H84D,H84E,H84F)
7.b Secondary CH2 refined with riding coordinates:
 C7(H7A,H7B), C11(H11A,H11B), C31(H31A,H31B), C35(H35A,H35B), C39(H39A,H39B),
 C43(H43A,H43B), C60(H60A,H60B), C64(H64A,H64B), C68(H68A,H68B), C72(H72A,H72B),
  C80(H80A,H80B), C81(H81A,H81B), C82(H82A,H82B), C83(H83A,H83B), C80A(H80C,
 H80D), C81A(H81C,H81D), C82A(H82C,H82D), C83A(H83C,H83D)
7.c Aromatic/amide H refined with riding coordinates:
 C4(H4), C17(H17), C20(H20), C23(H23), C26(H26), C46(H46), C49(H49), C52(H52),
 C55(H55), C74(H74), C75(H75), C76(H76), C77(H77), C78(H78)
7.d Idealised Me refined as rotating group:
 C9(H9A,H9B,H9C), C10(H10A,H10B,H10C), C13(H13A,H13B,H13C), C14(H14A,H14B,
 H14C), C29(H29A,H29B,H29C), C30(H30A,H30B,H30C), C33(H33A,H33B,H33C), C34(H34A,
 H34B,H34C), C37(H37A,H37B,H37C), C38(H38A,H38B,H38C), C41(H41A,H41B,H41C),
 C42(H42A,H42B,H42C), C58(H58A,H58B,H58C), C59(H59A,H59B,H59C), C62(H62A,H62B,
 H62C), C63(H63A,H63B,H63C), C66(H66A,H66B,H66C), C67(H67A,H67B,H67C), C70(H70A,
 H70B,H70C), C71(H71A,H71B,H71C), C79(H79A,H79B,H79C), C84(H84A,H84B,H84C),
 C79A(H79D,H79E,H79F)
;
_atom_sites_solution_hydrogens     mixed
_atom_sites_solution_primary       dual
_atom_sites_solution_secondary     ?
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_site_symmetry_order
  _atom_site_calc_flag
  _atom_site_refinement_flags_posn
  _atom_site_refinement_flags_adp
  _atom_site_refinement_flags_occupancy
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 Ge1 Ge 0.36641(3) 0.51940(3) 0.21593(3) 0.03544(14) Uani 1 1 d D . . A 1
 Si1 Si 0.36850(7) 0.72600(7) 0.17834(6) 0.0231(2) Uani 1 1 d . U . A 1
 H1A H 0.274(3) 0.759(3) 0.159(2) 0.028 Uiso 1 1 d . U . B 1
 H1B H 0.368(3) 0.797(3) 0.219(2) 0.028 Uiso 1 1 d . U . C 1
 N1 N 0.38252(19) 0.62890(18) 0.23910(17) 0.0186(4) Uani 1 1 d . U . A 1
 C1 C 0.3817(2) 0.63919(19) 0.32222(17) 0.0130(5) Uani 1 1 d . U . . .
 C2 C 0.2933(2) 0.65128(19) 0.38084(17) 0.0112(5) Uani 1 1 d . . . . .
 C3 C 0.2894(2) 0.6648(2) 0.45982(17) 0.0133(6) Uani 1 1 d . . . . .
 C4 C 0.3725(2) 0.6669(2) 0.48264(18) 0.0157(6) Uani 1 1 d . . . . .
 H4 H 0.369164 0.678617 0.536045 0.019 Uiso 1 1 calc R U . . .
 C5 C 0.4608(2) 0.6514(2) 0.42604(18) 0.0135(6) Uani 1 1 d . . . . .
 C6 C 0.4664(2) 0.63648(19) 0.34654(17) 0.0116(5) Uani 1 1 d . . . . .
 C7 C 0.1297(2) 0.6584(2) 0.45663(18) 0.0174(6) Uani 1 1 d . . . . .
 H7A H 0.065728 0.705929 0.462853 0.021 Uiso 1 1 calc R U . . .
 H7B H 0.117238 0.597679 0.469528 0.021 Uiso 1 1 calc R U . . .
 C8 C 0.1873(2) 0.6777(2) 0.51320(18) 0.0169(6) Uani 1 1 d . . . . .
 C9 C 0.1441(3) 0.7750(2) 0.5469(2) 0.0252(7) Uani 1 1 d . . . . .
 H9A H 0.187773 0.787136 0.576236 0.038 Uiso 1 1 calc R U . . .
 H9B H 0.079619 0.780071 0.582553 0.038 Uiso 1 1 calc R U . . .
 H9C H 0.137282 0.819859 0.503314 0.038 Uiso 1 1 calc R U . . .
 C10 C 0.1884(2) 0.6084(3) 0.5824(2) 0.0245(7) Uani 1 1 d . . . . .
 H10A H 0.218967 0.545930 0.561882 0.037 Uiso 1 1 calc R U . . .
 H10B H 0.121063 0.613720 0.612502 0.037 Uiso 1 1 calc R U . . .
 H10C H 0.225898 0.621106 0.617239 0.037 Uiso 1 1 calc R U . . .
 C11 C 0.6297(2) 0.6033(2) 0.36414(18) 0.0155(6) Uani 1 1 d . . . . .
 H11A H 0.657193 0.536698 0.373560 0.019 Uiso 1 1 calc R U . . .
 H11B H 0.684532 0.631349 0.347608 0.019 Uiso 1 1 calc R U . . .
 C12 C 0.5590(2) 0.6483(2) 0.44087(18) 0.0145(6) Uani 1 1 d . . . . .
 C13 C 0.5643(3) 0.7456(2) 0.4524(2) 0.0237(7) Uani 1 1 d . . . . .
 H13A H 0.551443 0.784104 0.406097 0.036 Uiso 1 1 calc R U . . .
 H13B H 0.629749 0.742208 0.458515 0.036 Uiso 1 1 calc R U . . .
 H13C H 0.515157 0.772341 0.499956 0.036 Uiso 1 1 calc R U . . .
 C14 C 0.5796(2) 0.5900(2) 0.51411(19) 0.0218(7) Uani 1 1 d . . . . .
 H14A H 0.531722 0.618625 0.561578 0.033 Uiso 1 1 calc R U . . .
 H14B H 0.645810 0.585817 0.518827 0.033 Uiso 1 1 calc R U . . .
 H14C H 0.574496 0.528116 0.508757 0.033 Uiso 1 1 calc R U . . .
 C15 C 0.5720(2) 0.61799(19) 0.29720(17) 0.0121(6) Uani 1 1 d . . . . .
 C16 C 0.5970(2) 0.6931(2) 0.23828(18) 0.0134(6) Uani 1 1 d . . . . .
 C17 C 0.5683(2) 0.7876(2) 0.24529(19) 0.0162(6) Uani 1 1 d . . . . .
 H17 H 0.520448 0.815066 0.290737 0.019 Uiso 1 1 calc R U . . .
 C18 C 0.6088(2) 0.8440(2) 0.1862(2) 0.0173(6) Uani 1 1 d . . . . .
 C19 C 0.6806(2) 0.8032(2) 0.1196(2) 0.0185(6) Uani 1 1 d . . . . .
 C20 C 0.7052(2) 0.7077(2) 0.11084(19) 0.0187(6) Uani 1 1 d . . . . .
 H20 H 0.751072 0.679812 0.064634 0.022 Uiso 1 1 calc R U . . .
 C21 C 0.6633(2) 0.6537(2) 0.16891(18) 0.0145(6) Uani 1 1 d . . . . .
 C22 C 0.6750(2) 0.5544(2) 0.17252(17) 0.0133(6) Uani 1 1 d . . . . .
 C23 C 0.7302(2) 0.4859(2) 0.11867(18) 0.0156(6) Uani 1 1 d . . . . .
 H23 H 0.770360 0.500989 0.070581 0.019 Uiso 1 1 calc R U . . .
 C24 C 0.7276(2) 0.3945(2) 0.13401(18) 0.0156(6) Uani 1 1 d . . . . .
 C25 C 0.6661(2) 0.37353(19) 0.20490(18) 0.0141(6) Uani 1 1 d . . . . .
 C26 C 0.6124(2) 0.4438(2) 0.25975(18) 0.0150(6) Uani 1 1 d . . . . .
 H26 H 0.572839 0.429342 0.308439 0.018 Uiso 1 1 calc R U . . .
 C27 C 0.6162(2) 0.53349(19) 0.24416(18) 0.0124(6) Uani 1 1 d . . . . .
 C28 C 0.6566(2) 0.2757(2) 0.22528(19) 0.0182(6) Uani 1 1 d . . . . .
 C29 C 0.5497(3) 0.2764(3) 0.2538(3) 0.0348(9) Uani 1 1 d . . . . .
 H29A H 0.519747 0.312495 0.302221 0.052 Uiso 1 1 calc R U . . .
 H29B H 0.545727 0.213152 0.264907 0.052 Uiso 1 1 calc R U . . .
 H29C H 0.514659 0.303856 0.212669 0.052 Uiso 1 1 calc R U . . .
 C30 C 0.7114(4) 0.2334(3) 0.2896(3) 0.0388(10) Uani 1 1 d . . . . .
 H30A H 0.780471 0.232000 0.270624 0.058 Uiso 1 1 calc R U . . .
 H30B H 0.706518 0.170606 0.301748 0.058 Uiso 1 1 calc R U . . .
 H30C H 0.682294 0.270512 0.337480 0.058 Uiso 1 1 calc R U . . .
 C31 C 0.6993(3) 0.2154(2) 0.1512(2) 0.0291(8) Uani 1 1 d . . . . .
 H31A H 0.706638 0.150178 0.167605 0.035 Uiso 1 1 calc R U . . .
 H31B H 0.652598 0.232149 0.116495 0.035 Uiso 1 1 calc R U . . .
 C32 C 0.7907(2) 0.3220(2) 0.07125(19) 0.0202(7) Uani 1 1 d . . . . .
 C33 C 0.7483(3) 0.3399(3) -0.0024(2) 0.0316(8) Uani 1 1 d . . . . .
 H33A H 0.681385 0.334262 0.011921 0.047 Uiso 1 1 calc R U . . .
 H33B H 0.789053 0.294856 -0.042986 0.047 Uiso 1 1 calc R U . . .
 H33C H 0.747422 0.402080 -0.023090 0.047 Uiso 1 1 calc R U . . .
 C34 C 0.8971(3) 0.3279(3) 0.0460(2) 0.0323(9) Uani 1 1 d . . . . .
 H34A H 0.897807 0.388469 0.022130 0.048 Uiso 1 1 calc R U . . .
 H34B H 0.936050 0.280031 0.007261 0.048 Uiso 1 1 calc R U . . .
 H34C H 0.924943 0.318784 0.092565 0.048 Uiso 1 1 calc R U . . .
 C35 C 0.7966(3) 0.2252(2) 0.1050(2) 0.0283(8) Uani 1 1 d . . . . .
 H35A H 0.822688 0.181064 0.060877 0.034 Uiso 1 1 calc R U . . .
 H35B H 0.843044 0.209443 0.139870 0.034 Uiso 1 1 calc R U . . .
 C36 C 0.5730(2) 0.9486(2) 0.1984(2) 0.0241(7) Uani 1 1 d . . . . .
 C37 C 0.4613(3) 0.9825(3) 0.2206(3) 0.0479(13) Uani 1 1 d . . . . .
 H37A H 0.435342 0.964753 0.179575 0.072 Uiso 1 1 calc R U . . .
 H37B H 0.440262 1.049617 0.224967 0.072 Uiso 1 1 calc R U . . .
 H37C H 0.436433 0.954845 0.271500 0.072 Uiso 1 1 calc R U . . .
 C38 C 0.6128(4) 0.9724(3) 0.2654(3) 0.0432(11) Uani 1 1 d . . . . .
 H38A H 0.589013 0.940846 0.314411 0.065 Uiso 1 1 calc R U . . .
 H38B H 0.590008 1.038967 0.273415 0.065 Uiso 1 1 calc R U . . .
 H38C H 0.684568 0.952361 0.250819 0.065 Uiso 1 1 calc R U . . .
 C39 C 0.6089(3) 0.9988(3) 0.1215(3) 0.0357(9) Uani 1 1 d . . . . .
 H39A H 0.567962 0.998684 0.084278 0.043 Uiso 1 1 calc R U . . .
 H39B H 0.599617 1.063588 0.133739 0.043 Uiso 1 1 calc R U . . .
 C40 C 0.7350(3) 0.8578(2) 0.0549(2) 0.0256(7) Uani 1 1 d . . . . .
 C41 C 0.7061(4) 0.8568(4) -0.0229(3) 0.0458(11) Uani 1 1 d . . . . .
 H41A H 0.723699 0.793166 -0.040341 0.069 Uiso 1 1 calc R U . . .
 H41B H 0.740742 0.892246 -0.063180 0.069 Uiso 1 1 calc R U . . .
 H41C H 0.635244 0.884206 -0.015204 0.069 Uiso 1 1 calc R U . . .
 C42 C 0.8459(3) 0.8146(3) 0.0415(3) 0.0417(11) Uani 1 1 d . . . . .
 H42A H 0.864758 0.809911 0.092108 0.062 Uiso 1 1 calc R U . . .
 H42B H 0.880115 0.853204 0.004409 0.062 Uiso 1 1 calc R U . . .
 H42C H 0.863724 0.753099 0.019449 0.062 Uiso 1 1 calc R U . . .
 C43 C 0.7136(3) 0.9570(3) 0.0820(3) 0.0352(9) Uani 1 1 d . . . . .
 H43A H 0.754572 0.957192 0.119161 0.042 Uiso 1 1 calc R U . . .
 H43B H 0.732516 0.995416 0.035345 0.042 Uiso 1 1 calc R U . . .
 C44 C 0.1917(2) 0.65962(19) 0.36876(17) 0.0122(6) Uani 1 1 d . . . . .
 C45 C 0.1759(2) 0.5877(2) 0.32157(18) 0.0140(6) Uani 1 1 d . . . . .
 C46 C 0.1936(2) 0.4937(2) 0.33472(19) 0.0172(6) Uani 1 1 d . . . . .
 H46 H 0.227563 0.464920 0.374043 0.021 Uiso 1 1 calc R U . . .
 C47 C 0.1617(2) 0.4402(2) 0.2904(2) 0.0178(6) Uani 1 1 d . . . . .
 C48 C 0.1081(2) 0.4833(2) 0.23438(19) 0.0174(6) Uani 1 1 d . . . . .
 C49 C 0.0915(2) 0.5789(2) 0.22107(19) 0.0176(6) Uani 1 1 d . . . . .
 H49 H 0.057340 0.608367 0.182037 0.021 Uiso 1 1 calc R U . . .
 C50 C 0.1243(2) 0.6304(2) 0.26396(18) 0.0144(6) Uani 1 1 d . . . . .
 C51 C 0.1113(2) 0.7295(2) 0.26428(18) 0.0134(6) Uani 1 1 d . . . . .
 C52 C 0.0710(2) 0.8004(2) 0.21669(18) 0.0146(6) Uani 1 1 d . . . . .
 H52 H 0.043928 0.787547 0.176332 0.018 Uiso 1 1 calc R U . . .
 C53 C 0.0699(2) 0.8908(2) 0.22747(18) 0.0145(6) Uani 1 1 d . . . . .
 C54 C 0.1090(2) 0.90911(19) 0.28819(18) 0.0135(6) Uani 1 1 d . . . . .
 C55 C 0.1527(2) 0.8358(2) 0.33398(18) 0.0136(6) Uani 1 1 d . . . . .
 H55 H 0.182710 0.847343 0.372880 0.016 Uiso 1 1 calc R U . . .
 C56 C 0.1524(2) 0.7472(2) 0.32300(18) 0.0129(6) Uani 1 1 d . . . . .
 C57 C 0.1839(2) 0.3362(2) 0.3076(2) 0.0229(7) Uani 1 1 d . . . . .
 C58 C 0.1161(3) 0.3197(3) 0.3858(3) 0.0357(9) Uani 1 1 d . . . . .
 H58A H 0.128402 0.348645 0.428744 0.053 Uiso 1 1 calc R U . . .
 H58B H 0.128454 0.253388 0.396379 0.053 Uiso 1 1 calc R U . . .
 H58C H 0.047758 0.346344 0.382618 0.053 Uiso 1 1 calc R U . . .
 C59 C 0.2905(3) 0.2939(2) 0.3143(3) 0.0324(9) Uani 1 1 d . . . . .
 H59A H 0.335001 0.310675 0.267179 0.049 Uiso 1 1 calc R U . . .
 H59B H 0.304700 0.226761 0.318378 0.049 Uiso 1 1 calc R U . . .
 H59C H 0.299610 0.317211 0.361645 0.049 Uiso 1 1 calc R U . . .
 C60 C 0.1702(3) 0.2883(2) 0.2387(3) 0.0310(8) Uani 1 1 d . . . . .
 H60A H 0.224028 0.289263 0.191534 0.037 Uiso 1 1 calc R U . . .
 H60B H 0.174229 0.223193 0.253580 0.037 Uiso 1 1 calc R U . . .
 C61 C 0.0648(3) 0.4326(2) 0.1869(2) 0.0225(7) Uani 1 1 d . . . . .
 C62 C -0.0445(3) 0.4818(3) 0.1943(3) 0.0332(9) Uani 1 1 d . . . . .
 H62A H -0.077478 0.492985 0.250358 0.050 Uiso 1 1 calc R U . . .
 H62B H -0.074154 0.443225 0.172131 0.050 Uiso 1 1 calc R U . . .
 H62C H -0.051486 0.540624 0.165303 0.050 Uiso 1 1 calc R U . . .
 C63 C 0.1198(3) 0.4313(3) 0.0992(2) 0.0342(9) Uani 1 1 d . . . . .
 H63A H 0.115931 0.494409 0.079947 0.051 Uiso 1 1 calc R U . . .
 H63B H 0.089818 0.402342 0.067961 0.051 Uiso 1 1 calc R U . . .
 H63C H 0.188595 0.396156 0.093829 0.051 Uiso 1 1 calc R U . . .
 C64 C 0.0737(3) 0.3337(2) 0.2179(2) 0.0294(8) Uani 1 1 d . . . . .
 H64A H 0.019997 0.334228 0.265493 0.035 Uiso 1 1 calc R U . . .
 H64B H 0.065821 0.297150 0.176984 0.035 Uiso 1 1 calc R U . . .
 C65 C 0.0269(2) 0.9662(2) 0.1714(2) 0.0208(7) Uani 1 1 d . . . . .
 C66 C -0.0846(3) 0.9845(3) 0.1904(3) 0.0347(9) Uani 1 1 d . . . . .
 H66A H -0.100467 0.927049 0.186590 0.052 Uiso 1 1 calc R U . . .
 H66B H -0.111621 1.029861 0.152595 0.052 Uiso 1 1 calc R U . . .
 H66C H -0.113073 1.008215 0.244311 0.052 Uiso 1 1 calc R U . . .
 C67 C 0.0705(4) 0.9352(3) 0.0849(2) 0.0367(9) Uani 1 1 d . . . . .
 H67A H 0.142026 0.912506 0.075338 0.055 Uiso 1 1 calc R U . . .
 H67B H 0.052720 0.987469 0.049161 0.055 Uiso 1 1 calc R U . . .
 H67C H 0.044520 0.886010 0.074992 0.055 Uiso 1 1 calc R U . . .
 C68 C 0.0537(3) 1.0549(2) 0.1793(2) 0.0253(7) Uani 1 1 d . . . . .
 H68A H 0.123058 1.047288 0.151517 0.030 Uiso 1 1 calc R U . . .
 H68B H 0.012696 1.106346 0.153280 0.030 Uiso 1 1 calc R U . . .
 C69 C 0.1075(2) 1.0060(2) 0.3075(2) 0.0191(6) Uani 1 1 d . . . . .
 C70 C 0.0685(3) 1.0224(3) 0.3969(2) 0.0358(9) Uani 1 1 d . . . . .
 H70A H 0.003850 1.011586 0.414272 0.054 Uiso 1 1 calc R U . . .
 H70B H 0.063021 1.085986 0.408198 0.054 Uiso 1 1 calc R U . . .
 H70C H 0.113733 0.980124 0.425388 0.054 Uiso 1 1 calc R U . . .
 C71 C 0.2127(3) 1.0141(3) 0.2820(3) 0.0378(10) Uani 1 1 d . . . . .
 H71A H 0.255715 0.964532 0.307033 0.057 Uiso 1 1 calc R U . . .
 H71B H 0.213917 1.073689 0.298342 0.057 Uiso 1 1 calc R U . . .
 H71C H 0.235580 1.009339 0.224220 0.057 Uiso 1 1 calc R U . . .
 C72 C 0.0390(3) 1.0786(2) 0.2647(2) 0.0240(7) Uani 1 1 d . . . . .
 H72A H -0.029855 1.084122 0.292939 0.029 Uiso 1 1 calc R U . . .
 H72B H 0.050996 1.138951 0.266709 0.029 Uiso 1 1 calc R U . . .
 C73 C 0.4592(3) 0.7020(3) 0.0809(2) 0.0254(7) Uani 1 1 d . . . A 1
 C74 C 0.5182(3) 0.6138(3) 0.0563(2) 0.0303(8) Uani 1 1 d . . . A 1
 H74 H 0.517164 0.563370 0.092443 0.036 Uiso 1 1 calc R U . A 1
 C75 C 0.5779(3) 0.5984(3) -0.0193(2) 0.0355(9) Uani 1 1 d . . . A 1
 H75 H 0.616341 0.537842 -0.035044 0.043 Uiso 1 1 calc R U . A 1
 C76 C 0.5813(3) 0.6717(3) -0.0718(2) 0.0402(10) Uani 1 1 d . . . A 1
 H76 H 0.622701 0.661582 -0.123613 0.048 Uiso 1 1 calc R U . A 1
 C77 C 0.5250(3) 0.7588(3) -0.0494(3) 0.0392(10) Uani 1 1 d . . . A 1
 H77 H 0.527559 0.808976 -0.085549 0.047 Uiso 1 1 calc R U . A 1
 C78 C 0.4641(3) 0.7740(3) 0.0266(2) 0.0336(9) Uani 1 1 d . . . A 1
 H78 H 0.425297 0.834643 0.041516 0.040 Uiso 1 1 calc R U . A 1
 C79 C -0.1667(5) 0.7402(6) 0.3060(5) 0.0671(19) Uani 0.825(7) 1 d D U P D 1
 H79A H -0.124099 0.768527 0.265470 0.101 Uiso 0.825(7) 1 calc R U P D 1
 H79B H -0.234814 0.778169 0.313101 0.101 Uiso 0.825(7) 1 calc R U P D 1
 H79C H -0.160968 0.678619 0.289246 0.101 Uiso 0.825(7) 1 calc R U P D 1
 C80 C -0.1366(5) 0.7332(5) 0.3827(5) 0.0678(17) Uani 0.825(7) 1 d D U P D 1
 H80A H -0.071119 0.688262 0.376920 0.081 Uiso 0.825(7) 1 calc R U P D 1
 H80B H -0.183340 0.709279 0.424244 0.081 Uiso 0.825(7) 1 calc R U P D 1
 C81 C -0.1327(5) 0.8243(5) 0.4099(5) 0.0675(16) Uani 0.825(7) 1 d D U P D 1
 H81A H -0.100186 0.812833 0.454570 0.081 Uiso 0.825(7) 1 calc R U P D 1
 H81B H -0.093189 0.852926 0.365887 0.081 Uiso 0.825(7) 1 calc R U P D 1
 C82 C -0.2326(5) 0.8887(6) 0.4353(5) 0.0650(16) Uani 0.825(7) 1 d D U P D 1
 H82A H -0.266515 0.895511 0.391778 0.078 Uiso 0.825(7) 1 calc R U P D 1
 H82B H -0.270037 0.861231 0.481491 0.078 Uiso 0.825(7) 1 calc R U P D 1
 C83 C -0.2336(6) 0.9769(6) 0.4559(6) 0.0760(19) Uani 0.825(7) 1 d D U P D 1
 H83A H -0.204691 1.007320 0.407209 0.091 Uiso 0.825(7) 1 calc R U P D 1
 H83B H -0.190153 0.968755 0.492622 0.091 Uiso 0.825(7) 1 calc R U P D 1
 C84 C -0.3341(8) 1.0430(7) 0.4946(8) 0.107(3) Uani 0.825(7) 1 d D U P D 1
 H84A H -0.372761 1.064327 0.454806 0.160 Uiso 0.825(7) 1 calc R U P D 1
 H84B H -0.324124 1.095922 0.516124 0.160 Uiso 0.825(7) 1 calc R U P D 1
 H84C H -0.369204 1.010599 0.537593 0.160 Uiso 0.825(7) 1 calc R U P D 1
 C79A C -0.131(2) 0.6630(19) 0.394(2) 0.060(5) Uani 0.175(7) 1 d D U P D 2
 H79D H -0.158758 0.675622 0.450104 0.090 Uiso 0.175(7) 1 calc R U P D 2
 H79E H -0.059088 0.641339 0.383745 0.090 Uiso 0.175(7) 1 calc R U P D 2
 H79F H -0.155142 0.615645 0.377856 0.090 Uiso 0.175(7) 1 calc R U P D 2
 C80A C -0.160(2) 0.7493(18) 0.3463(16) 0.066(3) Uani 0.175(7) 1 d D U P D 2
 H80C H -0.224256 0.754419 0.335630 0.080 Uiso 0.175(7) 1 calc R U P D 2
 H80D H -0.111539 0.744249 0.294594 0.080 Uiso 0.175(7) 1 calc R U P D 2
 C81A C -0.167(2) 0.8369(18) 0.386(2) 0.070(3) Uani 0.175(7) 1 d D U P D 2
 H81C H -0.118732 0.822970 0.420062 0.084 Uiso 0.175(7) 1 calc R U P D 2
 H81D H -0.149691 0.882717 0.345562 0.084 Uiso 0.175(7) 1 calc R U P D 2
 C82A C -0.2668(19) 0.876(3) 0.436(2) 0.074(3) Uani 0.175(7) 1 d D U P D 2
 H82C H -0.309415 0.906369 0.399765 0.088 Uiso 0.175(7) 1 calc R U P D 2
 H82D H -0.290851 0.824096 0.462118 0.088 Uiso 0.175(7) 1 calc R U P D 2
 C83A C -0.281(2) 0.939(3) 0.495(2) 0.078(4) Uani 0.175(7) 1 d D U P D 2
 H83C H -0.234552 0.976636 0.475221 0.094 Uiso 0.175(7) 1 calc R U P D 2
 H83D H -0.262704 0.904236 0.541849 0.094 Uiso 0.175(7) 1 calc R U P D 2
 C84A C -0.384(3) 1.007(3) 0.523(3) 0.102(9) Uani 0.175(7) 1 d D U P D 2
 H84D H -0.384120 1.056196 0.555950 0.153 Uiso 0.175(7) 1 d R U P D 2
 H84E H -0.409820 1.033486 0.477351 0.153 Uiso 0.175(7) 1 d R U P D 2
 H84F H -0.429120 0.972386 0.555950 0.153 Uiso 0.175(7) 1 d R U P D 2
 H1 H 0.400(6) 0.458(5) 0.280(3) 0.123 Uiso 1 1 d D U . E 1


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 Ge1 N1 1.842(3) . ?
 Ge1 H1 1.47(2) . ?
 Si1 H1A 1.44(4) . ?
 Si1 H1B 1.34(4) . ?
 Si1 N1 1.733(3) . ?
 Si1 C73 1.865(4) . ?
 N1 C1 1.468(4) . ?
 C1 C2 1.411(4) . ?
 C1 C6 1.402(4) . ?
 C2 C3 1.395(4) . ?
 C2 C44 1.527(4) . ?
 C3 C4 1.385(4) . ?
 C3 C8 1.522(4) . ?
 C4 H4 0.9500 . ?
 C4 C5 1.390(4) . ?
 C5 C6 1.402(4) . ?
 C5 C12 1.516(4) . ?
 C6 C15 1.530(4) . ?
 C7 H7A 0.9900 . ?
 C7 H7B 0.9900 . ?
 C7 C8 1.547(4) . ?
 C7 C44 1.576(4) . ?
 C8 C9 1.532(5) . ?
 C8 C10 1.533(4) . ?
 C9 H9A 0.9800 . ?
 C9 H9B 0.9800 . ?
 C9 H9C 0.9800 . ?
 C10 H10A 0.9800 . ?
 C10 H10B 0.9800 . ?
 C10 H10C 0.9800 . ?
 C11 H11A 0.9900 . ?
 C11 H11B 0.9900 . ?
 C11 C12 1.543(4) . ?
 C11 C15 1.572(4) . ?
 C12 C13 1.537(4) . ?
 C12 C14 1.533(4) . ?
 C13 H13A 0.9800 . ?
 C13 H13B 0.9800 . ?
 C13 H13C 0.9800 . ?
 C14 H14A 0.9800 . ?
 C14 H14B 0.9800 . ?
 C14 H14C 0.9800 . ?
 C15 C16 1.533(4) . ?
 C15 C27 1.531(4) . ?
 C16 C17 1.380(4) . ?
 C16 C21 1.401(4) . ?
 C17 H17 0.9500 . ?
 C17 C18 1.411(4) . ?
 C18 C19 1.406(5) . ?
 C18 C36 1.537(4) . ?
 C19 C20 1.402(4) . ?
 C19 C40 1.540(4) . ?
 C20 H20 0.9500 . ?
 C20 C21 1.386(4) . ?
 C21 C22 1.467(4) . ?
 C22 C23 1.384(4) . ?
 C22 C27 1.399(4) . ?
 C23 H23 0.9500 . ?
 C23 C24 1.402(4) . ?
 C24 C25 1.410(4) . ?
 C24 C32 1.540(4) . ?
 C25 C26 1.409(4) . ?
 C25 C28 1.538(4) . ?
 C26 H26 0.9500 . ?
 C26 C27 1.382(4) . ?
 C28 C29 1.522(5) . ?
 C28 C30 1.531(5) . ?
 C28 C31 1.539(4) . ?
 C29 H29A 0.9800 . ?
 C29 H29B 0.9800 . ?
 C29 H29C 0.9800 . ?
 C30 H30A 0.9800 . ?
 C30 H30B 0.9800 . ?
 C30 H30C 0.9800 . ?
 C31 H31A 0.9900 . ?
 C31 H31B 0.9900 . ?
 C31 C35 1.499(5) . ?
 C32 C33 1.533(5) . ?
 C32 C34 1.540(5) . ?
 C32 C35 1.524(5) . ?
 C33 H33A 0.9800 . ?
 C33 H33B 0.9800 . ?
 C33 H33C 0.9800 . ?
 C34 H34A 0.9800 . ?
 C34 H34B 0.9800 . ?
 C34 H34C 0.9800 . ?
 C35 H35A 0.9900 . ?
 C35 H35B 0.9900 . ?
 C36 C37 1.527(5) . ?
 C36 C38 1.542(6) . ?
 C36 C39 1.535(5) . ?
 C37 H37A 0.9800 . ?
 C37 H37B 0.9800 . ?
 C37 H37C 0.9800 . ?
 C38 H38A 0.9800 . ?
 C38 H38B 0.9800 . ?
 C38 H38C 0.9800 . ?
 C39 H39A 0.9900 . ?
 C39 H39B 0.9900 . ?
 C39 C43 1.488(6) . ?
 C40 C41 1.522(6) . ?
 C40 C42 1.533(5) . ?
 C40 C43 1.540(5) . ?
 C41 H41A 0.9800 . ?
 C41 H41B 0.9800 . ?
 C41 H41C 0.9800 . ?
 C42 H42A 0.9800 . ?
 C42 H42B 0.9800 . ?
 C42 H42C 0.9800 . ?
 C43 H43A 0.9900 . ?
 C43 H43B 0.9900 . ?
 C44 C45 1.527(4) . ?
 C44 C56 1.530(4) . ?
 C45 C46 1.385(4) . ?
 C45 C50 1.410(4) . ?
 C46 H46 0.9500 . ?
 C46 C47 1.413(5) . ?
 C47 C48 1.405(5) . ?
 C47 C57 1.537(4) . ?
 C48 C49 1.411(4) . ?
 C48 C61 1.534(4) . ?
 C49 H49 0.9500 . ?
 C49 C50 1.382(4) . ?
 C50 C51 1.462(4) . ?
 C51 C52 1.385(4) . ?
 C51 C56 1.394(4) . ?
 C52 H52 0.9500 . ?
 C52 C53 1.399(4) . ?
 C53 C54 1.408(4) . ?
 C53 C65 1.536(4) . ?
 C54 C55 1.405(4) . ?
 C54 C69 1.533(4) . ?
 C55 H55 0.9500 . ?
 C55 C56 1.378(4) . ?
 C57 C58 1.524(5) . ?
 C57 C59 1.539(5) . ?
 C57 C60 1.541(5) . ?
 C58 H58A 0.9800 . ?
 C58 H58B 0.9800 . ?
 C58 H58C 0.9800 . ?
 C59 H59A 0.9800 . ?
 C59 H59B 0.9800 . ?
 C59 H59C 0.9800 . ?
 C60 H60A 0.9900 . ?
 C60 H60B 0.9900 . ?
 C60 C64 1.503(5) . ?
 C61 C62 1.537(5) . ?
 C61 C63 1.538(5) . ?
 C61 C64 1.533(5) . ?
 C62 H62A 0.9800 . ?
 C62 H62B 0.9800 . ?
 C62 H62C 0.9800 . ?
 C63 H63A 0.9800 . ?
 C63 H63B 0.9800 . ?
 C63 H63C 0.9800 . ?
 C64 H64A 0.9900 . ?
 C64 H64B 0.9900 . ?
 C65 C66 1.533(5) . ?
 C65 C67 1.540(5) . ?
 C65 C68 1.537(5) . ?
 C66 H66A 0.9800 . ?
 C66 H66B 0.9800 . ?
 C66 H66C 0.9800 . ?
 C67 H67A 0.9800 . ?
 C67 H67B 0.9800 . ?
 C67 H67C 0.9800 . ?
 C68 H68A 0.9900 . ?
 C68 H68B 0.9900 . ?
 C68 C72 1.511(5) . ?
 C69 C70 1.535(5) . ?
 C69 C71 1.537(5) . ?
 C69 C72 1.539(4) . ?
 C70 H70A 0.9800 . ?
 C70 H70B 0.9800 . ?
 C70 H70C 0.9800 . ?
 C71 H71A 0.9800 . ?
 C71 H71B 0.9800 . ?
 C71 H71C 0.9800 . ?
 C72 H72A 0.9900 . ?
 C72 H72B 0.9900 . ?
 C73 C74 1.403(5) . ?
 C73 C78 1.390(5) . ?
 C74 H74 0.9500 . ?
 C74 C75 1.384(6) . ?
 C75 H75 0.9500 . ?
 C75 C76 1.385(6) . ?
 C76 H76 0.9500 . ?
 C76 C77 1.370(7) . ?
 C77 H77 0.9500 . ?
 C77 C78 1.395(6) . ?
 C78 H78 0.9500 . ?
 C79 H79A 0.9800 . ?
 C79 H79B 0.9800 . ?
 C79 H79C 0.9800 . ?
 C79 C80 1.497(11) . ?
 C80 H80A 0.9900 . ?
 C80 H80B 0.9900 . ?
 C80 C81 1.525(11) . ?
 C81 H81A 0.9900 . ?
 C81 H81B 0.9900 . ?
 C81 C82 1.488(9) . ?
 C82 H82A 0.9900 . ?
 C82 H82B 0.9900 . ?
 C82 C83 1.415(10) . ?
 C83 H83A 0.9900 . ?
 C83 H83B 0.9900 . ?
 C83 C84 1.547(12) . ?
 C84 H84A 0.9800 . ?
 C84 H84B 0.9800 . ?
 C84 H84C 0.9800 . ?
 C79A H79D 0.9800 . ?
 C79A H79E 0.9800 . ?
 C79A H79F 0.9800 . ?
 C79A C80A 1.498(15) . ?
 C80A H80C 0.9900 . ?
 C80A H80D 0.9900 . ?
 C80A C81A 1.526(14) . ?
 C81A H81C 0.9900 . ?
 C81A H81D 0.9900 . ?
 C81A C82A 1.485(13) . ?
 C82A H82C 0.9900 . ?
 C82A H82D 0.9900 . ?
 C82A C83A 1.406(14) . ?
 C83A H83C 0.9900 . ?
 C83A H83D 0.9900 . ?
 C83A C84A 1.546(15) . ?
 C84A H84D 0.9897 . ?
 C84A H84E 0.9687 . ?
 C84A H84F 0.9977 . ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 N1 Ge1 H1 102(3) . . ?
 H1A Si1 H1B 101(2) . . ?
 N1 Si1 H1A 114.5(16) . . ?
 N1 Si1 H1B 108.8(17) . . ?
 N1 Si1 C73 110.56(15) . . ?
 C73 Si1 H1A 105.2(16) . . ?
 C73 Si1 H1B 116.5(17) . . ?
 Si1 N1 Ge1 124.33(16) . . ?
 C1 N1 Ge1 115.16(19) . . ?
 C1 N1 Si1 118.5(2) . . ?
 C2 C1 N1 119.7(3) . . ?
 C6 C1 N1 122.4(3) . . ?
 C6 C1 C2 117.9(3) . . ?
 C1 C2 C44 127.5(3) . . ?
 C3 C2 C1 121.0(3) . . ?
 C3 C2 C44 111.3(2) . . ?
 C2 C3 C8 112.8(3) . . ?
 C4 C3 C2 120.7(3) . . ?
 C4 C3 C8 126.5(3) . . ?
 C3 C4 H4 120.6 . . ?
 C3 C4 C5 118.8(3) . . ?
 C5 C4 H4 120.6 . . ?
 C4 C5 C6 121.3(3) . . ?
 C4 C5 C12 126.0(3) . . ?
 C6 C5 C12 112.8(3) . . ?
 C1 C6 C5 120.2(3) . . ?
 C1 C6 C15 128.9(3) . . ?
 C5 C6 C15 111.0(3) . . ?
 H7A C7 H7B 108.3 . . ?
 C8 C7 H7A 109.9 . . ?
 C8 C7 H7B 109.9 . . ?
 C8 C7 C44 108.8(2) . . ?
 C44 C7 H7A 109.9 . . ?
 C44 C7 H7B 109.9 . . ?
 C3 C8 C7 102.5(2) . . ?
 C3 C8 C9 111.7(3) . . ?
 C3 C8 C10 111.2(2) . . ?
 C9 C8 C7 112.3(3) . . ?
 C9 C8 C10 108.5(3) . . ?
 C10 C8 C7 110.6(3) . . ?
 C8 C9 H9A 109.5 . . ?
 C8 C9 H9B 109.5 . . ?
 C8 C9 H9C 109.5 . . ?
 H9A C9 H9B 109.5 . . ?
 H9A C9 H9C 109.5 . . ?
 H9B C9 H9C 109.5 . . ?
 C8 C10 H10A 109.5 . . ?
 C8 C10 H10B 109.5 . . ?
 C8 C10 H10C 109.5 . . ?
 H10A C10 H10B 109.5 . . ?
 H10A C10 H10C 109.5 . . ?
 H10B C10 H10C 109.5 . . ?
 H11A C11 H11B 108.3 . . ?
 C12 C11 H11A 109.9 . . ?
 C12 C11 H11B 109.9 . . ?
 C12 C11 C15 109.0(2) . . ?
 C15 C11 H11A 109.9 . . ?
 C15 C11 H11B 109.9 . . ?
 C5 C12 C11 101.1(2) . . ?
 C5 C12 C13 110.9(2) . . ?
 C5 C12 C14 112.4(3) . . ?
 C13 C12 C11 112.9(3) . . ?
 C14 C12 C11 111.3(3) . . ?
 C14 C12 C13 108.1(3) . . ?
 C12 C13 H13A 109.5 . . ?
 C12 C13 H13B 109.5 . . ?
 C12 C13 H13C 109.5 . . ?
 H13A C13 H13B 109.5 . . ?
 H13A C13 H13C 109.5 . . ?
 H13B C13 H13C 109.5 . . ?
 C12 C14 H14A 109.5 . . ?
 C12 C14 H14B 109.5 . . ?
 C12 C14 H14C 109.5 . . ?
 H14A C14 H14B 109.5 . . ?
 H14A C14 H14C 109.5 . . ?
 H14B C14 H14C 109.5 . . ?
 C6 C15 C11 101.1(2) . . ?
 C6 C15 C16 117.5(2) . . ?
 C6 C15 C27 119.2(2) . . ?
 C16 C15 C11 110.8(2) . . ?
 C27 C15 C11 107.5(2) . . ?
 C27 C15 C16 100.6(2) . . ?
 C17 C16 C15 130.7(3) . . ?
 C17 C16 C21 118.9(3) . . ?
 C21 C16 C15 110.3(2) . . ?
 C16 C17 H17 119.4 . . ?
 C16 C17 C18 121.3(3) . . ?
 C18 C17 H17 119.4 . . ?
 C17 C18 C36 118.2(3) . . ?
 C19 C18 C17 119.3(3) . . ?
 C19 C18 C36 122.5(3) . . ?
 C18 C19 C40 123.4(3) . . ?
 C20 C19 C18 118.9(3) . . ?
 C20 C19 C40 117.6(3) . . ?
 C19 C20 H20 119.6 . . ?
 C21 C20 C19 120.7(3) . . ?
 C21 C20 H20 119.6 . . ?
 C16 C21 C22 108.6(3) . . ?
 C20 C21 C16 120.6(3) . . ?
 C20 C21 C22 130.8(3) . . ?
 C23 C22 C21 131.0(3) . . ?
 C23 C22 C27 120.5(3) . . ?
 C27 C22 C21 108.5(2) . . ?
 C22 C23 H23 119.5 . . ?
 C22 C23 C24 121.0(3) . . ?
 C24 C23 H23 119.5 . . ?
 C23 C24 C25 118.8(3) . . ?
 C23 C24 C32 118.1(3) . . ?
 C25 C24 C32 123.1(3) . . ?
 C24 C25 C28 122.2(3) . . ?
 C26 C25 C24 119.2(3) . . ?
 C26 C25 C28 118.5(3) . . ?
 C25 C26 H26 119.3 . . ?
 C27 C26 C25 121.3(3) . . ?
 C27 C26 H26 119.3 . . ?
 C22 C27 C15 110.6(2) . . ?
 C26 C27 C15 130.1(3) . . ?
 C26 C27 C22 119.1(3) . . ?
 C25 C28 C31 110.4(3) . . ?
 C29 C28 C25 111.2(3) . . ?
 C29 C28 C30 109.7(3) . . ?
 C29 C28 C31 106.5(3) . . ?
 C30 C28 C25 109.5(3) . . ?
 C30 C28 C31 109.6(3) . . ?
 C28 C29 H29A 109.5 . . ?
 C28 C29 H29B 109.5 . . ?
 C28 C29 H29C 109.5 . . ?
 H29A C29 H29B 109.5 . . ?
 H29A C29 H29C 109.5 . . ?
 H29B C29 H29C 109.5 . . ?
 C28 C30 H30A 109.5 . . ?
 C28 C30 H30B 109.5 . . ?
 C28 C30 H30C 109.5 . . ?
 H30A C30 H30B 109.5 . . ?
 H30A C30 H30C 109.5 . . ?
 H30B C30 H30C 109.5 . . ?
 C28 C31 H31A 109.0 . . ?
 C28 C31 H31B 109.0 . . ?
 H31A C31 H31B 107.8 . . ?
 C35 C31 C28 113.0(3) . . ?
 C35 C31 H31A 109.0 . . ?
 C35 C31 H31B 109.0 . . ?
 C33 C32 C24 109.1(3) . . ?
 C33 C32 C34 108.0(3) . . ?
 C34 C32 C24 111.1(3) . . ?
 C35 C32 C24 110.7(3) . . ?
 C35 C32 C33 111.9(3) . . ?
 C35 C32 C34 106.0(3) . . ?
 C32 C33 H33A 109.5 . . ?
 C32 C33 H33B 109.5 . . ?
 C32 C33 H33C 109.5 . . ?
 H33A C33 H33B 109.5 . . ?
 H33A C33 H33C 109.5 . . ?
 H33B C33 H33C 109.5 . . ?
 C32 C34 H34A 109.5 . . ?
 C32 C34 H34B 109.5 . . ?
 C32 C34 H34C 109.5 . . ?
 H34A C34 H34B 109.5 . . ?
 H34A C34 H34C 109.5 . . ?
 H34B C34 H34C 109.5 . . ?
 C31 C35 C32 112.7(3) . . ?
 C31 C35 H35A 109.0 . . ?
 C31 C35 H35B 109.0 . . ?
 C32 C35 H35A 109.0 . . ?
 C32 C35 H35B 109.0 . . ?
 H35A C35 H35B 107.8 . . ?
 C18 C36 C38 109.2(3) . . ?
 C37 C36 C18 111.0(3) . . ?
 C37 C36 C38 109.0(4) . . ?
 C37 C36 C39 107.7(3) . . ?
 C39 C36 C18 110.2(3) . . ?
 C39 C36 C38 109.8(3) . . ?
 C36 C37 H37A 109.5 . . ?
 C36 C37 H37B 109.5 . . ?
 C36 C37 H37C 109.5 . . ?
 H37A C37 H37B 109.5 . . ?
 H37A C37 H37C 109.5 . . ?
 H37B C37 H37C 109.5 . . ?
 C36 C38 H38A 109.5 . . ?
 C36 C38 H38B 109.5 . . ?
 C36 C38 H38C 109.5 . . ?
 H38A C38 H38B 109.5 . . ?
 H38A C38 H38C 109.5 . . ?
 H38B C38 H38C 109.5 . . ?
 C36 C39 H39A 108.8 . . ?
 C36 C39 H39B 108.8 . . ?
 H39A C39 H39B 107.7 . . ?
 C43 C39 C36 113.6(3) . . ?
 C43 C39 H39A 108.8 . . ?
 C43 C39 H39B 108.8 . . ?
 C41 C40 C19 110.5(3) . . ?
 C41 C40 C42 108.5(4) . . ?
 C41 C40 C43 111.0(3) . . ?
 C42 C40 C19 109.9(3) . . ?
 C42 C40 C43 106.6(3) . . ?
 C43 C40 C19 110.2(3) . . ?
 C40 C41 H41A 109.5 . . ?
 C40 C41 H41B 109.5 . . ?
 C40 C41 H41C 109.5 . . ?
 H41A C41 H41B 109.5 . . ?
 H41A C41 H41C 109.5 . . ?
 H41B C41 H41C 109.5 . . ?
 C40 C42 H42A 109.5 . . ?
 C40 C42 H42B 109.5 . . ?
 C40 C42 H42C 109.5 . . ?
 H42A C42 H42B 109.5 . . ?
 H42A C42 H42C 109.5 . . ?
 H42B C42 H42C 109.5 . . ?
 C39 C43 C40 113.3(3) . . ?
 C39 C43 H43A 108.9 . . ?
 C39 C43 H43B 108.9 . . ?
 C40 C43 H43A 108.9 . . ?
 C40 C43 H43B 108.9 . . ?
 H43A C43 H43B 107.7 . . ?
 C2 C44 C7 102.1(2) . . ?
 C2 C44 C45 120.6(2) . . ?
 C2 C44 C56 112.4(2) . . ?
 C45 C44 C7 108.9(2) . . ?
 C45 C44 C56 100.5(2) . . ?
 C56 C44 C7 112.8(2) . . ?
 C46 C45 C44 129.4(3) . . ?
 C46 C45 C50 119.4(3) . . ?
 C50 C45 C44 110.6(2) . . ?
 C45 C46 H46 119.6 . . ?
 C45 C46 C47 120.9(3) . . ?
 C47 C46 H46 119.6 . . ?
 C46 C47 C57 118.4(3) . . ?
 C48 C47 C46 119.6(3) . . ?
 C48 C47 C57 122.0(3) . . ?
 C47 C48 C49 118.9(3) . . ?
 C47 C48 C61 123.8(3) . . ?
 C49 C48 C61 117.3(3) . . ?
 C48 C49 H49 119.5 . . ?
 C50 C49 C48 121.0(3) . . ?
 C50 C49 H49 119.5 . . ?
 C45 C50 C51 108.7(3) . . ?
 C49 C50 C45 120.2(3) . . ?
 C49 C50 C51 131.0(3) . . ?
 C52 C51 C50 131.5(3) . . ?
 C52 C51 C56 120.2(3) . . ?
 C56 C51 C50 108.2(3) . . ?
 C51 C52 H52 119.7 . . ?
 C51 C52 C53 120.6(3) . . ?
 C53 C52 H52 119.7 . . ?
 C52 C53 C54 119.1(3) . . ?
 C52 C53 C65 118.4(3) . . ?
 C54 C53 C65 122.5(3) . . ?
 C53 C54 C69 123.5(3) . . ?
 C55 C54 C53 119.3(3) . . ?
 C55 C54 C69 117.2(3) . . ?
 C54 C55 H55 119.7 . . ?
 C56 C55 C54 120.6(3) . . ?
 C56 C55 H55 119.7 . . ?
 C51 C56 C44 111.6(2) . . ?
 C55 C56 C44 128.5(3) . . ?
 C55 C56 C51 119.9(3) . . ?
 C47 C57 C59 111.5(3) . . ?
 C47 C57 C60 109.4(3) . . ?
 C58 C57 C47 109.0(3) . . ?
 C58 C57 C59 108.4(3) . . ?
 C58 C57 C60 111.3(3) . . ?
 C59 C57 C60 107.3(3) . . ?
 C57 C58 H58A 109.5 . . ?
 C57 C58 H58B 109.5 . . ?
 C57 C58 H58C 109.5 . . ?
 H58A C58 H58B 109.5 . . ?
 H58A C58 H58C 109.5 . . ?
 H58B C58 H58C 109.5 . . ?
 C57 C59 H59A 109.5 . . ?
 C57 C59 H59B 109.5 . . ?
 C57 C59 H59C 109.5 . . ?
 H59A C59 H59B 109.5 . . ?
 H59A C59 H59C 109.5 . . ?
 H59B C59 H59C 109.5 . . ?
 C57 C60 H60A 109.2 . . ?
 C57 C60 H60B 109.2 . . ?
 H60A C60 H60B 107.9 . . ?
 C64 C60 C57 112.3(3) . . ?
 C64 C60 H60A 109.2 . . ?
 C64 C60 H60B 109.2 . . ?
 C48 C61 C62 110.2(3) . . ?
 C48 C61 C63 109.0(3) . . ?
 C62 C61 C63 109.3(3) . . ?
 C64 C61 C48 111.0(3) . . ?
 C64 C61 C62 107.8(3) . . ?
 C64 C61 C63 109.5(3) . . ?
 C61 C62 H62A 109.5 . . ?
 C61 C62 H62B 109.5 . . ?
 C61 C62 H62C 109.5 . . ?
 H62A C62 H62B 109.5 . . ?
 H62A C62 H62C 109.5 . . ?
 H62B C62 H62C 109.5 . . ?
 C61 C63 H63A 109.5 . . ?
 C61 C63 H63B 109.5 . . ?
 C61 C63 H63C 109.5 . . ?
 H63A C63 H63B 109.5 . . ?
 H63A C63 H63C 109.5 . . ?
 H63B C63 H63C 109.5 . . ?
 C60 C64 C61 112.7(3) . . ?
 C60 C64 H64A 109.0 . . ?
 C60 C64 H64B 109.0 . . ?
 C61 C64 H64A 109.0 . . ?
 C61 C64 H64B 109.0 . . ?
 H64A C64 H64B 107.8 . . ?
 C53 C65 C67 109.9(3) . . ?
 C53 C65 C68 110.5(3) . . ?
 C66 C65 C53 109.4(3) . . ?
 C66 C65 C67 109.2(3) . . ?
 C66 C65 C68 110.5(3) . . ?
 C68 C65 C67 107.3(3) . . ?
 C65 C66 H66A 109.5 . . ?
 C65 C66 H66B 109.5 . . ?
 C65 C66 H66C 109.5 . . ?
 H66A C66 H66B 109.5 . . ?
 H66A C66 H66C 109.5 . . ?
 H66B C66 H66C 109.5 . . ?
 C65 C67 H67A 109.5 . . ?
 C65 C67 H67B 109.5 . . ?
 C65 C67 H67C 109.5 . . ?
 H67A C67 H67B 109.5 . . ?
 H67A C67 H67C 109.5 . . ?
 H67B C67 H67C 109.5 . . ?
 C65 C68 H68A 109.1 . . ?
 C65 C68 H68B 109.1 . . ?
 H68A C68 H68B 107.9 . . ?
 C72 C68 C65 112.3(3) . . ?
 C72 C68 H68A 109.1 . . ?
 C72 C68 H68B 109.1 . . ?
 C54 C69 C70 110.1(3) . . ?
 C54 C69 C71 108.5(3) . . ?
 C54 C69 C72 110.1(3) . . ?
 C70 C69 C71 109.3(3) . . ?
 C70 C69 C72 107.8(3) . . ?
 C71 C69 C72 111.0(3) . . ?
 C69 C70 H70A 109.5 . . ?
 C69 C70 H70B 109.5 . . ?
 C69 C70 H70C 109.5 . . ?
 H70A C70 H70B 109.5 . . ?
 H70A C70 H70C 109.5 . . ?
 H70B C70 H70C 109.5 . . ?
 C69 C71 H71A 109.5 . . ?
 C69 C71 H71B 109.5 . . ?
 C69 C71 H71C 109.5 . . ?
 H71A C71 H71B 109.5 . . ?
 H71A C71 H71C 109.5 . . ?
 H71B C71 H71C 109.5 . . ?
 C68 C72 C69 112.5(3) . . ?
 C68 C72 H72A 109.1 . . ?
 C68 C72 H72B 109.1 . . ?
 C69 C72 H72A 109.1 . . ?
 C69 C72 H72B 109.1 . . ?
 H72A C72 H72B 107.8 . . ?
 C74 C73 Si1 123.8(3) . . ?
 C78 C73 Si1 118.8(3) . . ?
 C78 C73 C74 117.3(3) . . ?
 C73 C74 H74 119.2 . . ?
 C75 C74 C73 121.6(4) . . ?
 C75 C74 H74 119.2 . . ?
 C74 C75 H75 120.2 . . ?
 C74 C75 C76 119.6(4) . . ?
 C76 C75 H75 120.2 . . ?
 C75 C76 H76 119.9 . . ?
 C77 C76 C75 120.2(4) . . ?
 C77 C76 H76 119.9 . . ?
 C76 C77 H77 120.0 . . ?
 C76 C77 C78 120.1(4) . . ?
 C78 C77 H77 120.0 . . ?
 C73 C78 C77 121.2(4) . . ?
 C73 C78 H78 119.4 . . ?
 C77 C78 H78 119.4 . . ?
 H79A C79 H79B 109.5 . . ?
 H79A C79 H79C 109.5 . . ?
 H79B C79 H79C 109.5 . . ?
 C80 C79 H79A 109.5 . . ?
 C80 C79 H79B 109.5 . . ?
 C80 C79 H79C 109.5 . . ?
 C79 C80 H80A 108.8 . . ?
 C79 C80 H80B 108.8 . . ?
 C79 C80 C81 113.7(6) . . ?
 H80A C80 H80B 107.7 . . ?
 C81 C80 H80A 108.8 . . ?
 C81 C80 H80B 108.8 . . ?
 C80 C81 H81A 109.4 . . ?
 C80 C81 H81B 109.4 . . ?
 H81A C81 H81B 108.0 . . ?
 C82 C81 C80 111.3(6) . . ?
 C82 C81 H81A 109.4 . . ?
 C82 C81 H81B 109.4 . . ?
 C81 C82 H82A 108.7 . . ?
 C81 C82 H82B 108.7 . . ?
 H82A C82 H82B 107.6 . . ?
 C83 C82 C81 114.1(7) . . ?
 C83 C82 H82A 108.7 . . ?
 C83 C82 H82B 108.7 . . ?
 C82 C83 H83A 108.0 . . ?
 C82 C83 H83B 108.0 . . ?
 C82 C83 C84 117.3(8) . . ?
 H83A C83 H83B 107.2 . . ?
 C84 C83 H83A 108.0 . . ?
 C84 C83 H83B 108.0 . . ?
 C83 C84 H84A 109.5 . . ?
 C83 C84 H84B 109.5 . . ?
 C83 C84 H84C 109.5 . . ?
 H84A C84 H84B 109.5 . . ?
 H84A C84 H84C 109.5 . . ?
 H84B C84 H84C 109.5 . . ?
 H79D C79A H79E 109.5 . . ?
 H79D C79A H79F 109.5 . . ?
 H79E C79A H79F 109.5 . . ?
 C80A C79A H79D 109.5 . . ?
 C80A C79A H79E 109.5 . . ?
 C80A C79A H79F 109.5 . . ?
 C79A C80A H80C 108.7 . . ?
 C79A C80A H80D 108.7 . . ?
 C79A C80A C81A 114.2(15) . . ?
 H80C C80A H80D 107.6 . . ?
 C81A C80A H80C 108.7 . . ?
 C81A C80A H80D 108.7 . . ?
 C80A C81A H81C 109.5 . . ?
 C80A C81A H81D 109.5 . . ?
 H81C C81A H81D 108.1 . . ?
 C82A C81A C80A 110.8(15) . . ?
 C82A C81A H81C 109.5 . . ?
 C82A C81A H81D 109.5 . . ?
 C81A C82A H82C 107.5 . . ?
 C81A C82A H82D 107.5 . . ?
 H82C C82A H82D 107.0 . . ?
 C83A C82A C81A 119.1(18) . . ?
 C83A C82A H82C 107.5 . . ?
 C83A C82A H82D 107.5 . . ?
 C82A C83A H83C 107.8 . . ?
 C82A C83A H83D 107.8 . . ?
 C82A C83A C84A 118.2(18) . . ?
 H83C C83A H83D 107.1 . . ?
 C84A C83A H83C 107.8 . . ?
 C84A C83A H83D 107.8 . . ?
 C83A C84A H84D 112.0 . . ?
 C83A C84A H84E 109.7 . . ?
 C83A C84A H84F 109.3 . . ?
 H84D C84A H84E 109.6 . . ?
 H84D C84A H84F 107.2 . . ?
 H84E C84A H84F 108.9 . . ?

loop_
  _geom_torsion_atom_site_label_1
  _geom_torsion_atom_site_label_2
  _geom_torsion_atom_site_label_3
  _geom_torsion_atom_site_label_4
  _geom_torsion
  _geom_torsion_site_symmetry_1
  _geom_torsion_site_symmetry_2
  _geom_torsion_site_symmetry_3
  _geom_torsion_site_symmetry_4
  _geom_torsion_publ_flag
 Ge1 N1 C1 C2 -70.7(3) . . . . ?
 Ge1 N1 C1 C6 108.6(3) . . . . ?
 Si1 N1 C1 C2 94.1(3) . . . . ?
 Si1 N1 C1 C6 -86.7(3) . . . . ?
 Si1 C73 C74 C75 174.0(3) . . . . ?
 Si1 C73 C78 C77 -175.0(3) . . . . ?
 N1 Si1 C73 C74 10.0(4) . . . . ?
 N1 Si1 C73 C78 -175.0(3) . . . . ?
 N1 C1 C2 C3 -177.5(3) . . . . ?
 N1 C1 C2 C44 -2.9(4) . . . . ?
 N1 C1 C6 C5 176.7(3) . . . . ?
 N1 C1 C6 C15 -3.7(5) . . . . ?
 C1 C2 C3 C4 0.1(4) . . . . ?
 C1 C2 C3 C8 179.2(3) . . . . ?
 C1 C2 C44 C7 172.8(3) . . . . ?
 C1 C2 C44 C45 52.1(4) . . . . ?
 C1 C2 C44 C56 -66.1(4) . . . . ?
 C1 C6 C15 C11 -167.8(3) . . . . ?
 C1 C6 C15 C16 71.5(4) . . . . ?
 C1 C6 C15 C27 -50.4(4) . . . . ?
 C2 C1 C6 C5 -4.1(4) . . . . ?
 C2 C1 C6 C15 175.5(3) . . . . ?
 C2 C3 C4 C5 -2.6(4) . . . . ?
 C2 C3 C8 C7 6.6(3) . . . . ?
 C2 C3 C8 C9 -113.9(3) . . . . ?
 C2 C3 C8 C10 124.7(3) . . . . ?
 C2 C44 C45 C46 58.6(4) . . . . ?
 C2 C44 C45 C50 -130.3(3) . . . . ?
 C2 C44 C56 C51 134.9(3) . . . . ?
 C2 C44 C56 C55 -45.9(4) . . . . ?
 C3 C2 C44 C7 -12.2(3) . . . . ?
 C3 C2 C44 C45 -132.9(3) . . . . ?
 C3 C2 C44 C56 108.9(3) . . . . ?
 C3 C4 C5 C6 1.8(4) . . . . ?
 C3 C4 C5 C12 -178.1(3) . . . . ?
 C4 C3 C8 C7 -174.4(3) . . . . ?
 C4 C3 C8 C9 65.1(4) . . . . ?
 C4 C3 C8 C10 -56.3(4) . . . . ?
 C4 C5 C6 C1 1.6(4) . . . . ?
 C4 C5 C6 C15 -178.0(3) . . . . ?
 C4 C5 C12 C11 165.0(3) . . . . ?
 C4 C5 C12 C13 -75.0(4) . . . . ?
 C4 C5 C12 C14 46.2(4) . . . . ?
 C5 C6 C15 C11 11.8(3) . . . . ?
 C5 C6 C15 C16 -108.8(3) . . . . ?
 C5 C6 C15 C27 129.2(3) . . . . ?
 C6 C1 C2 C3 3.2(4) . . . . ?
 C6 C1 C2 C44 177.8(3) . . . . ?
 C6 C5 C12 C11 -14.9(3) . . . . ?
 C6 C5 C12 C13 105.2(3) . . . . ?
 C6 C5 C12 C14 -133.6(3) . . . . ?
 C6 C15 C16 C17 40.5(5) . . . . ?
 C6 C15 C16 C21 -142.5(3) . . . . ?
 C6 C15 C27 C22 141.3(3) . . . . ?
 C6 C15 C27 C26 -44.5(4) . . . . ?
 C7 C44 C45 C46 -58.7(4) . . . . ?
 C7 C44 C45 C50 112.4(3) . . . . ?
 C7 C44 C56 C51 -110.4(3) . . . . ?
 C7 C44 C56 C55 68.9(4) . . . . ?
 C8 C3 C4 C5 178.5(3) . . . . ?
 C8 C7 C44 C2 16.1(3) . . . . ?
 C8 C7 C44 C45 144.6(2) . . . . ?
 C8 C7 C44 C56 -104.7(3) . . . . ?
 C11 C15 C16 C17 -74.9(4) . . . . ?
 C11 C15 C16 C21 102.0(3) . . . . ?
 C11 C15 C27 C22 -104.7(3) . . . . ?
 C11 C15 C27 C26 69.5(4) . . . . ?
 C12 C5 C6 C1 -178.5(3) . . . . ?
 C12 C5 C6 C15 1.8(3) . . . . ?
 C12 C11 C15 C6 -21.2(3) . . . . ?
 C12 C11 C15 C16 104.1(3) . . . . ?
 C12 C11 C15 C27 -146.9(2) . . . . ?
 C15 C11 C12 C5 22.1(3) . . . . ?
 C15 C11 C12 C13 -96.5(3) . . . . ?
 C15 C11 C12 C14 141.7(3) . . . . ?
 C15 C16 C17 C18 173.0(3) . . . . ?
 C15 C16 C21 C20 -172.5(3) . . . . ?
 C15 C16 C21 C22 7.9(3) . . . . ?
 C16 C15 C27 C22 11.3(3) . . . . ?
 C16 C15 C27 C26 -174.6(3) . . . . ?
 C16 C17 C18 C19 -0.9(5) . . . . ?
 C16 C17 C18 C36 180.0(3) . . . . ?
 C16 C21 C22 C23 178.6(3) . . . . ?
 C16 C21 C22 C27 -0.3(3) . . . . ?
 C17 C16 C21 C20 4.9(5) . . . . ?
 C17 C16 C21 C22 -174.8(3) . . . . ?
 C17 C18 C19 C20 4.5(5) . . . . ?
 C17 C18 C19 C40 -175.3(3) . . . . ?
 C17 C18 C36 C37 -49.3(5) . . . . ?
 C17 C18 C36 C38 70.9(4) . . . . ?
 C17 C18 C36 C39 -168.5(3) . . . . ?
 C18 C19 C20 C21 -3.4(5) . . . . ?
 C18 C19 C40 C41 -112.4(4) . . . . ?
 C18 C19 C40 C42 127.9(4) . . . . ?
 C18 C19 C40 C43 10.7(5) . . . . ?
 C18 C36 C39 C43 -44.7(5) . . . . ?
 C19 C18 C36 C37 131.7(4) . . . . ?
 C19 C18 C36 C38 -108.2(4) . . . . ?
 C19 C18 C36 C39 12.5(5) . . . . ?
 C19 C20 C21 C16 -1.3(5) . . . . ?
 C19 C20 C21 C22 178.2(3) . . . . ?
 C19 C40 C43 C39 -42.6(5) . . . . ?
 C20 C19 C40 C41 67.9(4) . . . . ?
 C20 C19 C40 C42 -51.9(4) . . . . ?
 C20 C19 C40 C43 -169.1(3) . . . . ?
 C20 C21 C22 C23 -1.0(6) . . . . ?
 C20 C21 C22 C27 -179.9(3) . . . . ?
 C21 C16 C17 C18 -3.7(5) . . . . ?
 C21 C22 C23 C24 -178.0(3) . . . . ?
 C21 C22 C27 C15 -7.4(3) . . . . ?
 C21 C22 C27 C26 177.7(3) . . . . ?
 C22 C23 C24 C25 1.3(5) . . . . ?
 C22 C23 C24 C32 179.8(3) . . . . ?
 C23 C22 C27 C15 173.6(3) . . . . ?
 C23 C22 C27 C26 -1.3(4) . . . . ?
 C23 C24 C25 C26 -2.8(4) . . . . ?
 C23 C24 C25 C28 178.2(3) . . . . ?
 C23 C24 C32 C33 -68.9(4) . . . . ?
 C23 C24 C32 C34 50.1(4) . . . . ?
 C23 C24 C32 C35 167.5(3) . . . . ?
 C24 C25 C26 C27 2.4(5) . . . . ?
 C24 C25 C28 C29 -132.8(3) . . . . ?
 C24 C25 C28 C30 105.8(4) . . . . ?
 C24 C25 C28 C31 -14.9(4) . . . . ?
 C24 C32 C35 C31 44.6(4) . . . . ?
 C25 C24 C32 C33 109.6(3) . . . . ?
 C25 C24 C32 C34 -131.4(3) . . . . ?
 C25 C24 C32 C35 -14.0(4) . . . . ?
 C25 C26 C27 C15 -174.0(3) . . . . ?
 C25 C26 C27 C22 -0.3(5) . . . . ?
 C25 C28 C31 C35 45.7(4) . . . . ?
 C26 C25 C28 C29 48.1(4) . . . . ?
 C26 C25 C28 C30 -73.2(4) . . . . ?
 C26 C25 C28 C31 166.1(3) . . . . ?
 C27 C15 C16 C17 171.6(3) . . . . ?
 C27 C15 C16 C21 -11.4(3) . . . . ?
 C27 C22 C23 C24 0.8(5) . . . . ?
 C28 C25 C26 C27 -178.6(3) . . . . ?
 C28 C31 C35 C32 -63.5(4) . . . . ?
 C29 C28 C31 C35 166.5(3) . . . . ?
 C30 C28 C31 C35 -74.9(4) . . . . ?
 C32 C24 C25 C26 178.7(3) . . . . ?
 C32 C24 C25 C28 -0.3(5) . . . . ?
 C33 C32 C35 C31 -77.3(4) . . . . ?
 C34 C32 C35 C31 165.1(3) . . . . ?
 C36 C18 C19 C20 -176.5(3) . . . . ?
 C36 C18 C19 C40 3.8(5) . . . . ?
 C36 C39 C43 C40 62.7(5) . . . . ?
 C37 C36 C39 C43 -165.9(4) . . . . ?
 C38 C36 C39 C43 75.5(4) . . . . ?
 C40 C19 C20 C21 176.4(3) . . . . ?
 C41 C40 C43 C39 80.2(4) . . . . ?
 C42 C40 C43 C39 -161.8(4) . . . . ?
 C44 C2 C3 C4 -175.2(3) . . . . ?
 C44 C2 C3 C8 3.8(3) . . . . ?
 C44 C7 C8 C3 -14.1(3) . . . . ?
 C44 C7 C8 C9 105.9(3) . . . . ?
 C44 C7 C8 C10 -132.7(3) . . . . ?
 C44 C45 C46 C47 171.3(3) . . . . ?
 C44 C45 C50 C49 -172.1(3) . . . . ?
 C44 C45 C50 C51 5.2(3) . . . . ?
 C45 C44 C56 C51 5.5(3) . . . . ?
 C45 C44 C56 C55 -175.3(3) . . . . ?
 C45 C46 C47 C48 -2.5(5) . . . . ?
 C45 C46 C47 C57 179.8(3) . . . . ?
 C45 C50 C51 C52 175.8(3) . . . . ?
 C45 C50 C51 C56 -1.5(3) . . . . ?
 C46 C45 C50 C49 0.0(4) . . . . ?
 C46 C45 C50 C51 177.3(3) . . . . ?
 C46 C47 C48 C49 3.0(5) . . . . ?
 C46 C47 C48 C61 -176.1(3) . . . . ?
 C46 C47 C57 C58 74.2(4) . . . . ?
 C46 C47 C57 C59 -45.4(4) . . . . ?
 C46 C47 C57 C60 -163.9(3) . . . . ?
 C47 C48 C49 C50 -2.1(5) . . . . ?
 C47 C48 C61 C62 128.3(3) . . . . ?
 C47 C48 C61 C63 -111.8(4) . . . . ?
 C47 C48 C61 C64 8.9(5) . . . . ?
 C47 C57 C60 C64 -50.0(4) . . . . ?
 C48 C47 C57 C58 -103.6(4) . . . . ?
 C48 C47 C57 C59 136.8(3) . . . . ?
 C48 C47 C57 C60 18.4(4) . . . . ?
 C48 C49 C50 C45 0.6(5) . . . . ?
 C48 C49 C50 C51 -175.9(3) . . . . ?
 C48 C61 C64 C60 -40.5(4) . . . . ?
 C49 C48 C61 C62 -50.9(4) . . . . ?
 C49 C48 C61 C63 69.0(4) . . . . ?
 C49 C48 C61 C64 -170.2(3) . . . . ?
 C49 C50 C51 C52 -7.4(6) . . . . ?
 C49 C50 C51 C56 175.4(3) . . . . ?
 C50 C45 C46 C47 0.9(4) . . . . ?
 C50 C51 C52 C53 -177.9(3) . . . . ?
 C50 C51 C56 C44 -2.8(3) . . . . ?
 C50 C51 C56 C55 177.9(3) . . . . ?
 C51 C52 C53 C54 -0.9(4) . . . . ?
 C51 C52 C53 C65 178.3(3) . . . . ?
 C52 C51 C56 C44 179.6(3) . . . . ?
 C52 C51 C56 C55 0.3(4) . . . . ?
 C52 C53 C54 C55 3.2(4) . . . . ?
 C52 C53 C54 C69 -177.3(3) . . . . ?
 C52 C53 C65 C66 71.4(4) . . . . ?
 C52 C53 C65 C67 -48.5(4) . . . . ?
 C52 C53 C65 C68 -166.7(3) . . . . ?
 C53 C54 C55 C56 -3.8(4) . . . . ?
 C53 C54 C69 C70 131.0(3) . . . . ?
 C53 C54 C69 C71 -109.4(4) . . . . ?
 C53 C54 C69 C72 12.3(4) . . . . ?
 C53 C65 C68 C72 -45.1(4) . . . . ?
 C54 C53 C65 C66 -109.4(3) . . . . ?
 C54 C53 C65 C67 130.7(3) . . . . ?
 C54 C53 C65 C68 12.5(4) . . . . ?
 C54 C55 C56 C44 -177.1(3) . . . . ?
 C54 C55 C56 C51 2.1(4) . . . . ?
 C54 C69 C72 C68 -44.9(4) . . . . ?
 C55 C54 C69 C70 -49.4(4) . . . . ?
 C55 C54 C69 C71 70.2(4) . . . . ?
 C55 C54 C69 C72 -168.1(3) . . . . ?
 C56 C44 C45 C46 -177.4(3) . . . . ?
 C56 C44 C45 C50 -6.3(3) . . . . ?
 C56 C51 C52 C53 -0.9(5) . . . . ?
 C57 C47 C48 C49 -179.3(3) . . . . ?
 C57 C47 C48 C61 1.6(5) . . . . ?
 C57 C60 C64 C61 64.0(4) . . . . ?
 C58 C57 C60 C64 70.5(4) . . . . ?
 C59 C57 C60 C64 -171.1(3) . . . . ?
 C61 C48 C49 C50 177.1(3) . . . . ?
 C62 C61 C64 C60 -161.2(3) . . . . ?
 C63 C61 C64 C60 79.9(4) . . . . ?
 C65 C53 C54 C55 -176.0(3) . . . . ?
 C65 C53 C54 C69 3.6(5) . . . . ?
 C65 C68 C72 C69 64.2(4) . . . . ?
 C66 C65 C68 C72 76.2(4) . . . . ?
 C67 C65 C68 C72 -164.9(3) . . . . ?
 C69 C54 C55 C56 176.6(3) . . . . ?
 C70 C69 C72 C68 -165.0(3) . . . . ?
 C71 C69 C72 C68 75.2(4) . . . . ?
 C73 Si1 N1 Ge1 -61.8(2) . . . . ?
 C73 Si1 N1 C1 135.0(2) . . . . ?
 C73 C74 C75 C76 1.2(6) . . . . ?
 C74 C73 C78 C77 0.3(6) . . . . ?
 C74 C75 C76 C77 -0.7(6) . . . . ?
 C75 C76 C77 C78 0.0(7) . . . . ?
 C76 C77 C78 C73 0.2(7) . . . . ?
 C78 C73 C74 C75 -1.0(6) . . . . ?
 C79 C80 C81 C82 70.0(8) . . . . ?
 C80 C81 C82 C83 -175.7(7) . . . . ?
 C81 C82 C83 C84 -171.1(9) . . . . ?
 C79A C80A C81A C82A -90(4) . . . . ?
 C80A C81A C82A C83A 161(4) . . . . ?
 C81A C82A C83A C84A 157(4) . . . . ?

_olex2_submission_special_instructions  'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
