data_6
_audit_creation_date               2025-06-08
_audit_creation_method
;
Olex2 1.5
(compiled 2024.02.16 svn.r378c4104 for OlexSys, GUI svn.r6928)
;
_shelx_SHELXL_version_number       '2019/3'
_audit_contact_author_address      ?
_audit_contact_author_email        ?
_audit_contact_author_name         ''
_audit_contact_author_phone        ?
_publ_contact_author_id_orcid      ?
_publ_section_references
;
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.
;
_chemical_name_common              ?
_chemical_name_systematic          ?
_chemical_formula_moiety           'C75 H98 Ge N4 Si, C6 H14'
_chemical_formula_sum              'C81 H112 Ge N4 Si'
_chemical_formula_weight           1242.42
_chemical_melting_point            ?
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'C' 'C' 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Ge' 'Ge' -1.0885 0.8855
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N' 'N' 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Si' 'Si' 0.2541 0.3302 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system        'triclinic'
_space_group_IT_number             2
_space_group_name_H-M_alt          'P -1'
_space_group_name_Hall             '-P 1'
loop_
  _space_group_symop_operation_xyz
 'x, y, z'
 '-x, -y, -z'

_cell_length_a                     13.4555(2)
_cell_length_b                     15.3862(2)
_cell_length_c                     18.4991(2)
_cell_angle_alpha                  93.3890(10)
_cell_angle_beta                   92.7760(10)
_cell_angle_gamma                  103.9750(10)
_cell_volume                       3702.21(8)
_cell_formula_units_Z              2
_cell_measurement_reflns_used      43710
_cell_measurement_temperature      150.00(10)
_cell_measurement_theta_max        76.5250
_cell_measurement_theta_min        2.3860
_shelx_estimated_absorpt_T_max     0.886
_shelx_estimated_absorpt_T_min     0.835
_exptl_absorpt_coefficient_mu      1.038
_exptl_absorpt_correction_T_max    1.00000
_exptl_absorpt_correction_T_min    0.94348
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.42.73a (Rigaku Oxford Diffraction, 2022)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details     ?
_exptl_crystal_colour              yellow
_exptl_crystal_colour_primary      yellow
_exptl_crystal_density_diffrn      1.115
_exptl_crystal_density_meas        ?
_exptl_crystal_density_method      ?
_exptl_crystal_description         block
_exptl_crystal_F_000               1344
_exptl_crystal_size_max            0.18
_exptl_crystal_size_mid            0.15
_exptl_crystal_size_min            0.12
_exptl_transmission_factor_max     ?
_exptl_transmission_factor_min     ?
_diffrn_reflns_av_R_equivalents    0.0366
_diffrn_reflns_av_unetI/netI       0.0340
_diffrn_reflns_Laue_measured_fraction_full  1.000
_diffrn_reflns_Laue_measured_fraction_max  0.978
_diffrn_reflns_limit_h_max         16
_diffrn_reflns_limit_h_min         -15
_diffrn_reflns_limit_k_max         18
_diffrn_reflns_limit_k_min         -19
_diffrn_reflns_limit_l_max         23
_diffrn_reflns_limit_l_min         -23
_diffrn_reflns_number              63863
_diffrn_reflns_point_group_measured_fraction_full  1.000
_diffrn_reflns_point_group_measured_fraction_max  0.978
_diffrn_reflns_theta_full          67.684
_diffrn_reflns_theta_max           76.751
_diffrn_reflns_theta_min           2.398
_diffrn_ambient_temperature        150.15
_diffrn_detector_area_resol_mean   10.0000
_diffrn_detector_type              HyPix
_diffrn_measured_fraction_theta_full  1.000
_diffrn_measured_fraction_theta_max  0.978
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
--------------------------------------------------------------------------
  1  ω    -25.00  26.00   0.50    0.06    --   48.13 -19.00 -60.00  102
  2  ω     20.00  62.00   0.50    0.06    --   48.13 -57.00   0.00   84
  3  ω    -22.00   4.00   0.50    0.06    --   48.13 -57.00   0.00   52
  4  ω    -17.00  10.00   0.50    0.06    --   48.13 -19.00  30.00   54
  5  ω     91.00 122.00   0.50    0.23    --  104.75  98.00  54.00   62
  6  ω    -25.00  29.00   0.50    0.06    --   48.13 -19.00-120.00  108
  7  ω     35.00  68.00   0.50    0.23    --  104.75 -61.00   0.00   66
  8  ω     18.00  76.00   0.50    0.06    --   48.13-125.00-150.00  116
  9  ω     33.00  71.00   0.50    0.23    --  104.75 -61.00-150.00   76
 10  ω    -22.00  74.00   0.50    0.06    --   48.13 -98.00 -53.00  192
 11  ω     34.00  75.00   0.50    0.23    --  104.75 -95.00   0.00   82
 12  ω     86.00 111.00   0.50    0.23    --  104.75-125.00  60.00   50
 13  ω     46.00 111.00   0.50    0.23    --  104.75-125.00  90.00  130
 14  ω     39.00  90.00   0.50    0.23    --  104.75-125.00 120.00  102
 15  ω     59.00 119.00   0.50    0.23    --  104.75-135.00 148.84  120
 16  ω     76.00 118.00   0.50    0.23    --  104.75-134.00  65.69   84
 17  ω     39.00  65.00   0.50    0.23    --  104.75-134.00  65.69   52
 18  ω     83.00 109.00   0.50    0.23    --  104.75-112.00 -57.23   52
 19  ω     70.00 106.00   0.50    0.23    --  104.75 -98.00 -53.00   72
 20  ω     33.00 105.00   0.50    0.23    --  104.75 -95.00-180.00  144
 21  ω     39.00  66.00   0.50    0.23    --  104.75-111.00 -98.84   54
 22  ω     38.00  85.00   0.50    0.23    --  104.75 -95.00 -90.00   94
 23  ω     33.00  98.00   0.50    0.23    --  104.75 -95.00-150.00  130
 24  ω     38.00  65.00   0.50    0.23    --  104.75 -98.00 -53.00   54
 25  ω     33.00  93.00   0.50    0.23    --  104.75 -95.00 -30.00  120
 26  ω     57.00  83.00   0.50    0.23    --  104.75 -95.00 120.00   52
 27  ω     50.00  97.00   0.50    0.23    --  104.75 -95.00 150.00   94
 28  ω     97.00 178.00   0.50    0.23    --  104.75  30.00 150.00  162
 29  ω     94.00 168.00   0.50    0.23    --  104.75  45.00  30.00  148
 30  ω     94.00 126.00   0.50    0.23    --  104.75  45.00 -30.00   64
 31  ω    144.00 170.00   0.50    0.23    --  104.75  45.00 -30.00   52
 32  ω    134.00 159.00   0.50    0.23    --  104.75  30.00-150.00   50
 33  ω    -68.00 -39.00   0.50    0.23    -- -104.00  61.00 -30.00   58
 34  ω    -62.00 -32.00   0.50    0.23    -- -104.00  61.00  60.00   60
 35  ω    -58.00 -33.00   0.50    0.23    -- -104.00  61.00 150.00   50
 36  ω    -78.00 -38.00   0.50    0.23    -- -104.00 113.00  90.12   80
 37  ω   -109.00 -76.00   0.50    0.23    -- -104.00 115.00  11.18   66
 38  ω    -75.00 -48.00   0.50    0.23    -- -104.00 109.00 122.50   54
 39  ω   -119.00 -93.00   0.50    0.23    -- -104.00 135.00 -93.66   52
 40  ω   -119.00 -60.00   0.50    0.23    -- -104.00 135.00-145.55  118
 41  ω    -65.00 -40.00   0.50    0.23    -- -104.00 112.00-161.98   50
 42  ω   -108.00 -70.00   0.50    0.23    -- -104.00 112.00-161.98   76
 43  ω    -66.00  22.00   0.50    0.06    --  -48.13  98.00  54.00  176
 44  ω    -69.00 -36.00   0.50    0.23    -- -104.00 108.00 160.79   66
 45  ω   -107.00 -82.00   0.50    0.23    -- -104.00 108.00 160.79   50
 46  ω   -108.00 -82.00   0.50    0.23    -- -104.00 109.00 122.50   52
 47  ω    -70.00 -45.00   0.50    0.23    -- -104.00  98.00  54.00   50
 48  ω   -126.00 -94.00   0.50    0.23    -- -104.00 -15.00  30.00   64
 49  ω   -133.00 -93.00   0.50    0.23    -- -104.00 -15.00 150.00   80
 50  ω   -175.00 -90.00   0.50    0.23    -- -104.00 -61.00   0.00  170
 51  ω   -175.00 -92.00   0.50    0.23    -- -104.00 -61.00 -30.00  166
 52  ω   -174.00-132.00   0.50    0.23    -- -104.00 -15.00 -60.00   84
 53  ω   -175.00 -93.00   0.50    0.23    -- -104.00 -15.00-120.00  164
 54  ω   -174.00-134.00   0.50    0.23    -- -104.00 -15.00-150.00   80
 55  ω   -137.00-112.00   0.50    0.23    -- -104.00 -98.00 -53.00   50
;
_diffrn_measurement_device         'four-circle diffractometer'
_diffrn_measurement_device_type    'XtaLAB Synergy R, DW system, HyPix'
_diffrn_measurement_method         'ω scans'
_diffrn_radiation_type             CuK\a
_diffrn_radiation_wavelength       1.54184
_diffrn_source                     ?
_reflns_Friedel_coverage           0.000
_reflns_Friedel_fraction_full      .
_reflns_Friedel_fraction_max       .
_reflns_number_gt                  13519
_reflns_number_total               15262
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression       'I > 2σ(I)'
_computing_cell_refinement         'CrysAlisPro 1.171.42.73a (Rigaku OD, 2022)'
_computing_data_collection         'CrysAlisPro 1.171.42.73a (Rigaku OD, 2022)'
_computing_data_reduction          'CrysAlisPro 1.171.42.73a (Rigaku OD, 2022)'
_computing_molecular_graphics      'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement    'SHELXL 2019/3 (Sheldrick, 2015)'
_computing_structure_solution      'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max           0.436
_refine_diff_density_min           -0.457
_refine_diff_density_rms           0.043
_refine_ls_extinction_coef         .
_refine_ls_extinction_method       none
_refine_ls_goodness_of_fit_ref     1.057
_refine_ls_hydrogen_treatment      constr
_refine_ls_matrix_type             full
_refine_ls_number_parameters       1143
_refine_ls_number_reflns           15262
_refine_ls_number_restraints       938
_refine_ls_R_factor_all            0.0444
_refine_ls_R_factor_gt             0.0398
_refine_ls_restrained_S_all        1.060
_refine_ls_shift/su_max            0.002
_refine_ls_shift/su_mean           0.000
_refine_ls_structure_factor_coef   Fsqd
_refine_ls_weighting_details      
 'w=1/[σ²(Fo²)+(0.0550P)²+1.1492P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme        calc
_refine_ls_wR_factor_gt            0.1067
_refine_ls_wR_factor_ref           0.1104
_refine_special_details           
 'In the structure, Ge-N4 moiety exhibit a positional disorder, they were separated using PART instruction and refined using a free variable (FVAR). SAME and RIGU instructions were applied make the shape, position and anisotropic displacement parameters in a reasonable range, the final occupancies of 0.8654(12):0.1346(12) have been determined for PART 1 and PART 2, respectively. C36 to C43, C57 to C64, C65 to C72 and n-hexane solvents (C81 to C86) groups also exhibit a positional disorder, they were separated using PART 1 and PART 2 instructions and refined using free variables (FVAR). SAME instruction was used to fix the disordered parts in reasonable shape and positions, RIGU and SIMU instruction to make the anisotropic displacement parameters of the disordered parts within reasonable limits. The occupancies of 0.656(5):0.344(5) for C36 to C43, 0.735(6):0.265(6) for C57 to C64, 0.133(5):0.867(5) for C65 to C72 and 0.243(5):0.757(5) for C81 to C86 have been determined for PART 1 and PART 2.'
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Uiso/Uaniso restraints and constraints
C81 \\sim C82 \\sim C83 \\sim C84 \\sim C85 \\sim C86 \\sim C81A \\sim C82A
\\sim C83A \\sim C84A \\sim C85A \\sim C86A: within 2A with sigma of 0.01 and
sigma for terminal atoms of 0.02 within 2A
C36 \\sim C37 \\sim C38 \\sim C39 \\sim C40 \\sim C41 \\sim C42 \\sim C43 \\sim
C57 \\sim C58 \\sim C59 \\sim C60 \\sim C61 \\sim C62 \\sim C63 \\sim C64 \\sim
C65 \\sim C66 \\sim C67 \\sim C68 \\sim C69 \\sim C70 \\sim C71 \\sim C72 \\sim
Ge1A \\sim N1A \\sim N2A \\sim N3A \\sim N4A \\sim C36A \\sim C37A \\sim C38A
\\sim C39A \\sim C40A \\sim C41A \\sim C42A \\sim C43A: within 2A with sigma of
0.01 and sigma for terminal atoms of 0.02 within 2A
3. Rigid body (RIGU) restrains
 C57, C58, C59, C60, C61, C62, C63, C64, C65, C66, C67, C68, C69, C70, C71,
 C72, Ge1A, N1A, N2A, N3A, N4A, C36A, C37A, C38A, C39A, C40A, C41A, C42A, C43A,
 C57A, C58A, C59A, C60A, C61A, C62A, C63A, C64A
 with sigma for 1-2 distances of 0.002 and sigma for 1-3 distances of 0.002
 C65, C66, C67, C68, C69, C70, C71, C72, Ge1A, N1A, N2A, N3A, N4A, C36A, C37A,
 C38A, C39A, C40A, C41A, C42A, C43A, C57A, C58A, C59A, C60A, C61A, C62A, C63A,
 C64A, C65A, C66A, C67A, C68A, C69A, C70A, C71A, C72A
 with sigma for 1-2 distances of 0.002 and sigma for 1-3 distances of 0.002
 C81, C82, C83, C84, C85, C86, C81A, C82A, C83A, C84A, C85A, C86A
 with sigma for 1-2 distances of 0.002 and sigma for 1-3 distances of 0.002
 C36, C37, C38, C39, C40, C41, C42, C43, C57, C58, C59, C60, C61, C62, C63,
 C64, C65, C66, C67, C68, C69, C70, C71, C72, Ge1A, N1A, N2A, N3A, N4A, C36A,
 C37A, C38A, C39A, C40A, C41A, C42A, C43A
 with sigma for 1-2 distances of 0.002 and sigma for 1-3 distances of 0.002
 Ge1, N1, N2, N3, N4, C36, C37, C38, C39, C40, C41, C42, C43, C57, C58, C59,
 C60, C61, C62, C63, C64, C65, C66, C67, C68, C69, C70, C71, C72, Ge1A, N1A,
 N2A, N3A, N4A
 with sigma for 1-2 distances of 0.002 and sigma for 1-3 distances of 0.002
4. Same fragment restrains
{Ge1A, N1A, N2A, N3A, N4A} sigma for 1-2: 0.01, 1-3: 0.02
as in
{Ge1, N1, N2, N3, N4}
{C57A, C58A, C59A, C60A, C61A, C62A, C63A, C64A} sigma for 1-2: 0.01, 1-3: 0.02
as in
{C57, C58, C59, C60, C61, C62, C63, C64}
{C65A, C66A, C67A, C68A, C69A, C70A, C71A, C72A} sigma for 1-2: 0.01, 1-3: 0.02
as in
{C65, C66, C67, C68, C69, C70, C71, C72}
{C36A, C37A, C38A, C39A, C40A, C41A, C42A, C43A} sigma for 1-2: 0.01, 1-3: 0.02
as in
{C36, C37, C38, C39, C40, C41, C42, C43}
{C81A, C82A, C83A, C84A, C85A, C86A} sigma for 1-2: 0.01, 1-3: 0.02
as in
{C81, C82, C83, C84, C85, C86}
5. Others
 Sof(C36A)=Sof(C37A)=Sof(H37D)=Sof(H37E)=Sof(H37F)=Sof(C38A)=Sof(H38D)=
 Sof(H38E)=Sof(H38F)=Sof(C39A)=Sof(H39C)=Sof(H39D)=Sof(C40A)=Sof(C41A)=
 Sof(H41D)=Sof(H41E)=Sof(H41F)=Sof(C42A)=Sof(H42D)=Sof(H42E)=Sof(H42F)=
 Sof(C43A)=Sof(H43C)=Sof(H43D)=1-FVAR(1)
 Sof(C36)=Sof(C37)=Sof(H37A)=Sof(H37B)=Sof(H37C)=Sof(C38)=Sof(H38A)=Sof(H38B)=
 Sof(H38C)=Sof(C39)=Sof(H39A)=Sof(H39B)=Sof(C40)=Sof(C41)=Sof(H41A)=Sof(H41B)=
 Sof(H41C)=Sof(C42)=Sof(H42A)=Sof(H42B)=Sof(H42C)=Sof(C43)=Sof(H43A)=Sof(H43B)=
 FVAR(1)
 Sof(C57A)=Sof(C58A)=Sof(H58D)=Sof(H58E)=Sof(H58F)=Sof(C59A)=Sof(H59D)=
 Sof(H59E)=Sof(H59F)=Sof(C60A)=Sof(H60C)=Sof(H60D)=Sof(C61A)=Sof(C62A)=
 Sof(H62D)=Sof(H62E)=Sof(H62F)=Sof(C63A)=Sof(H63D)=Sof(H63E)=Sof(H63F)=
 Sof(C64A)=Sof(H64C)=Sof(H64D)=1-FVAR(2)
 Sof(C57)=Sof(C58)=Sof(H58A)=Sof(H58B)=Sof(H58C)=Sof(C59)=Sof(H59A)=Sof(H59B)=
 Sof(H59C)=Sof(C60)=Sof(H60A)=Sof(H60B)=Sof(C61)=Sof(C62)=Sof(H62A)=Sof(H62B)=
 Sof(H62C)=Sof(C63)=Sof(H63A)=Sof(H63B)=Sof(H63C)=Sof(C64)=Sof(H64A)=Sof(H64B)=
 FVAR(2)
 Sof(C81A)=Sof(H81D)=Sof(H81E)=Sof(H81F)=Sof(C82A)=Sof(H82C)=Sof(H82D)=
 Sof(C83A)=Sof(H83C)=Sof(H83D)=Sof(C84A)=Sof(H84C)=Sof(H84D)=Sof(C85A)=
 Sof(H85C)=Sof(H85D)=Sof(C86A)=Sof(H86D)=Sof(H86E)=Sof(H86F)=1-FVAR(3)
 Sof(C81)=Sof(H81A)=Sof(H81B)=Sof(H81C)=Sof(C82)=Sof(H82A)=Sof(H82B)=Sof(C83)=
 Sof(H83A)=Sof(H83B)=Sof(C84)=Sof(H84A)=Sof(H84B)=Sof(C85)=Sof(H85A)=Sof(H85B)=
 Sof(C86)=Sof(H86A)=Sof(H86B)=Sof(H86C)=FVAR(3)
 Sof(Ge1A)=Sof(N1A)=Sof(N2A)=Sof(N3A)=Sof(N4A)=1-FVAR(4)
 Sof(Ge1)=Sof(N1)=Sof(N2)=Sof(N3)=Sof(N4)=FVAR(4)
 Sof(C65A)=Sof(C66A)=Sof(H66D)=Sof(H66E)=Sof(H66F)=Sof(C67A)=Sof(H67D)=
 Sof(H67E)=Sof(H67F)=Sof(C68A)=Sof(H68C)=Sof(H68D)=Sof(C69A)=Sof(C70A)=
 Sof(H70D)=Sof(H70E)=Sof(H70F)=Sof(C71A)=Sof(H71D)=Sof(H71E)=Sof(H71F)=
 Sof(C72A)=Sof(H72C)=Sof(H72D)=1-FVAR(5)
 Sof(C65)=Sof(C66)=Sof(H66A)=Sof(H66B)=Sof(H66C)=Sof(C67)=Sof(H67A)=Sof(H67B)=
 Sof(H67C)=Sof(C68)=Sof(H68A)=Sof(H68B)=Sof(C69)=Sof(C70)=Sof(H70A)=Sof(H70B)=
 Sof(H70C)=Sof(C71)=Sof(H71A)=Sof(H71B)=Sof(H71C)=Sof(C72)=Sof(H72A)=Sof(H72B)=
 FVAR(5)
6.a Secondary CH2 refined with riding coordinates:
 C7(H7A,H7B), C11(H11A,H11B), C31(H31A,H31B), C35(H35A,H35B), C39(H39A,H39B),
 C43(H43A,H43B), C60(H60A,H60B), C64(H64A,H64B), C68(H68A,H68B), C72(H72A,H72B),
  C39A(H39C,H39D), C43A(H43C,H43D), C60A(H60C,H60D), C64A(H64C,H64D), C68A(H68C,
 H68D), C72A(H72C,H72D), C82(H82A,H82B), C83(H83A,H83B), C84(H84A,H84B),
 C85(H85A,H85B), C82A(H82C,H82D), C83A(H83C,H83D), C84A(H84C,H84D), C85A(H85C,
 H85D)
6.b Aromatic/amide H refined with riding coordinates:
 C4(H4), C17(H17), C20(H20), C23(H23), C26(H26), C46(H46), C49(H49), C52(H52),
 C55(H55)
6.c Idealised Me refined as rotating group:
 C9(H9A,H9B,H9C), C10(H10A,H10B,H10C), C13(H13A,H13B,H13C), C14(H14A,H14B,
 H14C), C29(H29A,H29B,H29C), C30(H30A,H30B,H30C), C33(H33A,H33B,H33C), C34(H34A,
 H34B,H34C), C73(H73A,H73B,H73C), C74(H74A,H74B,H74C), C75(H75A,H75B,H75C),
 C37(H37A,H37B,H37C), C38(H38A,H38B,H38C), C41(H41A,H41B,H41C), C42(H42A,H42B,
 H42C), C58(H58A,H58B,H58C), C59(H59A,H59B,H59C), C62(H62A,H62B,H62C), C63(H63A,
 H63B,H63C), C66(H66A,H66B,H66C), C67(H67A,H67B,H67C), C70(H70A,H70B,H70C),
 C71(H71A,H71B,H71C), C37A(H37D,H37E,H37F), C38A(H38D,H38E,H38F), C41A(H41D,
 H41E,H41F), C42A(H42D,H42E,H42F), C58A(H58D,H58E,H58F), C59A(H59D,H59E,H59F),
 C62A(H62D,H62E,H62F), C63A(H63D,H63E,H63F), C66A(H66D,H66E,H66F), C67A(H67D,
 H67E,H67F), C70A(H70D,H70E,H70F), C71A(H71D,H71E,H71F), C81(H81A,H81B,H81C),
 C86(H86A,H86B,H86C), C81A(H81D,H81E,H81F), C86A(H86D,H86E,H86F)
;
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary       dual
_atom_sites_solution_secondary     ?
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_site_symmetry_order
  _atom_site_calc_flag
  _atom_site_refinement_flags_posn
  _atom_site_refinement_flags_adp
  _atom_site_refinement_flags_occupancy
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 Si1 Si 0.18931(4) 0.24954(3) 0.58335(2) 0.03844(11) Uani 1 1 d . . . . .
 C1 C 0.13128(9) 0.33593(8) 0.87190(7) 0.0213(2) Uani 1 1 d . . . . .
 C2 C 0.03210(9) 0.32203(8) 0.89605(7) 0.0208(2) Uani 1 1 d . . . . .
 C3 C 0.01713(9) 0.33521(8) 0.96959(7) 0.0217(2) Uani 1 1 d . . . . .
 C4 C 0.10029(10) 0.36200(9) 1.02042(7) 0.0243(3) Uani 1 1 d . . . . .
 H4 H 0.089876 0.369896 1.070564 0.029 Uiso 1 1 calc R U . . .
 C5 C 0.19908(10) 0.37702(8) 0.99639(7) 0.0225(2) Uani 1 1 d . . . . .
 C6 C 0.21483(9) 0.36461(8) 0.92314(7) 0.0218(2) Uani 1 1 d . . . . .
 C7 C -0.14877(10) 0.30331(10) 0.90733(7) 0.0269(3) Uani 1 1 d . . . . .
 H7A H -0.174762 0.356472 0.896754 0.032 Uiso 1 1 calc R U . . .
 H7B H -0.207752 0.250052 0.903857 0.032 Uiso 1 1 calc R U . . .
 C8 C -0.09548(10) 0.31676(9) 0.98475(7) 0.0239(3) Uani 1 1 d . . . . .
 C9 C -0.12773(11) 0.23316(10) 1.02757(8) 0.0321(3) Uani 1 1 d . . . . .
 H9A H -0.114507 0.181161 1.000045 0.048 Uiso 1 1 calc R U . . .
 H9B H -0.201082 0.221998 1.035510 0.048 Uiso 1 1 calc R U . . .
 H9C H -0.088199 0.242933 1.074497 0.048 Uiso 1 1 calc R U . . .
 C10 C -0.11944(11) 0.39677(10) 1.02767(8) 0.0307(3) Uani 1 1 d . . . . .
 H10A H -0.084615 0.404366 1.076219 0.046 Uiso 1 1 calc R U . . .
 H10B H -0.193696 0.385721 1.031898 0.046 Uiso 1 1 calc R U . . .
 H10C H -0.095334 0.451356 1.002310 0.046 Uiso 1 1 calc R U . . .
 C11 C 0.38070(11) 0.41391(11) 0.98733(8) 0.0344(3) Uani 1 1 d . . . . .
 H11A H 0.428026 0.375928 0.999622 0.041 Uiso 1 1 calc R U . . .
 H11B H 0.421278 0.476963 0.988570 0.041 Uiso 1 1 calc R U . . .
 C12 C 0.29875(10) 0.40570(9) 1.04334(7) 0.0257(3) Uani 1 1 d . . . . .
 C13 C 0.30795(13) 0.49534(12) 1.08685(11) 0.0462(4) Uani 1 1 d . . . . .
 H13A H 0.373544 0.512046 1.115813 0.069 Uiso 1 1 calc R U . . .
 H13B H 0.251426 0.489481 1.119133 0.069 Uiso 1 1 calc R U . . .
 H13C H 0.304774 0.541882 1.053480 0.069 Uiso 1 1 calc R U . . .
 C14 C 0.30693(12) 0.33475(12) 1.09640(9) 0.0388(3) Uani 1 1 d . . . . .
 H14A H 0.302535 0.277159 1.069231 0.058 Uiso 1 1 calc R U . . .
 H14B H 0.250714 0.328169 1.128998 0.058 Uiso 1 1 calc R U . . .
 H14C H 0.372774 0.353470 1.124956 0.058 Uiso 1 1 calc R U . . .
 C15 C 0.32844(10) 0.38353(9) 0.90927(7) 0.0246(3) Uani 1 1 d . . . . .
 C16 C 0.36307(10) 0.30489(9) 0.87352(8) 0.0263(3) Uani 1 1 d . . . . .
 C17 C 0.35219(11) 0.21973(10) 0.89647(8) 0.0313(3) Uani 1 1 d . . . . .
 H17 H 0.313774 0.202721 0.937314 0.038 Uiso 1 1 calc R U . . .
 C18 C 0.39747(11) 0.15762(9) 0.85999(9) 0.0318(3) Uani 1 1 d . . . . .
 C19 C 0.45387(10) 0.18324(9) 0.79934(8) 0.0306(3) Uani 1 1 d . . . . .
 C20 C 0.46172(11) 0.26935(9) 0.77566(8) 0.0301(3) Uani 1 1 d . . . . .
 H20 H 0.497999 0.286539 0.733934 0.036 Uiso 1 1 calc R U . . .
 C21 C 0.41710(10) 0.32972(9) 0.81249(8) 0.0264(3) Uani 1 1 d . . . . .
 C22 C 0.41705(10) 0.42325(9) 0.80098(8) 0.0258(3) Uani 1 1 d . . . . .
 C23 C 0.45763(11) 0.47921(9) 0.74823(8) 0.0290(3) Uani 1 1 d . . . . .
 H23 H 0.491427 0.456834 0.710031 0.035 Uiso 1 1 calc R U . . .
 C24 C 0.44951(10) 0.56867(9) 0.75040(8) 0.0284(3) Uani 1 1 d . . . . .
 C25 C 0.40224(10) 0.60190(9) 0.80848(8) 0.0279(3) Uani 1 1 d . . . . .
 C26 C 0.35841(10) 0.54322(9) 0.86007(8) 0.0274(3) Uani 1 1 d . . . . .
 H26 H 0.323511 0.564622 0.898070 0.033 Uiso 1 1 calc R U . . .
 C27 C 0.36516(10) 0.45512(9) 0.85648(7) 0.0248(3) Uani 1 1 d . . . . .
 C28 C 0.39565(11) 0.70007(9) 0.81815(9) 0.0334(3) Uani 1 1 d . . . . .
 C29 C 0.28475(13) 0.70547(12) 0.79903(11) 0.0453(4) Uani 1 1 d . . . . .
 H29A H 0.266067 0.685319 0.747849 0.068 Uiso 1 1 calc R U . . .
 H29B H 0.279594 0.767651 0.807542 0.068 Uiso 1 1 calc R U . . .
 H29C H 0.238011 0.666863 0.829539 0.068 Uiso 1 1 calc R U . . .
 C30 C 0.42522(13) 0.73815(10) 0.89677(10) 0.0405(4) Uani 1 1 d . . . . .
 H30A H 0.375402 0.705598 0.928707 0.061 Uiso 1 1 calc R U . . .
 H30B H 0.425385 0.801977 0.900768 0.061 Uiso 1 1 calc R U . . .
 H30C H 0.493797 0.731216 0.911126 0.061 Uiso 1 1 calc R U . . .
 C31 C 0.46995(14) 0.75741(10) 0.76917(10) 0.0424(4) Uani 1 1 d . . . . .
 H31A H 0.455112 0.817283 0.767875 0.051 Uiso 1 1 calc R U . . .
 H31B H 0.541087 0.766036 0.790070 0.051 Uiso 1 1 calc R U . . .
 C32 C 0.49379(12) 0.62585(10) 0.68881(8) 0.0353(3) Uani 1 1 d . . . . .
 C33 C 0.45381(18) 0.57610(13) 0.61478(10) 0.0546(5) Uani 1 1 d . . . . .
 H33A H 0.475558 0.616143 0.576177 0.082 Uiso 1 1 calc R U . . .
 H33B H 0.378690 0.557302 0.612645 0.082 Uiso 1 1 calc R U . . .
 H33C H 0.481653 0.523093 0.608257 0.082 Uiso 1 1 calc R U . . .
 C34 C 0.61133(13) 0.64418(12) 0.69469(10) 0.0435(4) Uani 1 1 d . . . . .
 H34A H 0.631429 0.587130 0.695789 0.065 Uiso 1 1 calc R U . . .
 H34B H 0.638430 0.681656 0.739337 0.065 Uiso 1 1 calc R U . . .
 H34C H 0.639157 0.675469 0.652712 0.065 Uiso 1 1 calc R U . . .
 C35 C 0.46184(15) 0.71500(11) 0.69265(10) 0.0447(4) Uani 1 1 d . . . . .
 H35A H 0.505994 0.757210 0.662252 0.054 Uiso 1 1 calc R U . . .
 H35B H 0.390120 0.704466 0.672407 0.054 Uiso 1 1 calc R U . . .
 C44 C -0.06908(9) 0.28980(8) 0.85086(7) 0.0222(2) Uani 1 1 d . . . . .
 C45 C -0.08943(9) 0.19323(9) 0.81773(7) 0.0239(3) Uani 1 1 d . . . . .
 C46 C -0.08473(10) 0.11577(9) 0.85007(8) 0.0277(3) Uani 1 1 d . . . . .
 H46 H -0.063286 0.119116 0.900056 0.033 Uiso 1 1 calc R U . . .
 C47 C -0.11123(11) 0.03171(9) 0.81015(8) 0.0304(3) Uani 1 1 d . . . . .
 C48 C -0.13805(11) 0.02762(10) 0.73568(9) 0.0323(3) Uani 1 1 d . . . . .
 C49 C -0.14233(11) 0.10674(10) 0.70320(8) 0.0315(3) Uani 1 1 d . . . . .
 H49 H -0.160793 0.104429 0.652771 0.038 Uiso 1 1 calc R U . . .
 C50 C -0.11986(10) 0.18823(9) 0.74397(7) 0.0256(3) Uani 1 1 d . . . . .
 C51 C -0.11914(10) 0.27874(9) 0.72309(7) 0.0255(3) Uani 1 1 d . . . . .
 C52 C -0.14899(11) 0.30880(10) 0.65836(8) 0.0296(3) Uani 1 1 d . . . . .
 H52 H -0.177202 0.266673 0.618620 0.035 Uiso 1 1 calc R U . . .
 C53 C -0.13808(11) 0.40030(10) 0.65086(8) 0.0291(3) Uani 1 1 d . . . . .
 C54 C -0.09234(10) 0.46230(9) 0.70952(8) 0.0276(3) Uani 1 1 d . . . . .
 C55 C -0.06762(10) 0.43016(9) 0.77583(7) 0.0262(3) Uani 1 1 d . . . . .
 H55 H -0.039949 0.471581 0.816114 0.031 Uiso 1 1 calc R U . . .
 C56 C -0.08298(9) 0.33915(9) 0.78333(7) 0.0235(2) Uani 1 1 d . . . . .
 C73 C 0.07226(19) 0.25874(17) 0.53034(11) 0.0640(6) Uani 1 1 d . . . . .
 H73A H 0.013284 0.212549 0.543460 0.096 Uiso 1 1 calc R U . . .
 H73B H 0.081564 0.250267 0.478411 0.096 Uiso 1 1 calc R U . . .
 H73C H 0.060053 0.318287 0.541142 0.096 Uiso 1 1 calc R U . . .
 C74 C 0.2024(2) 0.13200(15) 0.57873(11) 0.0613(5) Uani 1 1 d . . . . .
 H74A H 0.257961 0.127186 0.613368 0.092 Uiso 1 1 calc R U . . .
 H74B H 0.218318 0.114887 0.529549 0.092 Uiso 1 1 calc R U . . .
 H74C H 0.137944 0.091891 0.590826 0.092 Uiso 1 1 calc R U . . .
 C75 C 0.3054(2) 0.32658(18) 0.55280(13) 0.0737(7) Uani 1 1 d . . . . .
 H75A H 0.300027 0.388762 0.560793 0.110 Uiso 1 1 calc R U . . .
 H75B H 0.311292 0.312794 0.501016 0.110 Uiso 1 1 calc R U . . .
 H75C H 0.366329 0.318910 0.580448 0.110 Uiso 1 1 calc R U . . .
 Ge1 Ge 0.15492(2) 0.20777(2) 0.75330(2) 0.03082(8) Uani 0.8654(12) 1 d D . P A
 1
 N1 N 0.1471(3) 0.31734(13) 0.79752(10) 0.0225(4) Uani 0.8654(12) 1 d D . P A 1
 N2 N 0.15782(15) 0.38865(14) 0.75609(12) 0.0309(4) Uani 0.8654(12) 1 d D . P A
 1
 N3 N 0.1729(2) 0.36779(18) 0.68793(13) 0.0372(6) Uani 0.8654(12) 1 d D . P A 1
 N4 N 0.1752(4) 0.27855(15) 0.67510(11) 0.0299(4) Uani 0.8654(12) 1 d D . P A 1
 C36 C 0.5102(4) 0.1209(3) 0.7589(3) 0.0384(10) Uani 0.656(5) 1 d D U P B 1
 C37 C 0.4991(5) 0.1249(3) 0.6775(2) 0.0789(13) Uani 0.656(5) 1 d D U P B 1
 H37A H 0.426100 0.111061 0.661479 0.118 Uiso 0.656(5) 1 calc R U P B 1
 H37B H 0.531136 0.080935 0.653727 0.118 Uiso 0.656(5) 1 calc R U P B 1
 H37C H 0.532802 0.185263 0.664436 0.118 Uiso 0.656(5) 1 calc R U P B 1
 C38 C 0.6233(3) 0.1505(3) 0.7857(4) 0.0775(14) Uani 0.656(5) 1 d D U P B 1
 H38A H 0.651852 0.212311 0.773502 0.116 Uiso 0.656(5) 1 calc R U P B 1
 H38B H 0.661113 0.110687 0.762426 0.116 Uiso 0.656(5) 1 calc R U P B 1
 H38C H 0.629534 0.147516 0.838481 0.116 Uiso 0.656(5) 1 calc R U P B 1
 C39 C 0.4669(3) 0.02316(17) 0.77562(17) 0.0494(7) Uani 0.656(5) 1 d D U P B 1
 H39A H 0.398181 0.000281 0.750197 0.059 Uiso 0.656(5) 1 calc R U P B 1
 H39B H 0.512177 -0.014035 0.757284 0.059 Uiso 0.656(5) 1 calc R U P B 1
 C40 C 0.3878(4) 0.0665(5) 0.8925(3) 0.0397(11) Uani 0.656(5) 1 d D U P B 1
 C41 C 0.2752(4) 0.0162(6) 0.8845(3) 0.0641(13) Uani 0.656(5) 1 d D U P B 1
 H41A H 0.234513 0.050920 0.910929 0.096 Uiso 0.656(5) 1 calc R U P B 1
 H41B H 0.266979 -0.042538 0.904425 0.096 Uiso 0.656(5) 1 calc R U P B 1
 H41C H 0.251695 0.007917 0.833035 0.096 Uiso 0.656(5) 1 calc R U P B 1
 C42 C 0.4207(5) 0.0785(5) 0.9736(3) 0.0559(13) Uani 0.656(5) 1 d D U P B 1
 H42A H 0.492853 0.111807 0.980562 0.084 Uiso 0.656(5) 1 calc R U P B 1
 H42B H 0.412512 0.019449 0.992954 0.084 Uiso 0.656(5) 1 calc R U P B 1
 H42C H 0.377949 0.111962 0.999102 0.084 Uiso 0.656(5) 1 calc R U P B 1
 C43 C 0.4583(4) 0.0147(3) 0.8563(2) 0.0573(11) Uani 0.656(5) 1 d D U P B 1
 H43A H 0.527849 0.035631 0.880689 0.069 Uiso 0.656(5) 1 calc R U P B 1
 H43B H 0.433072 -0.049707 0.864540 0.069 Uiso 0.656(5) 1 calc R U P B 1
 C57 C -0.1136(3) -0.0524(4) 0.8477(2) 0.0391(9) Uani 0.735(6) 1 d D U P C 1
 C58 C -0.1748(4) -0.0528(5) 0.9160(3) 0.0591(12) Uani 0.735(6) 1 d D U P C 1
 H58A H -0.139738 -0.002555 0.950357 0.089 Uiso 0.735(6) 1 calc R U P C 1
 H58B H -0.179478 -0.109490 0.938822 0.089 Uiso 0.735(6) 1 calc R U P C 1
 H58C H -0.243914 -0.046752 0.902439 0.089 Uiso 0.735(6) 1 calc R U P C 1
 C59 C -0.0030(3) -0.0545(2) 0.8712(2) 0.0577(8) Uani 0.735(6) 1 d D U P C 1
 H59A H 0.035684 -0.058376 0.828048 0.087 Uiso 0.735(6) 1 calc R U P C 1
 H59B H -0.004151 -0.106939 0.899039 0.087 Uiso 0.735(6) 1 calc R U P C 1
 H59C H 0.029801 0.000349 0.901339 0.087 Uiso 0.735(6) 1 calc R U P C 1
 C60 C -0.1656(3) -0.13756(15) 0.79928(16) 0.0465(7) Uani 0.735(6) 1 d D U P C
 1
 H60A H -0.150310 -0.190507 0.821046 0.056 Uiso 0.735(6) 1 calc R U P C 1
 H60B H -0.240931 -0.145142 0.797294 0.056 Uiso 0.735(6) 1 calc R U P C 1
 C61 C -0.1584(4) -0.0571(4) 0.6837(3) 0.0410(9) Uani 0.735(6) 1 d D U P C 1
 C62 C -0.2742(4) -0.0838(6) 0.6605(4) 0.066(2) Uani 0.735(6) 1 d D U P C 1
 H62A H -0.313720 -0.095941 0.703465 0.100 Uiso 0.735(6) 1 calc R U P C 1
 H62B H -0.289383 -0.137780 0.627010 0.100 Uiso 0.735(6) 1 calc R U P C 1
 H62C H -0.293033 -0.034544 0.636256 0.100 Uiso 0.735(6) 1 calc R U P C 1
 C63 C -0.0953(3) -0.0435(2) 0.6165(2) 0.0570(9) Uani 0.735(6) 1 d D U P C 1
 H63A H -0.119140 -0.001482 0.586167 0.086 Uiso 0.735(6) 1 calc R U P C 1
 H63B H -0.103838 -0.101260 0.588570 0.086 Uiso 0.735(6) 1 calc R U P C 1
 H63C H -0.022631 -0.019040 0.631764 0.086 Uiso 0.735(6) 1 calc R U P C 1
 C64 C -0.1300(3) -0.13355(16) 0.72330(15) 0.0446(7) Uani 0.735(6) 1 d D U P C
 1
 H64A H -0.161306 -0.191425 0.695414 0.054 Uiso 0.735(6) 1 calc R U P C 1
 H64B H -0.054567 -0.125036 0.725409 0.054 Uiso 0.735(6) 1 calc R U P C 1
 C65 C -0.1946(13) 0.4267(9) 0.5869(11) 0.051(4) Uani 0.133(5) 1 d D U P D 1
 C66 C -0.3070(11) 0.3736(12) 0.5752(10) 0.055(4) Uani 0.133(5) 1 d D U P D 1
 H66A H -0.310303 0.309167 0.570804 0.083 Uiso 0.133(5) 1 calc R U P D 1
 H66B H -0.337614 0.390594 0.530696 0.083 Uiso 0.133(5) 1 calc R U P D 1
 H66C H -0.344921 0.387111 0.616608 0.083 Uiso 0.133(5) 1 calc R U P D 1
 C67 C -0.1374(16) 0.4053(15) 0.5210(11) 0.056(4) Uani 0.133(5) 1 d D U P D 1
 H67A H -0.070387 0.448285 0.522016 0.084 Uiso 0.133(5) 1 calc R U P D 1
 H67B H -0.177692 0.409543 0.476322 0.084 Uiso 0.133(5) 1 calc R U P D 1
 H67C H -0.127683 0.344289 0.522453 0.084 Uiso 0.133(5) 1 calc R U P D 1
 C68 C -0.1865(11) 0.5275(8) 0.5933(7) 0.047(3) Uani 0.133(5) 1 d D U P D 1
 H68A H -0.196383 0.547174 0.544028 0.057 Uiso 0.133(5) 1 calc R U P D 1
 H68B H -0.243237 0.538598 0.621697 0.057 Uiso 0.133(5) 1 calc R U P D 1
 C69 C -0.0666(10) 0.5625(15) 0.7066(7) 0.039(4) Uani 0.133(5) 1 d D U P D 1
 C70 C -0.1317(13) 0.6046(10) 0.7574(7) 0.043(3) Uani 0.133(5) 1 d D U P D 1
 H70A H -0.204045 0.572515 0.748806 0.064 Uiso 0.133(5) 1 calc R U P D 1
 H70B H -0.123627 0.667879 0.748048 0.064 Uiso 0.133(5) 1 calc R U P D 1
 H70C H -0.109005 0.600341 0.807969 0.064 Uiso 0.133(5) 1 calc R U P D 1
 C71 C 0.0476(9) 0.5996(10) 0.7290(10) 0.048(3) Uani 0.133(5) 1 d D U P D 1
 H71A H 0.058216 0.600930 0.781896 0.072 Uiso 0.133(5) 1 calc R U P D 1
 H71B H 0.070466 0.660652 0.713416 0.072 Uiso 0.133(5) 1 calc R U P D 1
 H71C H 0.087239 0.561096 0.706104 0.072 Uiso 0.133(5) 1 calc R U P D 1
 C72 C -0.0871(11) 0.5843(11) 0.6281(7) 0.043(3) Uani 0.133(5) 1 d D U P D 1
 H72A H -0.088330 0.648314 0.627714 0.052 Uiso 0.133(5) 1 calc R U P D 1
 H72B H -0.030114 0.575119 0.599030 0.052 Uiso 0.133(5) 1 calc R U P D 1
 Ge1A Ge 0.1760(2) 0.38018(16) 0.7216(2) 0.0503(8) Uani 0.1346(12) 1 d D U P A
 2
 N1A N 0.144(3) 0.3047(10) 0.7955(9) 0.046(3) Uani 0.1346(12) 1 d D U P A 2
 N2A N 0.1413(13) 0.2161(8) 0.7843(9) 0.057(3) Uani 0.1346(12) 1 d D U P A 2
 N3A N 0.1546(12) 0.1953(7) 0.7144(9) 0.065(3) Uani 0.1346(12) 1 d D U P A 2
 N4A N 0.177(4) 0.2700(10) 0.6744(10) 0.060(4) Uani 0.1346(12) 1 d D U P A 2
 C36A C 0.5125(7) 0.1231(7) 0.7617(5) 0.042(2) Uani 0.344(5) 1 d D U P B 2
 C37A C 0.4542(5) 0.0822(5) 0.6909(4) 0.0534(15) Uani 0.344(5) 1 d D U P B 2
 H37D H 0.385188 0.048197 0.700605 0.080 Uiso 0.344(5) 1 calc R U P B 2
 H37E H 0.490692 0.041921 0.666788 0.080 Uiso 0.344(5) 1 calc R U P B 2
 H37F H 0.448844 0.130112 0.659325 0.080 Uiso 0.344(5) 1 calc R U P B 2
 C38A C 0.6196(5) 0.1757(4) 0.7438(5) 0.0525(15) Uani 0.344(5) 1 d D U P B 2
 H38D H 0.612832 0.217004 0.706544 0.079 Uiso 0.344(5) 1 calc R U P B 2
 H38E H 0.658598 0.133740 0.725794 0.079 Uiso 0.344(5) 1 calc R U P B 2
 H38F H 0.655593 0.210080 0.787697 0.079 Uiso 0.344(5) 1 calc R U P B 2
 C39A C 0.5268(5) 0.0509(4) 0.8123(4) 0.0540(13) Uani 0.344(5) 1 d D U P B 2
 H39C H 0.558943 0.007964 0.786093 0.065 Uiso 0.344(5) 1 calc R U P B 2
 H39D H 0.573855 0.079721 0.854477 0.065 Uiso 0.344(5) 1 calc R U P B 2
 C40A C 0.3704(9) 0.0599(9) 0.8821(7) 0.0463(19) Uani 0.344(5) 1 d D U P B 2
 C41A C 0.2565(9) 0.0161(14) 0.8646(9) 0.089(3) Uani 0.344(5) 1 d D U P B 2
 H41D H 0.215440 0.055768 0.883885 0.133 Uiso 0.344(5) 1 calc R U P B 2
 H41E H 0.238156 -0.041427 0.886726 0.133 Uiso 0.344(5) 1 calc R U P B 2
 H41F H 0.242751 0.005977 0.811836 0.133 Uiso 0.344(5) 1 calc R U P B 2
 C42A C 0.3942(12) 0.0606(11) 0.9630(7) 0.069(3) Uani 0.344(5) 1 d D U P B 2
 H42D H 0.465828 0.092853 0.975296 0.104 Uiso 0.344(5) 1 calc R U P B 2
 H42E H 0.383526 -0.001337 0.976972 0.104 Uiso 0.344(5) 1 calc R U P B 2
 H42F H 0.348793 0.090572 0.989219 0.104 Uiso 0.344(5) 1 calc R U P B 2
 C43A C 0.4262(6) 0.0005(6) 0.8391(5) 0.0524(16) Uani 0.344(5) 1 d D U P B 2
 H43C H 0.439358 -0.046264 0.870190 0.063 Uiso 0.344(5) 1 calc R U P B 2
 H43D H 0.380659 -0.030300 0.796839 0.063 Uiso 0.344(5) 1 calc R U P B 2
 C57A C -0.0984(9) -0.0500(8) 0.8598(6) 0.041(3) Uani 0.265(6) 1 d D . P C 2
 C58A C -0.1892(13) -0.0727(15) 0.9078(11) 0.084(6) Uani 0.265(6) 1 d D . P C
 2
 H58D H -0.186903 -0.021409 0.942460 0.126 Uiso 0.265(6) 1 calc R U P C 2
 H58E H -0.185410 -0.125207 0.934309 0.126 Uiso 0.265(6) 1 calc R U P C 2
 H58F H -0.253538 -0.085950 0.877440 0.126 Uiso 0.265(6) 1 calc R U P C 2
 C59A C 0.0026(9) -0.0272(6) 0.9071(8) 0.083(4) Uani 0.265(6) 1 d D . P C 2
 H59D H 0.058604 0.003473 0.878742 0.125 Uiso 0.265(6) 1 calc R U P C 2
 H59E H 0.017134 -0.082602 0.923288 0.125 Uiso 0.265(6) 1 calc R U P C 2
 H59F H -0.003333 0.012207 0.949422 0.125 Uiso 0.265(6) 1 calc R U P C 2
 C60A C -0.0999(7) -0.1296(4) 0.8059(4) 0.0480(19) Uani 0.265(6) 1 d D . P C
 2
 H60C H -0.032736 -0.119746 0.784090 0.058 Uiso 0.265(6) 1 calc R U P C 2
 H60D H -0.109124 -0.184666 0.832533 0.058 Uiso 0.265(6) 1 calc R U P C 2
 C61A C -0.1714(9) -0.0679(9) 0.6957(6) 0.042(3) Uani 0.265(6) 1 d D . P C 2
 C62A C -0.2710(10) -0.0781(18) 0.6473(10) 0.053(4) Uani 0.265(6) 1 d D . P C
 2
 H62D H -0.327712 -0.075323 0.678024 0.079 Uiso 0.265(6) 1 calc R U P C 2
 H62E H -0.286836 -0.135992 0.618763 0.079 Uiso 0.265(6) 1 calc R U P C 2
 H62F H -0.261755 -0.029375 0.614575 0.079 Uiso 0.265(6) 1 calc R U P C 2
 C63A C -0.0848(8) -0.0669(7) 0.6453(7) 0.061(2) Uani 0.265(6) 1 d D . P C 2
 H63D H -0.078461 -0.016265 0.614693 0.092 Uiso 0.265(6) 1 calc R U P C 2
 H63E H -0.099923 -0.123210 0.614593 0.092 Uiso 0.265(6) 1 calc R U P C 2
 H63F H -0.020176 -0.060591 0.674336 0.092 Uiso 0.265(6) 1 calc R U P C 2
 C64A C -0.1832(7) -0.1441(4) 0.7463(5) 0.051(2) Uani 0.265(6) 1 d D . P C 2
 H64C H -0.250071 -0.151862 0.768324 0.061 Uiso 0.265(6) 1 calc R U P C 2
 H64D H -0.184346 -0.200463 0.717178 0.061 Uiso 0.265(6) 1 calc R U P C 2
 C65A C -0.18214(19) 0.43054(16) 0.58075(16) 0.0348(6) Uani 0.867(5) 1 d D . P D
 2
 C66A C -0.29734(18) 0.4200(2) 0.58886(15) 0.0503(6) Uani 0.867(5) 1 d D . P D
 2
 H66D H -0.330609 0.356721 0.593567 0.075 Uiso 0.867(5) 1 calc R U P D 2
 H66E H -0.327827 0.440696 0.545952 0.075 Uiso 0.867(5) 1 calc R U P D 2
 H66F H -0.307144 0.456012 0.632227 0.075 Uiso 0.867(5) 1 calc R U P D 2
 C67A C -0.1695(3) 0.3729(2) 0.51276(17) 0.0496(7) Uani 0.867(5) 1 d D . P D
 2
 H67D H -0.097439 0.370786 0.510891 0.074 Uiso 0.867(5) 1 calc R U P D 2
 H67E H -0.190455 0.399319 0.469380 0.074 Uiso 0.867(5) 1 calc R U P D 2
 H67F H -0.212460 0.311917 0.514615 0.074 Uiso 0.867(5) 1 calc R U P D 2
 C68A C -0.1289(2) 0.52798(14) 0.56916(11) 0.0466(6) Uani 0.867(5) 1 d D . P D
 2
 H68C H -0.059239 0.530522 0.553061 0.056 Uiso 0.867(5) 1 calc R U P D 2
 H68D H -0.167847 0.549402 0.530092 0.056 Uiso 0.867(5) 1 calc R U P D 2
 C69A C -0.0573(2) 0.5634(2) 0.69955(13) 0.0353(6) Uani 0.867(5) 1 d D . P D
 2
 C70A C -0.0682(3) 0.62122(16) 0.76776(13) 0.0609(8) Uani 0.867(5) 1 d D . P D
 2
 H70D H -0.138596 0.603082 0.782780 0.091 Uiso 0.867(5) 1 calc R U P D 2
 H70E H -0.052473 0.684573 0.757170 0.091 Uiso 0.867(5) 1 calc R U P D 2
 H70F H -0.020340 0.612915 0.806916 0.091 Uiso 0.867(5) 1 calc R U P D 2
 C71A C 0.05639(18) 0.58282(17) 0.68376(18) 0.0549(7) Uani 0.867(5) 1 d D . P D
 2
 H71D H 0.094863 0.562433 0.722932 0.082 Uiso 0.867(5) 1 calc R U P D 2
 H71E H 0.083237 0.647519 0.680562 0.082 Uiso 0.867(5) 1 calc R U P D 2
 H71F H 0.063798 0.550888 0.637672 0.082 Uiso 0.867(5) 1 calc R U P D 2
 C72A C -0.1205(2) 0.58996(18) 0.63710(14) 0.0454(7) Uani 0.867(5) 1 d D . P D
 2
 H72C H -0.190250 0.588607 0.652586 0.054 Uiso 0.867(5) 1 calc R U P D 2
 H72D H -0.088122 0.652196 0.625951 0.054 Uiso 0.867(5) 1 calc R U P D 2
 C81 C 0.8413(14) 0.1657(10) 0.3540(9) 0.099(4) Uani 0.243(5) 1 d D U P E 1
 H81A H 0.884197 0.151883 0.315725 0.149 Uiso 0.243(5) 1 calc R U P E 1
 H81B H 0.881917 0.214363 0.387621 0.149 Uiso 0.243(5) 1 calc R U P E 1
 H81C H 0.782671 0.184369 0.332203 0.149 Uiso 0.243(5) 1 calc R U P E 1
 C82 C 0.8037(10) 0.0846(8) 0.3941(6) 0.086(2) Uani 0.243(5) 1 d D U P E 1
 H82A H 0.863786 0.063135 0.411308 0.104 Uiso 0.243(5) 1 calc R U P E 1
 H82B H 0.761100 0.036939 0.359572 0.104 Uiso 0.243(5) 1 calc R U P E 1
 C83 C 0.7415(11) 0.0960(10) 0.4586(7) 0.082(2) Uani 0.243(5) 1 d D U P E 1
 H83A H 0.725486 0.038492 0.482114 0.099 Uiso 0.243(5) 1 calc R U P E 1
 H83B H 0.785520 0.141592 0.494052 0.099 Uiso 0.243(5) 1 calc R U P E 1
 C84 C 0.6421(11) 0.1232(12) 0.4443(9) 0.081(2) Uani 0.243(5) 1 d D U P E 1
 H84A H 0.655775 0.178206 0.417498 0.097 Uiso 0.243(5) 1 calc R U P E 1
 H84B H 0.593988 0.074983 0.413317 0.097 Uiso 0.243(5) 1 calc R U P E 1
 C85 C 0.5928(12) 0.1404(13) 0.5127(9) 0.075(2) Uani 0.243(5) 1 d D U P E 1
 H85A H 0.644832 0.181538 0.546609 0.090 Uiso 0.243(5) 1 calc R U P E 1
 H85B H 0.570434 0.083005 0.535719 0.090 Uiso 0.243(5) 1 calc R U P E 1
 C86 C 0.5006(11) 0.1810(11) 0.5022(9) 0.075(3) Uani 0.243(5) 1 d D U P E 1
 H86A H 0.454220 0.146860 0.462322 0.112 Uiso 0.243(5) 1 calc R U P E 1
 H86B H 0.524294 0.243636 0.490545 0.112 Uiso 0.243(5) 1 calc R U P E 1
 H86C H 0.464197 0.178436 0.546912 0.112 Uiso 0.243(5) 1 calc R U P E 1
 C81A C 0.8213(3) 0.1179(3) 0.3144(2) 0.0785(11) Uani 0.757(5) 1 d D U P E 2
 H81D H 0.872046 0.146598 0.281407 0.118 Uiso 0.757(5) 1 calc R U P E 2
 H81E H 0.753992 0.127261 0.299641 0.118 Uiso 0.757(5) 1 calc R U P E 2
 H81F H 0.817482 0.053397 0.312690 0.118 Uiso 0.757(5) 1 calc R U P E 2
 C82A C 0.8526(3) 0.1583(3) 0.3899(2) 0.0766(11) Uani 0.757(5) 1 d D U P E 2
 H82C H 0.860797 0.223973 0.390126 0.092 Uiso 0.757(5) 1 calc R U P E 2
 H82D H 0.920358 0.147861 0.404218 0.092 Uiso 0.757(5) 1 calc R U P E 2
 C83A C 0.7778(3) 0.1219(3) 0.4466(2) 0.0694(9) Uani 0.757(5) 1 d D U P E 2
 H83C H 0.767953 0.055956 0.445759 0.083 Uiso 0.757(5) 1 calc R U P E 2
 H83D H 0.808445 0.147720 0.495279 0.083 Uiso 0.757(5) 1 calc R U P E 2
 C84A C 0.6737(3) 0.1430(2) 0.4350(2) 0.0617(9) Uani 0.757(5) 1 d D U P E 2
 H84C H 0.684511 0.208037 0.429071 0.074 Uiso 0.757(5) 1 calc R U P E 2
 H84D H 0.639423 0.110413 0.389247 0.074 Uiso 0.757(5) 1 calc R U P E 2
 C85A C 0.6041(4) 0.1186(4) 0.4949(3) 0.0801(13) Uani 0.757(5) 1 d D U P E 2
 H85C H 0.638406 0.150884 0.540768 0.096 Uiso 0.757(5) 1 calc R U P E 2
 H85D H 0.592679 0.053464 0.500620 0.096 Uiso 0.757(5) 1 calc R U P E 2
 C86A C 0.5002(3) 0.1408(4) 0.4826(3) 0.0860(15) Uani 0.757(5) 1 d D U P E 2
 H86D H 0.467464 0.112233 0.435838 0.129 Uiso 0.757(5) 1 calc R U P E 2
 H86E H 0.510169 0.206061 0.482416 0.129 Uiso 0.757(5) 1 calc R U P E 2
 H86F H 0.456342 0.118480 0.521608 0.129 Uiso 0.757(5) 1 calc R U P E 2


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 Si1 C73 1.854(2) . ?
 Si1 C74 1.856(2) . ?
 Si1 C75 1.854(2) . ?
 Si1 N4 1.7603(17) . ?
 Si1 N4A 1.717(14) . ?
 C1 C2 1.3991(17) . ?
 C1 C6 1.4017(18) . ?
 C1 N1 1.425(2) . ?
 C1 N1A 1.497(13) . ?
 C2 C3 1.3951(18) . ?
 C2 C44 1.5208(17) . ?
 C3 C4 1.3912(18) . ?
 C3 C8 1.5158(17) . ?
 C4 H4 0.9500 . ?
 C4 C5 1.3924(18) . ?
 C5 C6 1.3908(18) . ?
 C5 C12 1.5178(17) . ?
 C6 C15 1.5228(17) . ?
 C7 H7A 0.9900 . ?
 C7 H7B 0.9900 . ?
 C7 C8 1.5499(18) . ?
 C7 C44 1.5730(17) . ?
 C8 C9 1.5344(19) . ?
 C8 C10 1.5332(18) . ?
 C9 H9A 0.9800 . ?
 C9 H9B 0.9800 . ?
 C9 H9C 0.9800 . ?
 C10 H10A 0.9800 . ?
 C10 H10B 0.9800 . ?
 C10 H10C 0.9800 . ?
 C11 H11A 0.9900 . ?
 C11 H11B 0.9900 . ?
 C11 C12 1.538(2) . ?
 C11 C15 1.569(2) . ?
 C12 C13 1.530(2) . ?
 C12 C14 1.530(2) . ?
 C13 H13A 0.9800 . ?
 C13 H13B 0.9800 . ?
 C13 H13C 0.9800 . ?
 C14 H14A 0.9800 . ?
 C14 H14B 0.9800 . ?
 C14 H14C 0.9800 . ?
 C15 C16 1.5252(18) . ?
 C15 C27 1.5237(18) . ?
 C16 C17 1.3775(19) . ?
 C16 C21 1.3947(19) . ?
 C17 H17 0.9500 . ?
 C17 C18 1.409(2) . ?
 C18 C19 1.407(2) . ?
 C18 C40 1.537(8) . ?
 C18 C40A 1.544(15) . ?
 C19 C20 1.401(2) . ?
 C19 C36 1.541(7) . ?
 C19 C36A 1.513(14) . ?
 C20 H20 0.9500 . ?
 C20 C21 1.3862(19) . ?
 C21 C22 1.4672(18) . ?
 C22 C23 1.3841(19) . ?
 C22 C27 1.3991(19) . ?
 C23 H23 0.9500 . ?
 C23 C24 1.4053(19) . ?
 C24 C25 1.407(2) . ?
 C24 C32 1.536(2) . ?
 C25 C26 1.405(2) . ?
 C25 C28 1.5348(19) . ?
 C26 H26 0.9500 . ?
 C26 C27 1.3782(19) . ?
 C28 C29 1.540(2) . ?
 C28 C30 1.532(2) . ?
 C28 C31 1.535(2) . ?
 C29 H29A 0.9800 . ?
 C29 H29B 0.9800 . ?
 C29 H29C 0.9800 . ?
 C30 H30A 0.9800 . ?
 C30 H30B 0.9800 . ?
 C30 H30C 0.9800 . ?
 C31 H31A 0.9900 . ?
 C31 H31B 0.9900 . ?
 C31 C35 1.511(3) . ?
 C32 C33 1.535(2) . ?
 C32 C34 1.535(2) . ?
 C32 C35 1.532(2) . ?
 C33 H33A 0.9800 . ?
 C33 H33B 0.9800 . ?
 C33 H33C 0.9800 . ?
 C34 H34A 0.9800 . ?
 C34 H34B 0.9800 . ?
 C34 H34C 0.9800 . ?
 C35 H35A 0.9900 . ?
 C35 H35B 0.9900 . ?
 C44 C45 1.5291(17) . ?
 C44 C56 1.5265(18) . ?
 C45 C46 1.3782(19) . ?
 C45 C50 1.3977(19) . ?
 C46 H46 0.9500 . ?
 C46 C47 1.408(2) . ?
 C47 C48 1.401(2) . ?
 C47 C57 1.499(6) . ?
 C47 C57A 1.637(14) . ?
 C48 C49 1.401(2) . ?
 C48 C61 1.534(6) . ?
 C48 C61A 1.559(14) . ?
 C49 H49 0.9500 . ?
 C49 C50 1.3840(19) . ?
 C50 C51 1.4650(19) . ?
 C51 C52 1.3847(19) . ?
 C51 C56 1.3961(18) . ?
 C52 H52 0.9500 . ?
 C52 C53 1.396(2) . ?
 C53 C54 1.413(2) . ?
 C53 C65 1.50(2) . ?
 C53 C65A 1.543(3) . ?
 C54 C55 1.4041(19) . ?
 C54 C69 1.50(2) . ?
 C54 C69A 1.538(4) . ?
 C55 H55 0.9500 . ?
 C55 C56 1.3816(19) . ?
 C73 H73A 0.9800 . ?
 C73 H73B 0.9800 . ?
 C73 H73C 0.9800 . ?
 C74 H74A 0.9800 . ?
 C74 H74B 0.9800 . ?
 C74 H74C 0.9800 . ?
 C75 H75A 0.9800 . ?
 C75 H75B 0.9800 . ?
 C75 H75C 0.9800 . ?
 Ge1 N1 1.858(2) . ?
 Ge1 N4 1.853(2) . ?
 N1 N2 1.359(3) . ?
 N2 N3 1.320(3) . ?
 N3 N4 1.387(4) . ?
 C36 C37 1.513(5) . ?
 C36 C38 1.529(5) . ?
 C36 C39 1.531(5) . ?
 C37 H37A 0.9800 . ?
 C37 H37B 0.9800 . ?
 C37 H37C 0.9800 . ?
 C38 H38A 0.9800 . ?
 C38 H38B 0.9800 . ?
 C38 H38C 0.9800 . ?
 C39 H39A 0.9900 . ?
 C39 H39B 0.9900 . ?
 C39 C43 1.513(5) . ?
 C40 C41 1.521(5) . ?
 C40 C42 1.530(4) . ?
 C40 C43 1.532(4) . ?
 C41 H41A 0.9800 . ?
 C41 H41B 0.9800 . ?
 C41 H41C 0.9800 . ?
 C42 H42A 0.9800 . ?
 C42 H42B 0.9800 . ?
 C42 H42C 0.9800 . ?
 C43 H43A 0.9900 . ?
 C43 H43B 0.9900 . ?
 C57 C58 1.541(4) . ?
 C57 C59 1.538(4) . ?
 C57 C60 1.538(4) . ?
 C58 H58A 0.9800 . ?
 C58 H58B 0.9800 . ?
 C58 H58C 0.9800 . ?
 C59 H59A 0.9800 . ?
 C59 H59B 0.9800 . ?
 C59 H59C 0.9800 . ?
 C60 H60A 0.9900 . ?
 C60 H60B 0.9900 . ?
 C60 C64 1.507(4) . ?
 C61 C62 1.545(4) . ?
 C61 C63 1.535(5) . ?
 C61 C64 1.536(4) . ?
 C62 H62A 0.9800 . ?
 C62 H62B 0.9800 . ?
 C62 H62C 0.9800 . ?
 C63 H63A 0.9800 . ?
 C63 H63B 0.9800 . ?
 C63 H63C 0.9800 . ?
 C64 H64A 0.9900 . ?
 C64 H64B 0.9900 . ?
 C65 C66 1.534(10) . ?
 C65 C67 1.535(10) . ?
 C65 C68 1.524(10) . ?
 C66 H66A 0.9800 . ?
 C66 H66B 0.9800 . ?
 C66 H66C 0.9800 . ?
 C67 H67A 0.9800 . ?
 C67 H67B 0.9800 . ?
 C67 H67C 0.9800 . ?
 C68 H68A 0.9900 . ?
 C68 H68B 0.9900 . ?
 C68 C72 1.501(9) . ?
 C69 C70 1.535(10) . ?
 C69 C71 1.532(10) . ?
 C69 C72 1.536(9) . ?
 C70 H70A 0.9800 . ?
 C70 H70B 0.9800 . ?
 C70 H70C 0.9800 . ?
 C71 H71A 0.9800 . ?
 C71 H71B 0.9800 . ?
 C71 H71C 0.9800 . ?
 C72 H72A 0.9900 . ?
 C72 H72B 0.9900 . ?
 Ge1A N1A 1.845(10) . ?
 Ge1A N4A 1.865(10) . ?
 N1A N2A 1.358(10) . ?
 N2A N3A 1.345(9) . ?
 N3A N4A 1.385(10) . ?
 C36A C37A 1.515(8) . ?
 C36A C38A 1.535(8) . ?
 C36A C39A 1.535(8) . ?
 C37A H37D 0.9800 . ?
 C37A H37E 0.9800 . ?
 C37A H37F 0.9800 . ?
 C38A H38D 0.9800 . ?
 C38A H38E 0.9800 . ?
 C38A H38F 0.9800 . ?
 C39A H39C 0.9900 . ?
 C39A H39D 0.9900 . ?
 C39A C43A 1.512(7) . ?
 C40A C41A 1.529(8) . ?
 C40A C42A 1.515(8) . ?
 C40A C43A 1.528(7) . ?
 C41A H41D 0.9800 . ?
 C41A H41E 0.9800 . ?
 C41A H41F 0.9800 . ?
 C42A H42D 0.9800 . ?
 C42A H42E 0.9800 . ?
 C42A H42F 0.9800 . ?
 C43A H43C 0.9900 . ?
 C43A H43D 0.9900 . ?
 C57A C58A 1.530(9) . ?
 C57A C59A 1.534(9) . ?
 C57A C60A 1.528(8) . ?
 C58A H58D 0.9800 . ?
 C58A H58E 0.9800 . ?
 C58A H58F 0.9800 . ?
 C59A H59D 0.9800 . ?
 C59A H59E 0.9800 . ?
 C59A H59F 0.9800 . ?
 C60A H60C 0.9900 . ?
 C60A H60D 0.9900 . ?
 C60A C64A 1.501(8) . ?
 C61A C62A 1.545(8) . ?
 C61A C63A 1.525(9) . ?
 C61A C64A 1.526(8) . ?
 C62A H62D 0.9800 . ?
 C62A H62E 0.9800 . ?
 C62A H62F 0.9800 . ?
 C63A H63D 0.9800 . ?
 C63A H63E 0.9800 . ?
 C63A H63F 0.9800 . ?
 C64A H64C 0.9900 . ?
 C64A H64D 0.9900 . ?
 C65A C66A 1.535(3) . ?
 C65A C67A 1.536(3) . ?
 C65A C68A 1.530(3) . ?
 C66A H66D 0.9800 . ?
 C66A H66E 0.9800 . ?
 C66A H66F 0.9800 . ?
 C67A H67D 0.9800 . ?
 C67A H67E 0.9800 . ?
 C67A H67F 0.9800 . ?
 C68A H68C 0.9900 . ?
 C68A H68D 0.9900 . ?
 C68A C72A 1.515(3) . ?
 C69A C70A 1.534(3) . ?
 C69A C71A 1.532(3) . ?
 C69A C72A 1.534(3) . ?
 C70A H70D 0.9800 . ?
 C70A H70E 0.9800 . ?
 C70A H70F 0.9800 . ?
 C71A H71D 0.9800 . ?
 C71A H71E 0.9800 . ?
 C71A H71F 0.9800 . ?
 C72A H72C 0.9900 . ?
 C72A H72D 0.9900 . ?
 C81 H81A 0.9800 . ?
 C81 H81B 0.9800 . ?
 C81 H81C 0.9800 . ?
 C81 C82 1.485(10) . ?
 C82 H82A 0.9900 . ?
 C82 H82B 0.9900 . ?
 C82 C83 1.517(10) . ?
 C83 H83A 0.9900 . ?
 C83 H83B 0.9900 . ?
 C83 C84 1.511(9) . ?
 C84 H84A 0.9900 . ?
 C84 H84B 0.9900 . ?
 C84 C85 1.496(10) . ?
 C85 H85A 0.9900 . ?
 C85 H85B 0.9900 . ?
 C85 C86 1.527(9) . ?
 C86 H86A 0.9800 . ?
 C86 H86B 0.9800 . ?
 C86 H86C 0.9800 . ?
 C81A H81D 0.9800 . ?
 C81A H81E 0.9800 . ?
 C81A H81F 0.9800 . ?
 C81A C82A 1.492(5) . ?
 C82A H82C 0.9900 . ?
 C82A H82D 0.9900 . ?
 C82A C83A 1.525(7) . ?
 C83A H83C 0.9900 . ?
 C83A H83D 0.9900 . ?
 C83A C84A 1.520(4) . ?
 C84A H84C 0.9900 . ?
 C84A H84D 0.9900 . ?
 C84A C85A 1.493(5) . ?
 C85A H85C 0.9900 . ?
 C85A H85D 0.9900 . ?
 C85A C86A 1.527(6) . ?
 C86A H86D 0.9800 . ?
 C86A H86E 0.9800 . ?
 C86A H86F 0.9800 . ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 C73 Si1 C74 111.24(11) . . ?
 C75 Si1 C73 111.09(13) . . ?
 C75 Si1 C74 110.96(12) . . ?
 N4 Si1 C73 107.73(18) . . ?
 N4 Si1 C74 106.34(10) . . ?
 N4 Si1 C75 109.29(16) . . ?
 N4A Si1 C73 110.2(17) . . ?
 N4A Si1 C74 102.0(6) . . ?
 N4A Si1 C75 111.1(14) . . ?
 C2 C1 C6 118.43(11) . . ?
 C2 C1 N1 120.8(2) . . ?
 C2 C1 N1A 118.6(16) . . ?
 C6 C1 N1 120.7(2) . . ?
 C6 C1 N1A 122.1(16) . . ?
 C1 C2 C44 127.57(11) . . ?
 C3 C2 C1 120.56(11) . . ?
 C3 C2 C44 111.85(11) . . ?
 C2 C3 C8 112.57(11) . . ?
 C4 C3 C2 120.79(11) . . ?
 C4 C3 C8 126.64(11) . . ?
 C3 C4 H4 120.6 . . ?
 C3 C4 C5 118.74(12) . . ?
 C5 C4 H4 120.6 . . ?
 C4 C5 C12 126.42(12) . . ?
 C6 C5 C4 120.91(11) . . ?
 C6 C5 C12 112.66(11) . . ?
 C1 C6 C15 127.38(12) . . ?
 C5 C6 C1 120.55(11) . . ?
 C5 C6 C15 112.05(11) . . ?
 H7A C7 H7B 108.3 . . ?
 C8 C7 H7A 109.9 . . ?
 C8 C7 H7B 109.9 . . ?
 C8 C7 C44 109.04(10) . . ?
 C44 C7 H7A 109.9 . . ?
 C44 C7 H7B 109.9 . . ?
 C3 C8 C7 102.36(10) . . ?
 C3 C8 C9 111.25(10) . . ?
 C3 C8 C10 111.34(11) . . ?
 C9 C8 C7 112.32(11) . . ?
 C10 C8 C7 110.81(11) . . ?
 C10 C8 C9 108.69(11) . . ?
 C8 C9 H9A 109.5 . . ?
 C8 C9 H9B 109.5 . . ?
 C8 C9 H9C 109.5 . . ?
 H9A C9 H9B 109.5 . . ?
 H9A C9 H9C 109.5 . . ?
 H9B C9 H9C 109.5 . . ?
 C8 C10 H10A 109.5 . . ?
 C8 C10 H10B 109.5 . . ?
 C8 C10 H10C 109.5 . . ?
 H10A C10 H10B 109.5 . . ?
 H10A C10 H10C 109.5 . . ?
 H10B C10 H10C 109.5 . . ?
 H11A C11 H11B 108.1 . . ?
 C12 C11 H11A 109.6 . . ?
 C12 C11 H11B 109.6 . . ?
 C12 C11 C15 110.16(11) . . ?
 C15 C11 H11A 109.6 . . ?
 C15 C11 H11B 109.6 . . ?
 C5 C12 C11 102.81(11) . . ?
 C5 C12 C13 111.85(11) . . ?
 C5 C12 C14 110.74(11) . . ?
 C13 C12 C11 111.24(13) . . ?
 C14 C12 C11 111.63(12) . . ?
 C14 C12 C13 108.53(13) . . ?
 C12 C13 H13A 109.5 . . ?
 C12 C13 H13B 109.5 . . ?
 C12 C13 H13C 109.5 . . ?
 H13A C13 H13B 109.5 . . ?
 H13A C13 H13C 109.5 . . ?
 H13B C13 H13C 109.5 . . ?
 C12 C14 H14A 109.5 . . ?
 C12 C14 H14B 109.5 . . ?
 C12 C14 H14C 109.5 . . ?
 H14A C14 H14B 109.5 . . ?
 H14A C14 H14C 109.5 . . ?
 H14B C14 H14C 109.5 . . ?
 C6 C15 C11 102.14(10) . . ?
 C6 C15 C16 115.27(11) . . ?
 C6 C15 C27 115.45(10) . . ?
 C16 C15 C11 112.83(11) . . ?
 C27 C15 C11 111.06(11) . . ?
 C27 C15 C16 100.54(10) . . ?
 C17 C16 C15 128.43(13) . . ?
 C17 C16 C21 120.08(13) . . ?
 C21 C16 C15 111.38(11) . . ?
 C16 C17 H17 119.7 . . ?
 C16 C17 C18 120.66(13) . . ?
 C18 C17 H17 119.7 . . ?
 C17 C18 C40 117.1(2) . . ?
 C17 C18 C40A 117.8(4) . . ?
 C19 C18 C17 119.30(13) . . ?
 C19 C18 C40 123.5(2) . . ?
 C19 C18 C40A 122.3(4) . . ?
 C18 C19 C36 122.40(18) . . ?
 C18 C19 C36A 122.1(3) . . ?
 C20 C19 C18 119.15(13) . . ?
 C20 C19 C36 118.43(19) . . ?
 C20 C19 C36A 118.6(3) . . ?
 C19 C20 H20 119.6 . . ?
 C21 C20 C19 120.70(13) . . ?
 C21 C20 H20 119.6 . . ?
 C16 C21 C22 108.39(12) . . ?
 C20 C21 C16 120.06(12) . . ?
 C20 C21 C22 131.52(13) . . ?
 C23 C22 C21 131.90(13) . . ?
 C23 C22 C27 119.88(12) . . ?
 C27 C22 C21 108.22(12) . . ?
 C22 C23 H23 119.6 . . ?
 C22 C23 C24 120.89(13) . . ?
 C24 C23 H23 119.6 . . ?
 C23 C24 C25 119.05(13) . . ?
 C23 C24 C32 117.86(13) . . ?
 C25 C24 C32 123.09(12) . . ?
 C24 C25 C28 122.90(13) . . ?
 C26 C25 C24 119.13(12) . . ?
 C26 C25 C28 117.98(13) . . ?
 C25 C26 H26 119.4 . . ?
 C27 C26 C25 121.12(13) . . ?
 C27 C26 H26 119.4 . . ?
 C22 C27 C15 111.35(11) . . ?
 C26 C27 C15 128.73(12) . . ?
 C26 C27 C22 119.79(12) . . ?
 C25 C28 C29 109.35(12) . . ?
 C30 C28 C25 111.03(12) . . ?
 C30 C28 C29 108.26(14) . . ?
 C30 C28 C31 108.00(13) . . ?
 C31 C28 C25 109.73(12) . . ?
 C31 C28 C29 110.45(13) . . ?
 C28 C29 H29A 109.5 . . ?
 C28 C29 H29B 109.5 . . ?
 C28 C29 H29C 109.5 . . ?
 H29A C29 H29B 109.5 . . ?
 H29A C29 H29C 109.5 . . ?
 H29B C29 H29C 109.5 . . ?
 C28 C30 H30A 109.5 . . ?
 C28 C30 H30B 109.5 . . ?
 C28 C30 H30C 109.5 . . ?
 H30A C30 H30B 109.5 . . ?
 H30A C30 H30C 109.5 . . ?
 H30B C30 H30C 109.5 . . ?
 C28 C31 H31A 109.1 . . ?
 C28 C31 H31B 109.1 . . ?
 H31A C31 H31B 107.9 . . ?
 C35 C31 C28 112.34(14) . . ?
 C35 C31 H31A 109.1 . . ?
 C35 C31 H31B 109.1 . . ?
 C33 C32 C24 110.37(13) . . ?
 C33 C32 C34 108.59(15) . . ?
 C34 C32 C24 109.51(13) . . ?
 C35 C32 C24 110.57(13) . . ?
 C35 C32 C33 108.07(14) . . ?
 C35 C32 C34 109.70(13) . . ?
 C32 C33 H33A 109.5 . . ?
 C32 C33 H33B 109.5 . . ?
 C32 C33 H33C 109.5 . . ?
 H33A C33 H33B 109.5 . . ?
 H33A C33 H33C 109.5 . . ?
 H33B C33 H33C 109.5 . . ?
 C32 C34 H34A 109.5 . . ?
 C32 C34 H34B 109.5 . . ?
 C32 C34 H34C 109.5 . . ?
 H34A C34 H34B 109.5 . . ?
 H34A C34 H34C 109.5 . . ?
 H34B C34 H34C 109.5 . . ?
 C31 C35 C32 112.66(14) . . ?
 C31 C35 H35A 109.1 . . ?
 C31 C35 H35B 109.1 . . ?
 C32 C35 H35A 109.1 . . ?
 C32 C35 H35B 109.1 . . ?
 H35A C35 H35B 107.8 . . ?
 C2 C44 C7 101.82(10) . . ?
 C2 C44 C45 114.32(10) . . ?
 C2 C44 C56 117.18(10) . . ?
 C45 C44 C7 113.14(10) . . ?
 C56 C44 C7 110.16(10) . . ?
 C56 C44 C45 100.67(10) . . ?
 C46 C45 C44 129.84(12) . . ?
 C46 C45 C50 119.36(12) . . ?
 C50 C45 C44 110.77(11) . . ?
 C45 C46 H46 119.5 . . ?
 C45 C46 C47 121.03(13) . . ?
 C47 C46 H46 119.5 . . ?
 C46 C47 C57 120.11(19) . . ?
 C46 C47 C57A 112.1(3) . . ?
 C48 C47 C46 119.26(13) . . ?
 C48 C47 C57 120.61(18) . . ?
 C48 C47 C57A 128.5(3) . . ?
 C47 C48 C49 119.27(13) . . ?
 C47 C48 C61 125.37(18) . . ?
 C47 C48 C61A 116.5(4) . . ?
 C49 C48 C61 115.28(18) . . ?
 C49 C48 C61A 124.0(4) . . ?
 C48 C49 H49 119.7 . . ?
 C50 C49 C48 120.54(13) . . ?
 C50 C49 H49 119.7 . . ?
 C45 C50 C51 108.73(11) . . ?
 C49 C50 C45 120.45(13) . . ?
 C49 C50 C51 130.80(13) . . ?
 C52 C51 C50 131.30(12) . . ?
 C52 C51 C56 120.43(12) . . ?
 C56 C51 C50 108.26(11) . . ?
 C51 C52 H52 119.6 . . ?
 C51 C52 C53 120.73(13) . . ?
 C53 C52 H52 119.6 . . ?
 C52 C53 C54 118.93(12) . . ?
 C52 C53 C65 117.7(5) . . ?
 C52 C53 C65A 119.19(14) . . ?
 C54 C53 C65 122.2(5) . . ?
 C54 C53 C65A 121.78(14) . . ?
 C53 C54 C69 124.6(5) . . ?
 C53 C54 C69A 121.21(14) . . ?
 C55 C54 C53 119.25(13) . . ?
 C55 C54 C69 116.2(5) . . ?
 C55 C54 C69A 119.12(14) . . ?
 C54 C55 H55 119.5 . . ?
 C56 C55 C54 120.94(12) . . ?
 C56 C55 H55 119.5 . . ?
 C51 C56 C44 111.09(11) . . ?
 C55 C56 C44 129.59(12) . . ?
 C55 C56 C51 119.30(12) . . ?
 Si1 C73 H73A 109.5 . . ?
 Si1 C73 H73B 109.5 . . ?
 Si1 C73 H73C 109.5 . . ?
 H73A C73 H73B 109.5 . . ?
 H73A C73 H73C 109.5 . . ?
 H73B C73 H73C 109.5 . . ?
 Si1 C74 H74A 109.5 . . ?
 Si1 C74 H74B 109.5 . . ?
 Si1 C74 H74C 109.5 . . ?
 H74A C74 H74B 109.5 . . ?
 H74A C74 H74C 109.5 . . ?
 H74B C74 H74C 109.5 . . ?
 Si1 C75 H75A 109.5 . . ?
 Si1 C75 H75B 109.5 . . ?
 Si1 C75 H75C 109.5 . . ?
 H75A C75 H75B 109.5 . . ?
 H75A C75 H75C 109.5 . . ?
 H75B C75 H75C 109.5 . . ?
 N4 Ge1 N1 79.74(8) . . ?
 C1 N1 Ge1 126.86(14) . . ?
 N2 N1 C1 115.02(18) . . ?
 N2 N1 Ge1 118.12(14) . . ?
 N3 N2 N1 112.4(2) . . ?
 N2 N3 N4 112.9(3) . . ?
 Si1 N4 Ge1 130.24(12) . . ?
 N3 N4 Si1 112.85(16) . . ?
 N3 N4 Ge1 116.77(15) . . ?
 C37 C36 C19 112.1(3) . . ?
 C37 C36 C38 110.2(5) . . ?
 C37 C36 C39 107.4(4) . . ?
 C38 C36 C19 107.3(4) . . ?
 C38 C36 C39 109.3(4) . . ?
 C39 C36 C19 110.6(3) . . ?
 C36 C37 H37A 109.5 . . ?
 C36 C37 H37B 109.5 . . ?
 C36 C37 H37C 109.5 . . ?
 H37A C37 H37B 109.5 . . ?
 H37A C37 H37C 109.5 . . ?
 H37B C37 H37C 109.5 . . ?
 C36 C38 H38A 109.5 . . ?
 C36 C38 H38B 109.5 . . ?
 C36 C38 H38C 109.5 . . ?
 H38A C38 H38B 109.5 . . ?
 H38A C38 H38C 109.5 . . ?
 H38B C38 H38C 109.5 . . ?
 C36 C39 H39A 109.4 . . ?
 C36 C39 H39B 109.4 . . ?
 H39A C39 H39B 108.0 . . ?
 C43 C39 C36 111.3(3) . . ?
 C43 C39 H39A 109.4 . . ?
 C43 C39 H39B 109.4 . . ?
 C41 C40 C18 107.7(5) . . ?
 C41 C40 C42 107.5(4) . . ?
 C41 C40 C43 113.1(4) . . ?
 C42 C40 C18 111.3(5) . . ?
 C42 C40 C43 106.5(4) . . ?
 C43 C40 C18 110.6(4) . . ?
 C40 C41 H41A 109.5 . . ?
 C40 C41 H41B 109.5 . . ?
 C40 C41 H41C 109.5 . . ?
 H41A C41 H41B 109.5 . . ?
 H41A C41 H41C 109.5 . . ?
 H41B C41 H41C 109.5 . . ?
 C40 C42 H42A 109.5 . . ?
 C40 C42 H42B 109.5 . . ?
 C40 C42 H42C 109.5 . . ?
 H42A C42 H42B 109.5 . . ?
 H42A C42 H42C 109.5 . . ?
 H42B C42 H42C 109.5 . . ?
 C39 C43 C40 115.7(4) . . ?
 C39 C43 H43A 108.4 . . ?
 C39 C43 H43B 108.4 . . ?
 C40 C43 H43A 108.4 . . ?
 C40 C43 H43B 108.4 . . ?
 H43A C43 H43B 107.4 . . ?
 C47 C57 C58 109.8(4) . . ?
 C47 C57 C59 108.9(3) . . ?
 C47 C57 C60 112.3(3) . . ?
 C59 C57 C58 108.4(4) . . ?
 C60 C57 C58 107.3(4) . . ?
 C60 C57 C59 110.1(3) . . ?
 C57 C58 H58A 109.5 . . ?
 C57 C58 H58B 109.5 . . ?
 C57 C58 H58C 109.5 . . ?
 H58A C58 H58B 109.5 . . ?
 H58A C58 H58C 109.5 . . ?
 H58B C58 H58C 109.5 . . ?
 C57 C59 H59A 109.5 . . ?
 C57 C59 H59B 109.5 . . ?
 C57 C59 H59C 109.5 . . ?
 H59A C59 H59B 109.5 . . ?
 H59A C59 H59C 109.5 . . ?
 H59B C59 H59C 109.5 . . ?
 C57 C60 H60A 109.2 . . ?
 C57 C60 H60B 109.2 . . ?
 H60A C60 H60B 107.9 . . ?
 C64 C60 C57 112.1(3) . . ?
 C64 C60 H60A 109.2 . . ?
 C64 C60 H60B 109.2 . . ?
 C48 C61 C62 107.7(4) . . ?
 C48 C61 C63 112.8(3) . . ?
 C48 C61 C64 109.4(3) . . ?
 C63 C61 C62 110.1(4) . . ?
 C63 C61 C64 107.6(3) . . ?
 C64 C61 C62 109.2(4) . . ?
 C61 C62 H62A 109.5 . . ?
 C61 C62 H62B 109.5 . . ?
 C61 C62 H62C 109.5 . . ?
 H62A C62 H62B 109.5 . . ?
 H62A C62 H62C 109.5 . . ?
 H62B C62 H62C 109.5 . . ?
 C61 C63 H63A 109.5 . . ?
 C61 C63 H63B 109.5 . . ?
 C61 C63 H63C 109.5 . . ?
 H63A C63 H63B 109.5 . . ?
 H63A C63 H63C 109.5 . . ?
 H63B C63 H63C 109.5 . . ?
 C60 C64 C61 112.4(3) . . ?
 C60 C64 H64A 109.1 . . ?
 C60 C64 H64B 109.1 . . ?
 C61 C64 H64A 109.1 . . ?
 C61 C64 H64B 109.1 . . ?
 H64A C64 H64B 107.9 . . ?
 C53 C65 C66 113.7(12) . . ?
 C53 C65 C67 104.9(13) . . ?
 C53 C65 C68 110.4(11) . . ?
 C66 C65 C67 108.4(12) . . ?
 C68 C65 C66 110.9(12) . . ?
 C68 C65 C67 108.3(12) . . ?
 C65 C66 H66A 109.5 . . ?
 C65 C66 H66B 109.5 . . ?
 C65 C66 H66C 109.5 . . ?
 H66A C66 H66B 109.5 . . ?
 H66A C66 H66C 109.5 . . ?
 H66B C66 H66C 109.5 . . ?
 C65 C67 H67A 109.5 . . ?
 C65 C67 H67B 109.5 . . ?
 C65 C67 H67C 109.5 . . ?
 H67A C67 H67B 109.5 . . ?
 H67A C67 H67C 109.5 . . ?
 H67B C67 H67C 109.5 . . ?
 C65 C68 H68A 108.5 . . ?
 C65 C68 H68B 108.5 . . ?
 H68A C68 H68B 107.5 . . ?
 C72 C68 C65 115.3(11) . . ?
 C72 C68 H68A 108.5 . . ?
 C72 C68 H68B 108.5 . . ?
 C54 C69 C70 110.7(12) . . ?
 C54 C69 C71 108.6(11) . . ?
 C54 C69 C72 108.5(11) . . ?
 C70 C69 C72 110.0(12) . . ?
 C71 C69 C70 110.0(11) . . ?
 C71 C69 C72 109.0(11) . . ?
 C69 C70 H70A 109.5 . . ?
 C69 C70 H70B 109.5 . . ?
 C69 C70 H70C 109.5 . . ?
 H70A C70 H70B 109.5 . . ?
 H70A C70 H70C 109.5 . . ?
 H70B C70 H70C 109.5 . . ?
 C69 C71 H71A 109.5 . . ?
 C69 C71 H71B 109.5 . . ?
 C69 C71 H71C 109.5 . . ?
 H71A C71 H71B 109.5 . . ?
 H71A C71 H71C 109.5 . . ?
 H71B C71 H71C 109.5 . . ?
 C68 C72 C69 112.9(10) . . ?
 C68 C72 H72A 109.0 . . ?
 C68 C72 H72B 109.0 . . ?
 C69 C72 H72A 109.0 . . ?
 C69 C72 H72B 109.0 . . ?
 H72A C72 H72B 107.8 . . ?
 N1A Ge1A N4A 79.1(5) . . ?
 C1 N1A Ge1A 124.1(8) . . ?
 N2A N1A C1 115.4(10) . . ?
 N2A N1A Ge1A 120.2(8) . . ?
 N3A N2A N1A 110.7(9) . . ?
 N2A N3A N4A 112.6(9) . . ?
 Si1 N4A Ge1A 126.4(9) . . ?
 N3A N4A Si1 116.1(10) . . ?
 N3A N4A Ge1A 117.1(8) . . ?
 C19 C36A C37A 109.0(7) . . ?
 C19 C36A C38A 111.8(7) . . ?
 C19 C36A C39A 109.1(6) . . ?
 C37A C36A C38A 107.6(7) . . ?
 C37A C36A C39A 111.8(8) . . ?
 C39A C36A C38A 107.6(7) . . ?
 C36A C37A H37D 109.5 . . ?
 C36A C37A H37E 109.5 . . ?
 C36A C37A H37F 109.5 . . ?
 H37D C37A H37E 109.5 . . ?
 H37D C37A H37F 109.5 . . ?
 H37E C37A H37F 109.5 . . ?
 C36A C38A H38D 109.5 . . ?
 C36A C38A H38E 109.5 . . ?
 C36A C38A H38F 109.5 . . ?
 H38D C38A H38E 109.5 . . ?
 H38D C38A H38F 109.5 . . ?
 H38E C38A H38F 109.5 . . ?
 C36A C39A H39C 109.2 . . ?
 C36A C39A H39D 109.2 . . ?
 H39C C39A H39D 107.9 . . ?
 C43A C39A C36A 112.0(6) . . ?
 C43A C39A H39C 109.2 . . ?
 C43A C39A H39D 109.2 . . ?
 C41A C40A C18 110.7(11) . . ?
 C42A C40A C18 108.7(10) . . ?
 C42A C40A C41A 108.9(8) . . ?
 C42A C40A C43A 111.6(8) . . ?
 C43A C40A C18 112.2(8) . . ?
 C43A C40A C41A 104.6(8) . . ?
 C40A C41A H41D 109.5 . . ?
 C40A C41A H41E 109.5 . . ?
 C40A C41A H41F 109.5 . . ?
 H41D C41A H41E 109.5 . . ?
 H41D C41A H41F 109.5 . . ?
 H41E C41A H41F 109.5 . . ?
 C40A C42A H42D 109.5 . . ?
 C40A C42A H42E 109.5 . . ?
 C40A C42A H42F 109.5 . . ?
 H42D C42A H42E 109.5 . . ?
 H42D C42A H42F 109.5 . . ?
 H42E C42A H42F 109.5 . . ?
 C39A C43A C40A 114.0(7) . . ?
 C39A C43A H43C 108.8 . . ?
 C39A C43A H43D 108.8 . . ?
 C40A C43A H43C 108.8 . . ?
 C40A C43A H43D 108.8 . . ?
 H43C C43A H43D 107.7 . . ?
 C58A C57A C47 109.1(12) . . ?
 C58A C57A C59A 109.8(10) . . ?
 C59A C57A C47 112.8(8) . . ?
 C60A C57A C47 105.5(7) . . ?
 C60A C57A C58A 110.3(9) . . ?
 C60A C57A C59A 109.3(8) . . ?
 C57A C58A H58D 109.5 . . ?
 C57A C58A H58E 109.5 . . ?
 C57A C58A H58F 109.5 . . ?
 H58D C58A H58E 109.5 . . ?
 H58D C58A H58F 109.5 . . ?
 H58E C58A H58F 109.5 . . ?
 C57A C59A H59D 109.5 . . ?
 C57A C59A H59E 109.5 . . ?
 C57A C59A H59F 109.5 . . ?
 H59D C59A H59E 109.5 . . ?
 H59D C59A H59F 109.5 . . ?
 H59E C59A H59F 109.5 . . ?
 C57A C60A H60C 108.9 . . ?
 C57A C60A H60D 108.9 . . ?
 H60C C60A H60D 107.7 . . ?
 C64A C60A C57A 113.5(7) . . ?
 C64A C60A H60C 108.9 . . ?
 C64A C60A H60D 108.9 . . ?
 C62A C61A C48 110.6(12) . . ?
 C63A C61A C48 102.1(8) . . ?
 C63A C61A C62A 107.3(9) . . ?
 C63A C61A C64A 112.0(8) . . ?
 C64A C61A C48 113.8(8) . . ?
 C64A C61A C62A 110.5(10) . . ?
 C61A C62A H62D 109.5 . . ?
 C61A C62A H62E 109.5 . . ?
 C61A C62A H62F 109.5 . . ?
 H62D C62A H62E 109.5 . . ?
 H62D C62A H62F 109.5 . . ?
 H62E C62A H62F 109.5 . . ?
 C61A C63A H63D 109.5 . . ?
 C61A C63A H63E 109.5 . . ?
 C61A C63A H63F 109.5 . . ?
 H63D C63A H63E 109.5 . . ?
 H63D C63A H63F 109.5 . . ?
 H63E C63A H63F 109.5 . . ?
 C60A C64A C61A 114.3(7) . . ?
 C60A C64A H64C 108.7 . . ?
 C60A C64A H64D 108.7 . . ?
 C61A C64A H64C 108.7 . . ?
 C61A C64A H64D 108.7 . . ?
 H64C C64A H64D 107.6 . . ?
 C66A C65A C53 107.0(2) . . ?
 C66A C65A C67A 108.2(2) . . ?
 C67A C65A C53 112.7(2) . . ?
 C68A C65A C53 110.98(18) . . ?
 C68A C65A C66A 110.7(2) . . ?
 C68A C65A C67A 107.3(2) . . ?
 C65A C66A H66D 109.5 . . ?
 C65A C66A H66E 109.5 . . ?
 C65A C66A H66F 109.5 . . ?
 H66D C66A H66E 109.5 . . ?
 H66D C66A H66F 109.5 . . ?
 H66E C66A H66F 109.5 . . ?
 C65A C67A H67D 109.5 . . ?
 C65A C67A H67E 109.5 . . ?
 C65A C67A H67F 109.5 . . ?
 H67D C67A H67E 109.5 . . ?
 H67D C67A H67F 109.5 . . ?
 H67E C67A H67F 109.5 . . ?
 C65A C68A H68C 109.1 . . ?
 C65A C68A H68D 109.1 . . ?
 H68C C68A H68D 107.8 . . ?
 C72A C68A C65A 112.7(2) . . ?
 C72A C68A H68C 109.1 . . ?
 C72A C68A H68D 109.1 . . ?
 C70A C69A C54 112.4(2) . . ?
 C70A C69A C72A 107.3(2) . . ?
 C71A C69A C54 106.8(2) . . ?
 C71A C69A C70A 108.6(2) . . ?
 C71A C69A C72A 110.7(2) . . ?
 C72A C69A C54 111.10(19) . . ?
 C69A C70A H70D 109.5 . . ?
 C69A C70A H70E 109.5 . . ?
 C69A C70A H70F 109.5 . . ?
 H70D C70A H70E 109.5 . . ?
 H70D C70A H70F 109.5 . . ?
 H70E C70A H70F 109.5 . . ?
 C69A C71A H71D 109.5 . . ?
 C69A C71A H71E 109.5 . . ?
 C69A C71A H71F 109.5 . . ?
 H71D C71A H71E 109.5 . . ?
 H71D C71A H71F 109.5 . . ?
 H71E C71A H71F 109.5 . . ?
 C68A C72A C69A 112.3(2) . . ?
 C68A C72A H72C 109.1 . . ?
 C68A C72A H72D 109.1 . . ?
 C69A C72A H72C 109.1 . . ?
 C69A C72A H72D 109.1 . . ?
 H72C C72A H72D 107.9 . . ?
 H81A C81 H81B 109.5 . . ?
 H81A C81 H81C 109.5 . . ?
 H81B C81 H81C 109.5 . . ?
 C82 C81 H81A 109.5 . . ?
 C82 C81 H81B 109.5 . . ?
 C82 C81 H81C 109.5 . . ?
 C81 C82 H82A 108.2 . . ?
 C81 C82 H82B 108.2 . . ?
 C81 C82 C83 116.3(10) . . ?
 H82A C82 H82B 107.4 . . ?
 C83 C82 H82A 108.2 . . ?
 C83 C82 H82B 108.2 . . ?
 C82 C83 H83A 107.9 . . ?
 C82 C83 H83B 107.9 . . ?
 H83A C83 H83B 107.2 . . ?
 C84 C83 C82 117.5(10) . . ?
 C84 C83 H83A 107.9 . . ?
 C84 C83 H83B 107.9 . . ?
 C83 C84 H84A 109.1 . . ?
 C83 C84 H84B 109.1 . . ?
 H84A C84 H84B 107.9 . . ?
 C85 C84 C83 112.4(10) . . ?
 C85 C84 H84A 109.1 . . ?
 C85 C84 H84B 109.1 . . ?
 C84 C85 H85A 108.6 . . ?
 C84 C85 H85B 108.6 . . ?
 C84 C85 C86 114.5(10) . . ?
 H85A C85 H85B 107.6 . . ?
 C86 C85 H85A 108.6 . . ?
 C86 C85 H85B 108.6 . . ?
 C85 C86 H86A 109.5 . . ?
 C85 C86 H86B 109.5 . . ?
 C85 C86 H86C 109.5 . . ?
 H86A C86 H86B 109.5 . . ?
 H86A C86 H86C 109.5 . . ?
 H86B C86 H86C 109.5 . . ?
 H81D C81A H81E 109.5 . . ?
 H81D C81A H81F 109.5 . . ?
 H81E C81A H81F 109.5 . . ?
 C82A C81A H81D 109.5 . . ?
 C82A C81A H81E 109.5 . . ?
 C82A C81A H81F 109.5 . . ?
 C81A C82A H82C 108.5 . . ?
 C81A C82A H82D 108.5 . . ?
 C81A C82A C83A 114.9(3) . . ?
 H82C C82A H82D 107.5 . . ?
 C83A C82A H82C 108.5 . . ?
 C83A C82A H82D 108.5 . . ?
 C82A C83A H83C 108.9 . . ?
 C82A C83A H83D 108.9 . . ?
 H83C C83A H83D 107.7 . . ?
 C84A C83A C82A 113.5(3) . . ?
 C84A C83A H83C 108.9 . . ?
 C84A C83A H83D 108.9 . . ?
 C83A C84A H84C 108.7 . . ?
 C83A C84A H84D 108.7 . . ?
 H84C C84A H84D 107.6 . . ?
 C85A C84A C83A 114.4(3) . . ?
 C85A C84A H84C 108.7 . . ?
 C85A C84A H84D 108.7 . . ?
 C84A C85A H85C 108.8 . . ?
 C84A C85A H85D 108.8 . . ?
 C84A C85A C86A 113.7(3) . . ?
 H85C C85A H85D 107.7 . . ?
 C86A C85A H85C 108.8 . . ?
 C86A C85A H85D 108.8 . . ?
 C85A C86A H86D 109.5 . . ?
 C85A C86A H86E 109.5 . . ?
 C85A C86A H86F 109.5 . . ?
 H86D C86A H86E 109.5 . . ?
 H86D C86A H86F 109.5 . . ?
 H86E C86A H86F 109.5 . . ?

loop_
  _geom_torsion_atom_site_label_1
  _geom_torsion_atom_site_label_2
  _geom_torsion_atom_site_label_3
  _geom_torsion_atom_site_label_4
  _geom_torsion
  _geom_torsion_site_symmetry_1
  _geom_torsion_site_symmetry_2
  _geom_torsion_site_symmetry_3
  _geom_torsion_site_symmetry_4
  _geom_torsion_publ_flag
 C1 C2 C3 C4 -0.29(18) . . . . ?
 C1 C2 C3 C8 180.00(11) . . . . ?
 C1 C2 C44 C7 -171.43(12) . . . . ?
 C1 C2 C44 C45 66.21(16) . . . . ?
 C1 C2 C44 C56 -51.22(17) . . . . ?
 C1 C6 C15 C11 179.21(13) . . . . ?
 C1 C6 C15 C16 -58.08(17) . . . . ?
 C1 C6 C15 C27 58.58(17) . . . . ?
 C1 N1 N2 N3 179.6(3) . . . . ?
 C1 N1A N2A N3A -179(2) . . . . ?
 C2 C1 C6 C5 1.33(18) . . . . ?
 C2 C1 C6 C15 179.81(11) . . . . ?
 C2 C1 N1 Ge1 -87.0(4) . . . . ?
 C2 C1 N1 N2 93.4(3) . . . . ?
 C2 C1 N1A Ge1A 105(2) . . . . ?
 C2 C1 N1A N2A -82(3) . . . . ?
 C2 C3 C4 C5 1.13(19) . . . . ?
 C2 C3 C8 C7 -7.98(14) . . . . ?
 C2 C3 C8 C9 112.18(13) . . . . ?
 C2 C3 C8 C10 -126.42(12) . . . . ?
 C2 C44 C45 C46 50.56(18) . . . . ?
 C2 C44 C45 C50 -131.54(12) . . . . ?
 C2 C44 C56 C51 131.62(12) . . . . ?
 C2 C44 C56 C55 -50.20(18) . . . . ?
 C3 C2 C44 C7 10.45(13) . . . . ?
 C3 C2 C44 C45 -111.90(12) . . . . ?
 C3 C2 C44 C56 130.67(12) . . . . ?
 C3 C4 C5 C6 -0.73(19) . . . . ?
 C3 C4 C5 C12 -179.53(12) . . . . ?
 C4 C3 C8 C7 172.32(12) . . . . ?
 C4 C3 C8 C9 -67.52(17) . . . . ?
 C4 C3 C8 C10 53.89(17) . . . . ?
 C4 C5 C6 C1 -0.51(19) . . . . ?
 C4 C5 C6 C15 -179.20(11) . . . . ?
 C4 C5 C12 C11 -178.48(13) . . . . ?
 C4 C5 C12 C13 -59.04(19) . . . . ?
 C4 C5 C12 C14 62.16(17) . . . . ?
 C5 C6 C15 C11 -2.20(14) . . . . ?
 C5 C6 C15 C16 120.51(12) . . . . ?
 C5 C6 C15 C27 -122.83(12) . . . . ?
 C6 C1 C2 C3 -0.94(18) . . . . ?
 C6 C1 C2 C44 -178.91(11) . . . . ?
 C6 C1 N1 Ge1 90.0(3) . . . . ?
 C6 C1 N1 N2 -89.6(3) . . . . ?
 C6 C1 N1A Ge1A -86(3) . . . . ?
 C6 C1 N1A N2A 87(3) . . . . ?
 C6 C5 C12 C11 2.64(14) . . . . ?
 C6 C5 C12 C13 122.08(14) . . . . ?
 C6 C5 C12 C14 -116.72(13) . . . . ?
 C6 C15 C16 C17 -55.71(19) . . . . ?
 C6 C15 C16 C21 128.25(12) . . . . ?
 C6 C15 C27 C22 -127.12(12) . . . . ?
 C6 C15 C27 C26 56.96(19) . . . . ?
 C7 C44 C45 C46 -65.39(17) . . . . ?
 C7 C44 C45 C50 112.51(12) . . . . ?
 C7 C44 C56 C51 -112.68(12) . . . . ?
 C7 C44 C56 C55 65.51(17) . . . . ?
 C8 C3 C4 C5 -179.20(12) . . . . ?
 C8 C7 C44 C2 -15.26(13) . . . . ?
 C8 C7 C44 C45 107.91(12) . . . . ?
 C8 C7 C44 C56 -140.29(11) . . . . ?
 C11 C15 C16 C17 61.11(18) . . . . ?
 C11 C15 C16 C21 -114.93(13) . . . . ?
 C11 C15 C27 C22 117.23(13) . . . . ?
 C11 C15 C27 C26 -58.69(18) . . . . ?
 C12 C5 C6 C1 178.45(11) . . . . ?
 C12 C5 C6 C15 -0.25(15) . . . . ?
 C12 C11 C15 C6 3.84(15) . . . . ?
 C12 C11 C15 C16 -120.51(13) . . . . ?
 C12 C11 C15 C27 127.48(12) . . . . ?
 C15 C11 C12 C5 -3.98(15) . . . . ?
 C15 C11 C12 C13 -123.84(13) . . . . ?
 C15 C11 C12 C14 114.76(13) . . . . ?
 C15 C16 C17 C18 -174.09(13) . . . . ?
 C15 C16 C21 C20 175.12(12) . . . . ?
 C15 C16 C21 C22 -3.24(15) . . . . ?
 C16 C15 C27 C22 -2.41(14) . . . . ?
 C16 C15 C27 C26 -178.33(13) . . . . ?
 C16 C17 C18 C19 -0.3(2) . . . . ?
 C16 C17 C18 C40 175.8(3) . . . . ?
 C16 C17 C18 C40A -172.0(5) . . . . ?
 C16 C21 C22 C23 -178.77(15) . . . . ?
 C16 C21 C22 C27 1.57(15) . . . . ?
 C17 C16 C21 C20 -1.3(2) . . . . ?
 C17 C16 C21 C22 -179.65(13) . . . . ?
 C17 C18 C19 C20 -1.4(2) . . . . ?
 C17 C18 C19 C36 176.9(2) . . . . ?
 C17 C18 C19 C36A 174.4(4) . . . . ?
 C17 C18 C40 C41 67.3(4) . . . . ?
 C17 C18 C40 C42 -50.4(4) . . . . ?
 C17 C18 C40 C43 -168.6(3) . . . . ?
 C17 C18 C40A C41A 64.5(9) . . . . ?
 C17 C18 C40A C42A -55.2(8) . . . . ?
 C17 C18 C40A C43A -179.1(5) . . . . ?
 C18 C19 C20 C21 1.8(2) . . . . ?
 C18 C19 C36 C37 139.2(3) . . . . ?
 C18 C19 C36 C38 -99.7(4) . . . . ?
 C18 C19 C36 C39 19.5(4) . . . . ?
 C18 C19 C36A C37A 105.1(5) . . . . ?
 C18 C19 C36A C38A -136.1(5) . . . . ?
 C18 C19 C36A C39A -17.3(7) . . . . ?
 C18 C40 C43 C39 -37.9(5) . . . . ?
 C18 C40A C43A C39A 27.0(10) . . . . ?
 C19 C18 C40 C41 -116.8(3) . . . . ?
 C19 C18 C40 C42 125.5(3) . . . . ?
 C19 C18 C40 C43 7.3(5) . . . . ?
 C19 C18 C40A C41A -107.0(8) . . . . ?
 C19 C18 C40A C42A 133.3(6) . . . . ?
 C19 C18 C40A C43A 9.4(10) . . . . ?
 C19 C20 C21 C16 -0.4(2) . . . . ?
 C19 C20 C21 C22 177.47(14) . . . . ?
 C19 C36 C39 C43 -48.1(4) . . . . ?
 C19 C36A C39A C43A 53.3(8) . . . . ?
 C20 C19 C36 C37 -42.5(4) . . . . ?
 C20 C19 C36 C38 78.7(4) . . . . ?
 C20 C19 C36 C39 -162.2(2) . . . . ?
 C20 C19 C36A C37A -79.1(6) . . . . ?
 C20 C19 C36A C38A 39.7(7) . . . . ?
 C20 C19 C36A C39A 158.5(4) . . . . ?
 C20 C21 C22 C23 3.1(3) . . . . ?
 C20 C21 C22 C27 -176.53(14) . . . . ?
 C21 C16 C17 C18 1.7(2) . . . . ?
 C21 C22 C23 C24 -178.20(14) . . . . ?
 C21 C22 C27 C15 0.69(15) . . . . ?
 C21 C22 C27 C26 177.02(12) . . . . ?
 C22 C23 C24 C25 2.0(2) . . . . ?
 C22 C23 C24 C32 -178.33(13) . . . . ?
 C23 C22 C27 C15 -179.02(12) . . . . ?
 C23 C22 C27 C26 -2.7(2) . . . . ?
 C23 C24 C25 C26 -4.2(2) . . . . ?
 C23 C24 C25 C28 176.12(13) . . . . ?
 C23 C24 C32 C33 50.59(19) . . . . ?
 C23 C24 C32 C34 -68.90(17) . . . . ?
 C23 C24 C32 C35 170.10(14) . . . . ?
 C24 C25 C26 C27 3.0(2) . . . . ?
 C24 C25 C28 C29 106.63(16) . . . . ?
 C24 C25 C28 C30 -133.98(15) . . . . ?
 C24 C25 C28 C31 -14.66(19) . . . . ?
 C24 C32 C35 C31 42.86(19) . . . . ?
 C25 C24 C32 C33 -129.80(16) . . . . ?
 C25 C24 C32 C34 110.71(16) . . . . ?
 C25 C24 C32 C35 -10.3(2) . . . . ?
 C25 C26 C27 C15 176.07(13) . . . . ?
 C25 C26 C27 C22 0.5(2) . . . . ?
 C25 C28 C31 C35 47.17(18) . . . . ?
 C26 C25 C28 C29 -73.04(17) . . . . ?
 C26 C25 C28 C30 46.35(17) . . . . ?
 C26 C25 C28 C31 165.67(13) . . . . ?
 C27 C15 C16 C17 179.46(14) . . . . ?
 C27 C15 C16 C21 3.42(14) . . . . ?
 C27 C22 C23 C24 1.4(2) . . . . ?
 C28 C25 C26 C27 -177.30(12) . . . . ?
 C28 C31 C35 C32 -64.36(19) . . . . ?
 C29 C28 C31 C35 -73.45(17) . . . . ?
 C30 C28 C31 C35 168.33(13) . . . . ?
 C32 C24 C25 C26 176.19(13) . . . . ?
 C32 C24 C25 C28 -3.5(2) . . . . ?
 C33 C32 C35 C31 163.75(15) . . . . ?
 C34 C32 C35 C31 -78.02(17) . . . . ?
 C44 C2 C3 C4 177.98(11) . . . . ?
 C44 C2 C3 C8 -1.74(14) . . . . ?
 C44 C7 C8 C3 14.37(13) . . . . ?
 C44 C7 C8 C9 -105.04(12) . . . . ?
 C44 C7 C8 C10 133.17(11) . . . . ?
 C44 C45 C46 C47 177.01(12) . . . . ?
 C44 C45 C50 C49 -179.96(12) . . . . ?
 C44 C45 C50 C51 1.51(15) . . . . ?
 C45 C44 C56 C51 7.01(13) . . . . ?
 C45 C44 C56 C55 -174.81(13) . . . . ?
 C45 C46 C47 C48 3.0(2) . . . . ?
 C45 C46 C47 C57 -175.1(2) . . . . ?
 C45 C46 C47 C57A 179.3(5) . . . . ?
 C45 C50 C51 C52 -175.26(14) . . . . ?
 C45 C50 C51 C56 3.13(15) . . . . ?
 C46 C45 C50 C49 -1.8(2) . . . . ?
 C46 C45 C50 C51 179.66(12) . . . . ?
 C46 C47 C48 C49 -2.8(2) . . . . ?
 C46 C47 C48 C61 173.6(2) . . . . ?
 C46 C47 C48 C61A -177.2(5) . . . . ?
 C46 C47 C57 C58 48.6(4) . . . . ?
 C46 C47 C57 C59 -70.0(3) . . . . ?
 C46 C47 C57 C60 167.8(2) . . . . ?
 C46 C47 C57A C58A 77.1(9) . . . . ?
 C46 C47 C57A C59A -45.2(9) . . . . ?
 C46 C47 C57A C60A -164.5(5) . . . . ?
 C47 C48 C49 C50 0.3(2) . . . . ?
 C47 C48 C61 C62 110.6(4) . . . . ?
 C47 C48 C61 C63 -127.7(3) . . . . ?
 C47 C48 C61 C64 -8.0(4) . . . . ?
 C47 C48 C61A C62A 132.7(8) . . . . ?
 C47 C48 C61A C63A -113.3(6) . . . . ?
 C47 C48 C61A C64A 7.6(9) . . . . ?
 C47 C57 C60 C64 44.9(4) . . . . ?
 C47 C57A C60A C64A -45.2(10) . . . . ?
 C48 C47 C57 C58 -129.6(3) . . . . ?
 C48 C47 C57 C59 111.8(3) . . . . ?
 C48 C47 C57 C60 -10.3(4) . . . . ?
 C48 C47 C57A C58A -107.1(9) . . . . ?
 C48 C47 C57A C59A 130.6(7) . . . . ?
 C48 C47 C57A C60A 11.4(9) . . . . ?
 C48 C49 C50 C45 2.0(2) . . . . ?
 C48 C49 C50 C51 -179.81(14) . . . . ?
 C48 C61 C64 C60 42.5(4) . . . . ?
 C48 C61A C64A C60A -42.2(11) . . . . ?
 C49 C48 C61 C62 -72.8(4) . . . . ?
 C49 C48 C61 C63 48.8(3) . . . . ?
 C49 C48 C61 C64 168.6(2) . . . . ?
 C49 C48 C61A C62A -41.4(10) . . . . ?
 C49 C48 C61A C63A 72.6(8) . . . . ?
 C49 C48 C61A C64A -166.6(5) . . . . ?
 C49 C50 C51 C52 6.4(3) . . . . ?
 C49 C50 C51 C56 -175.20(14) . . . . ?
 C50 C45 C46 C47 -0.7(2) . . . . ?
 C50 C51 C52 C53 -178.12(14) . . . . ?
 C50 C51 C56 C44 -6.56(14) . . . . ?
 C50 C51 C56 C55 175.04(12) . . . . ?
 C51 C52 C53 C54 2.4(2) . . . . ?
 C51 C52 C53 C65 -165.4(7) . . . . ?
 C51 C52 C53 C65A -173.86(15) . . . . ?
 C52 C51 C56 C44 172.04(12) . . . . ?
 C52 C51 C56 C55 -6.36(19) . . . . ?
 C52 C53 C54 C55 -5.7(2) . . . . ?
 C52 C53 C54 C69 173.8(6) . . . . ?
 C52 C53 C54 C69A 166.80(16) . . . . ?
 C52 C53 C65 C66 46.5(13) . . . . ?
 C52 C53 C65 C67 -71.7(11) . . . . ?
 C52 C53 C65 C68 171.8(8) . . . . ?
 C52 C53 C65A C66A 81.2(2) . . . . ?
 C52 C53 C65A C67A -37.5(3) . . . . ?
 C52 C53 C65A C68A -157.88(18) . . . . ?
 C53 C54 C55 C56 3.1(2) . . . . ?
 C53 C54 C69 C70 114.6(9) . . . . ?
 C53 C54 C69 C71 -124.6(8) . . . . ?
 C53 C54 C69 C72 -6.2(11) . . . . ?
 C53 C54 C69A C70A 147.4(2) . . . . ?
 C53 C54 C69A C71A -93.7(2) . . . . ?
 C53 C54 C69A C72A 27.1(3) . . . . ?
 C53 C65 C68 C72 34.1(16) . . . . ?
 C53 C65A C68A C72A -47.1(3) . . . . ?
 C54 C53 C65 C66 -120.9(10) . . . . ?
 C54 C53 C65 C67 120.9(10) . . . . ?
 C54 C53 C65 C68 4.5(13) . . . . ?
 C54 C53 C65A C66A -95.0(2) . . . . ?
 C54 C53 C65A C67A 146.3(2) . . . . ?
 C54 C53 C65A C68A 25.9(3) . . . . ?
 C54 C55 C56 C44 -175.08(12) . . . . ?
 C54 C55 C56 C51 3.0(2) . . . . ?
 C54 C69 C72 C68 43.8(15) . . . . ?
 C54 C69A C72A C68A -48.2(3) . . . . ?
 C55 C54 C69 C70 -65.9(10) . . . . ?
 C55 C54 C69 C71 55.0(10) . . . . ?
 C55 C54 C69 C72 173.4(7) . . . . ?
 C55 C54 C69A C70A -40.1(3) . . . . ?
 C55 C54 C69A C71A 78.9(2) . . . . ?
 C55 C54 C69A C72A -160.33(19) . . . . ?
 C56 C44 C45 C46 177.09(13) . . . . ?
 C56 C44 C45 C50 -5.00(13) . . . . ?
 C56 C51 C52 C53 3.7(2) . . . . ?
 C73 Si1 N4 Ge1 109.9(3) . . . . ?
 C73 Si1 N4 N3 -65.6(4) . . . . ?
 C73 Si1 N4A Ge1A -69(3) . . . . ?
 C73 Si1 N4A N3A 103(3) . . . . ?
 C74 Si1 N4 Ge1 -9.5(4) . . . . ?
 C74 Si1 N4 N3 175.0(3) . . . . ?
 C74 Si1 N4A Ge1A 172(3) . . . . ?
 C74 Si1 N4A N3A -15(4) . . . . ?
 C75 Si1 N4 Ge1 -129.3(3) . . . . ?
 C75 Si1 N4 N3 55.2(4) . . . . ?
 C75 Si1 N4A Ge1A 54(4) . . . . ?
 C75 Si1 N4A N3A -134(3) . . . . ?
 Ge1 N1 N2 N3 -0.1(4) . . . . ?
 N1 C1 C2 C3 176.14(15) . . . . ?
 N1 C1 C2 C44 -1.8(2) . . . . ?
 N1 C1 C6 C5 -175.75(14) . . . . ?
 N1 C1 C6 C15 2.7(2) . . . . ?
 N1 Ge1 N4 Si1 -176.2(4) . . . . ?
 N1 Ge1 N4 N3 -0.8(4) . . . . ?
 N1 N2 N3 N4 -0.6(4) . . . . ?
 N2 N3 N4 Si1 177.2(3) . . . . ?
 N2 N3 N4 Ge1 1.0(5) . . . . ?
 N4 Ge1 N1 C1 -179.1(4) . . . . ?
 N4 Ge1 N1 N2 0.5(3) . . . . ?
 C36 C19 C20 C21 -176.6(2) . . . . ?
 C36 C39 C43 C40 60.7(5) . . . . ?
 C37 C36 C39 C43 -170.6(4) . . . . ?
 C38 C36 C39 C43 69.8(5) . . . . ?
 C40 C18 C19 C20 -177.2(3) . . . . ?
 C40 C18 C19 C36 1.1(4) . . . . ?
 C41 C40 C43 C39 83.1(5) . . . . ?
 C42 C40 C43 C39 -159.0(4) . . . . ?
 C57 C47 C48 C49 175.4(2) . . . . ?
 C57 C47 C48 C61 -8.2(3) . . . . ?
 C57 C60 C64 C61 -63.2(4) . . . . ?
 C58 C57 C60 C64 165.6(4) . . . . ?
 C59 C57 C60 C64 -76.6(4) . . . . ?
 C61 C48 C49 C50 -176.5(2) . . . . ?
 C62 C61 C64 C60 -75.2(5) . . . . ?
 C63 C61 C64 C60 165.3(3) . . . . ?
 C65 C53 C54 C55 161.5(8) . . . . ?
 C65 C53 C54 C69 -19.0(10) . . . . ?
 C65 C68 C72 C69 -61.1(19) . . . . ?
 C66 C65 C68 C72 161.0(14) . . . . ?
 C67 C65 C68 C72 -80.2(18) . . . . ?
 C69 C54 C55 C56 -176.5(6) . . . . ?
 C70 C69 C72 C68 -77.4(18) . . . . ?
 C71 C69 C72 C68 161.9(15) . . . . ?
 Ge1A N1A N2A N3A -6(4) . . . . ?
 N1A C1 C2 C3 168.6(7) . . . . ?
 N1A C1 C2 C44 -9.3(7) . . . . ?
 N1A C1 C6 C5 -167.9(5) . . . . ?
 N1A C1 C6 C15 10.6(6) . . . . ?
 N1A Ge1A N4A Si1 173(4) . . . . ?
 N1A Ge1A N4A N3A 1(3) . . . . ?
 N1A N2A N3A N4A 6(4) . . . . ?
 N2A N3A N4A Si1 -177(2) . . . . ?
 N2A N3A N4A Ge1A -4(4) . . . . ?
 N4A Ge1A N1A C1 176(3) . . . . ?
 N4A Ge1A N1A N2A 3(3) . . . . ?
 C36A C19 C20 C21 -174.1(4) . . . . ?
 C36A C39A C43A C40A -60.2(10) . . . . ?
 C37A C36A C39A C43A -67.3(10) . . . . ?
 C38A C36A C39A C43A 174.7(7) . . . . ?
 C40A C18 C19 C20 169.9(6) . . . . ?
 C40A C18 C19 C36A -14.3(7) . . . . ?
 C41A C40A C43A C39A 147.1(10) . . . . ?
 C42A C40A C43A C39A -95.3(10) . . . . ?
 C57A C47 C48 C49 -178.4(6) . . . . ?
 C57A C47 C48 C61A 7.1(7) . . . . ?
 C57A C60A C64A C61A 64.9(12) . . . . ?
 C58A C57A C60A C64A 72.4(14) . . . . ?
 C59A C57A C60A C64A -166.7(10) . . . . ?
 C61A C48 C49 C50 174.3(5) . . . . ?
 C62A C61A C64A C60A -167.4(11) . . . . ?
 C63A C61A C64A C60A 73.0(12) . . . . ?
 C65A C53 C54 C55 170.46(16) . . . . ?
 C65A C53 C54 C69A -17.0(2) . . . . ?
 C65A C68A C72A C69A 61.1(3) . . . . ?
 C66A C65A C68A C72A 71.5(3) . . . . ?
 C67A C65A C68A C72A -170.6(2) . . . . ?
 C69A C54 C55 C56 -169.63(16) . . . . ?
 C70A C69A C72A C68A -171.5(3) . . . . ?
 C71A C69A C72A C68A 70.2(3) . . . . ?
 C81 C82 C83 C84 61.5(18) . . . . ?
 C82 C83 C84 C85 -174.7(15) . . . . ?
 C83 C84 C85 C86 171.6(14) . . . . ?
 C81A C82A C83A C84A -64.5(4) . . . . ?
 C82A C83A C84A C85A -172.4(4) . . . . ?
 C83A C84A C85A C86A 179.6(4) . . . . ?

_olex2_submission_special_instructions  'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
