data_2
_audit_creation_date               2025-06-08
_audit_creation_method
;
Olex2 1.5
(compiled 2024.02.16 svn.r378c4104 for OlexSys, GUI svn.r6928)
;
_shelx_SHELXL_version_number       '2019/3'
_audit_contact_author_address      ?
_audit_contact_author_email        ?
_audit_contact_author_name         ''
_audit_contact_author_phone        ?
_publ_contact_author_id_orcid      ?
_publ_section_references
;
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.
;
_chemical_name_common              ?
_chemical_name_systematic          ?
_chemical_formula_moiety           'C72 H89 Ge N3, C6 H14'
_chemical_formula_sum              'C78 H103 Ge N3'
_chemical_formula_weight           1155.22
_chemical_melting_point            ?
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'C' 'C' 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Ge' 'Ge' -1.0885 0.8855
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N' 'N' 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system        'triclinic'
_space_group_IT_number             2
_space_group_name_H-M_alt          'P -1'
_space_group_name_Hall             '-P 1'
loop_
  _space_group_symop_operation_xyz
 'x, y, z'
 '-x, -y, -z'

_cell_length_a                     14.3609(2)
_cell_length_b                     15.6097(2)
_cell_length_c                     16.7560(2)
_cell_angle_alpha                  99.1690(10)
_cell_angle_beta                   113.5330(10)
_cell_angle_gamma                  94.5230(10)
_cell_volume                       3357.39(8)
_cell_formula_units_Z              2
_cell_measurement_reflns_used      28353
_cell_measurement_temperature      100.00(10)
_cell_measurement_theta_max        71.9720
_cell_measurement_theta_min        2.8830
_shelx_estimated_absorpt_T_max     0.929
_shelx_estimated_absorpt_T_min     0.842
_exptl_absorpt_coefficient_mu      0.941
_exptl_absorpt_correction_T_max    1.00000
_exptl_absorpt_correction_T_min    0.95462
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.43.98a (Rigaku Oxford Diffraction, 2023)
Empirical absorption correction using spherical harmonics,
implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details     ?
_exptl_crystal_colour              yellow
_exptl_crystal_colour_primary      yellow
_exptl_crystal_density_diffrn      1.143
_exptl_crystal_density_meas        ?
_exptl_crystal_density_method      ?
_exptl_crystal_description         plate
_exptl_crystal_F_000               1248
_exptl_crystal_size_max            0.19
_exptl_crystal_size_mid            0.14
_exptl_crystal_size_min            0.08
_exptl_transmission_factor_max     ?
_exptl_transmission_factor_min     ?
_diffrn_reflns_av_R_equivalents    0.0195
_diffrn_reflns_av_unetI/netI       0.0211
_diffrn_reflns_Laue_measured_fraction_full  0.998
_diffrn_reflns_Laue_measured_fraction_max  0.976
_diffrn_reflns_limit_h_max         17
_diffrn_reflns_limit_h_min         -17
_diffrn_reflns_limit_k_max         19
_diffrn_reflns_limit_k_min         -18
_diffrn_reflns_limit_l_max         12
_diffrn_reflns_limit_l_min         -20
_diffrn_reflns_number              36367
_diffrn_reflns_point_group_measured_fraction_full  0.998
_diffrn_reflns_point_group_measured_fraction_max  0.976
_diffrn_reflns_theta_full          67.684
_diffrn_reflns_theta_max           71.915
_diffrn_reflns_theta_min           2.904
_diffrn_ambient_temperature        100.15
_diffrn_detector_area_resol_mean   10.0000
_diffrn_detector_type              HyPix
_diffrn_measured_fraction_theta_full  0.998
_diffrn_measured_fraction_theta_max  0.976
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
--------------------------------------------------------------------------
  1  ω    -59.00 -20.00   0.50    0.05    --  -97.00  50.00 150.00   78
  2  ω    -58.00 -15.00   0.50    0.05    --  -97.00  50.00 120.00   86
  3  ω    -59.00 -15.00   0.50    0.05    --  -97.00  50.00  90.00   88
  4  ω    -46.00 -16.00   0.50    0.05    --  -97.00  38.00   0.00   60
  5  ω    -42.00 -14.00   0.50    0.05    --  -97.00  38.00-120.00   56
  6  ω    -56.00 -18.00   0.50    0.05    --  -97.00  50.00-180.00   76
  7  ω    -45.00 -15.00   0.50    0.05    --  -97.00  38.00-180.00   60
  8  ω    -52.00 -27.00   0.50    0.05    --  -97.00  50.00-150.00   50
  9  ω    -45.00 -16.00   0.50    0.05    --  -97.00  38.00 -90.00   58
 10  ω    -23.00  25.00   0.50    0.05    --  -56.24  19.00-150.00   96
 11  ω    -46.00 -16.00   0.50    0.05    --  -97.00  38.00 -60.00   60
 12  ω    -46.00 -21.00   0.50    0.05    --  -97.00  38.00  90.00   50
 13  ω    -27.00  25.00   0.50    0.05    --  -56.24  19.00 150.00  104
 14  ω     -5.00  21.00   0.50    0.05    --  -56.24  19.00  90.00   52
 15  ω    -46.00 -20.00   0.50    0.05    --    0.00 105.00 -33.00   52
 16  ω    -88.00 -54.00   0.50    0.05    --    0.00 179.00   0.00   68
 17  ω     44.00  97.00   0.50    0.05    --  112.49 179.00  60.00  106
 18  ω     94.00 136.00   0.50    0.05    --   56.24 105.00 -33.00   84
 19  ω     48.00 136.00   0.50    0.05    --  112.49 179.00 120.00  176
 20  ω    115.00 175.00   0.50    0.05    --  112.49 112.00  60.00  120
 21  ω    120.00 170.00   0.50    0.05    --  112.49 112.00  30.00  100
 22  ω     86.00 121.00   0.50    0.05    --  112.49 105.00 -33.00   70
 23  ω     20.00 139.00   0.50    0.05    --  112.49  12.00 -30.00  238
 24  ω     17.00 116.00   0.50    0.05    --  112.49  12.00-180.00  198
 25  ω    150.00 175.00   0.50    0.05    --  112.49  12.00-180.00   50
 26  ω    142.00 167.00   0.50    0.05    --  112.49  12.00 -30.00   50
 27  ω     19.00  81.00   0.50    0.05    --    0.00  77.00  30.00  124
 28  ω    -44.00  -4.00   0.50    0.05    --    0.00  77.00  30.00   80
 29  ω    -37.00  23.00   0.50    0.05    --   56.24 -19.00-120.00  120
 30  ω     30.00  72.00   0.50    0.05    --  112.49 -64.00-180.00   84
 31  ω     35.00  68.00   0.50    0.05    --  112.49 -64.00-120.00   66
 32  ω     30.00  72.00   0.50    0.05    --  112.49 -64.00 -90.00   84
 33  ω     33.00  73.00   0.50    0.05    --  112.49 -64.00 -30.00   80
 34  ω     30.00  73.00   0.50    0.05    --  112.49 -64.00 -60.00   86
 35  ω     34.00  59.00   0.50    0.05    --  112.49 -64.00  30.00   50
 36  ω     66.00  91.00   0.50    0.05    --  112.49 -77.00  90.00   50
 37  ω     62.00  88.00   0.50    0.05    --  112.49 -77.00 120.00   52
 38  ω     32.00  57.00   0.50    0.05    --  112.49 -64.00 150.00   50
 39  ω     23.00  58.00   0.50    0.05    --  112.49 -77.00  90.00   70
 40  ω     43.00  69.00   0.50    0.05    --  112.49 -64.00  90.00   52
 41  ω    -38.00  23.00   0.50    0.05    --   56.24 -19.00 120.00  122
 42  ω    -31.00  40.00   0.50    0.05    --   56.24 -38.00   0.00  142
 43  ω    -38.00  21.00   0.50    0.05    --   56.24 -19.00 -60.00  118
 44  ω     31.00  62.00   0.50    0.05    --  112.49 -64.00-150.00   62
 45  ω     26.00 106.00   0.50    0.05    --  112.49-112.00-150.00  160
 46  ω     70.00  96.00   0.50    0.05    --  112.49-112.00-180.00   52
 47  ω     42.00  68.00   0.50    0.05    --  112.49-112.00-180.00   52
 48  ω     77.00 106.00   0.50    0.05    --  112.49-105.00-133.00   58
 49  ω     81.00 108.00   0.50    0.05    --  112.49-112.00 -30.00   54
 50  ω     75.00 107.00   0.50    0.05    --  112.49-112.00  60.00   64
 51  ω     22.00 104.00   0.50    0.05    --  112.49 -92.00  60.00  164
 52  ω     12.00  38.00   0.50    0.05    --   56.24-105.00-133.00   52
 53  ω      5.00  51.00   0.50    0.05    --    0.00-105.00-133.00   92
 54  ω     27.00  53.00   0.50    0.05    --    0.00 -99.00  60.00   52
 55  ω   -107.00 -70.00   0.50    0.05    --  -56.24 105.00 -33.00   74
 56  ω    -66.00 -33.00   0.50    0.05    --  -56.24 105.00 -33.00   66
 57  ω    -97.00 -61.00   0.50    0.05    --  -97.00 105.00 -33.00   72
 58  ω    -82.00 -49.00   0.50    0.05    --  -97.00 179.00 150.00   66
 59  ω   -148.00 -91.00   0.50    0.05    --  -97.00 179.00 150.00  114
 60  ω   -112.00 -32.00   0.50    0.05    --  -56.24 125.00 120.00  160
 61  ω   -147.00-122.00   0.50    0.05    --  -56.24 -99.00 -60.00   50
 62  ω   -139.00 -82.00   0.50    0.05    --  -56.24-125.00-120.00  114
 63  ω   -125.00 -99.00   0.50    0.05    --  -56.24-105.00-133.00   52
 64  ω   -159.00 -94.00   0.50    0.05    --  -97.00-105.00-133.00  130
 65  ω   -146.00 -91.00   0.50    0.05    --  -56.24 -99.00 120.00  110
;
_diffrn_measurement_device         'four-circle diffractometer'
_diffrn_measurement_device_type    'ROD, Synergy Custom system, HyPix'
_diffrn_measurement_method         'ω scans'
_diffrn_radiation_type             CuK\a
_diffrn_radiation_wavelength       1.54184
_diffrn_source                     ?
_reflns_Friedel_coverage           0.000
_reflns_Friedel_fraction_full      .
_reflns_Friedel_fraction_max       .
_reflns_number_gt                  12008
_reflns_number_total               12868
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression       'I > 2σ(I)'
_computing_cell_refinement         'CrysAlisPro 1.171.43.98a (Rigaku OD, 2023)'
_computing_data_collection        
 'CrysAlisPro system (CCD 43.98a 64-bit (release 24-11-2023))'
_computing_data_reduction          'CrysAlisPro 1.171.43.98a (Rigaku OD, 2023)'
_computing_molecular_graphics      'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_publication_material    'Olex2 1.5 (Dolomanov et al., 2009)'
_computing_structure_refinement    'SHELXL 2019/3 (Sheldrick, 2015)'
_computing_structure_solution      'SHELXT 2018/2 (Sheldrick, 2018)'
_refine_diff_density_max           0.587
_refine_diff_density_min           -1.401
_refine_diff_density_rms           0.045
_refine_ls_extinction_coef         .
_refine_ls_extinction_method       none
_refine_ls_goodness_of_fit_ref     1.053
_refine_ls_hydrogen_treatment      constr
_refine_ls_matrix_type             full
_refine_ls_number_parameters       912
_refine_ls_number_reflns           12868
_refine_ls_number_restraints       180
_refine_ls_R_factor_all            0.0383
_refine_ls_R_factor_gt             0.0361
_refine_ls_restrained_S_all        1.075
_refine_ls_shift/su_max            0.002
_refine_ls_shift/su_mean           0.000
_refine_ls_structure_factor_coef   Fsqd
_refine_ls_weighting_details      
 'w=1/[σ²(Fo²)+(0.0474P)²+1.8548P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme        calc
_refine_ls_wR_factor_gt            0.0944
_refine_ls_wR_factor_ref           0.0961
_refine_special_details           
 'In the structure, the Ge-N3 unit exhibits a positional disorder over two positions, they were separated using PART instruction and refined using a free variable (FVAR). SAME instruction was applied to make the shape and position of disordered Ge-N3 units in a reasonable range, the final occupancies of 0.9237(9):0.0763(9) have been determined for PART 1 and PART 2, respectively. C36 to C43 and n-hexane solvents (C73 to C78) also exhibit a positional disorder and they were separated using PART 1 and PART 2 instructions and refined using free variables (FVAR). SAME instruction was used to fix the disordered parts in reasonable shape and positions, RIGU and ISOR instructions to make the anisotropic displacement parameters of the disordered parts within reasonable limits. The occupancies of 0.454(4):0.546(4) for C36 to C43 and 0.669 (9):0.331(9) for C73 to C78 have been determined for PART 1 and PART 2.'
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2. Restrained distances
 Ge1-C1 \\sim Ge1A-C1
 with sigma of 0.002
3. Uiso/Uaniso restraints and constraints
Uanis(C36) \\sim Ueq: with sigma of 0.003 and sigma for terminal atoms of 0.006
4. Rigid body (RIGU) restrains
 C36, C37, C38, C39, C40, C41, C42, C43, C73, C74, C75, C76, C77, C78, Ge1A,
 N1A, N2A, N3A, C36A, C37A, C38A, C39A, C40A, C41A, C42A, C43A
 with sigma for 1-2 distances of 0.002 and sigma for 1-3 distances of 0.002
 C73, C74, C75, C76, C77, C78, Ge1A, N1A, N2A, N3A, C36A, C37A, C38A, C39A,
 C40A, C41A, C42A, C43A, C73A, C74A, C75A, C76A, C77A, C78A
 with sigma for 1-2 distances of 0.002 and sigma for 1-3 distances of 0.002
5. Same fragment restrains
{C73A, C74A, C75A, C76A, C77A, C78A} sigma for 1-2: 0.01, 1-3: 0.02
as in
{C73, C74, C75, C76, C77, C78}
{C36A, C37A, C38A, C39A, C40A, C41A, C42A, C43A} sigma for 1-2: 0.01, 1-3: 0.02
as in
{C36, C37, C38, C39, C40, C41, C42, C43}
{Ge1A, N1A, N2A, N3A} sigma for 1-2: 0.01, 1-3: 0.02
as in
{Ge1, N1, N2, N3}
6. Others
 Sof(C36A)=Sof(C37A)=Sof(H37D)=Sof(H37E)=Sof(H37F)=Sof(C38A)=Sof(H38D)=
 Sof(H38E)=Sof(H38F)=Sof(C39A)=Sof(H39C)=Sof(H39D)=Sof(C40A)=Sof(C41A)=
 Sof(H41D)=Sof(H41E)=Sof(H41F)=Sof(C42A)=Sof(H42D)=Sof(H42E)=Sof(H42F)=
 Sof(C43A)=Sof(H43C)=Sof(H43D)=1-FVAR(1)
 Sof(C36)=Sof(C37)=Sof(H37A)=Sof(H37B)=Sof(H37C)=Sof(C38)=Sof(H38A)=Sof(H38B)=
 Sof(H38C)=Sof(C39)=Sof(H39A)=Sof(H39B)=Sof(C40)=Sof(C41)=Sof(H41A)=Sof(H41B)=
 Sof(H41C)=Sof(C42)=Sof(H42A)=Sof(H42B)=Sof(H42C)=Sof(C43)=Sof(H43A)=Sof(H43B)=
 FVAR(1)
 Sof(Ge1A)=Sof(N1A)=Sof(N2A)=Sof(N3A)=1-FVAR(2)
 Sof(Ge1)=Sof(N1)=Sof(N2)=Sof(N3)=FVAR(2)
 Sof(C73A)=Sof(H73D)=Sof(H73E)=Sof(H73F)=Sof(C74A)=Sof(H74C)=Sof(H74D)=
 Sof(C75A)=Sof(H75C)=Sof(H75D)=Sof(C76A)=Sof(H76C)=Sof(H76D)=Sof(C77A)=
 Sof(H77C)=Sof(H77D)=Sof(C78A)=Sof(H78D)=Sof(H78E)=Sof(H78F)=1-FVAR(3)
 Sof(C73)=Sof(H73A)=Sof(H73B)=Sof(H73C)=Sof(C74)=Sof(H74A)=Sof(H74B)=Sof(C75)=
 Sof(H75A)=Sof(H75B)=Sof(C76)=Sof(H76A)=Sof(H76B)=Sof(C77)=Sof(H77A)=Sof(H77B)=
 Sof(C78)=Sof(H78A)=Sof(H78B)=Sof(H78C)=FVAR(3)
7.a Secondary CH2 refined with riding coordinates:
 C7(H7A,H7B), C11(H11A,H11B), C31(H31A,H31B), C35(H35A,H35B), C60(H60A,H60B),
 C64(H64A,H64B), C68(H68A,H68B), C72(H72A,H72B), C39(H39A,H39B), C43(H43A,H43B),
  C74(H74A,H74B), C75(H75A,H75B), C76(H76A,H76B), C77(H77A,H77B), C39A(H39C,
 H39D), C43A(H43C,H43D), C74A(H74C,H74D), C75A(H75C,H75D), C76A(H76C,H76D),
 C77A(H77C,H77D)
7.b Aromatic/amide H refined with riding coordinates:
 C4(H4), C17(H17), C20(H20), C23(H23), C26(H26), C46(H46), C49(H49), C52(H52),
 C55(H55)
7.c Idealised Me refined as rotating group:
 C9(H9A,H9B,H9C), C10(H10A,H10B,H10C), C13(H13A,H13B,H13C), C14(H14A,H14B,
 H14C), C29(H29A,H29B,H29C), C30(H30A,H30B,H30C), C33(H33A,H33B,H33C), C34(H34A,
 H34B,H34C), C58(H58A,H58B,H58C), C59(H59A,H59B,H59C), C62(H62A,H62B,H62C),
 C63(H63A,H63B,H63C), C66(H66A,H66B,H66C), C67(H67A,H67B,H67C), C70(H70A,H70B,
 H70C), C71(H71A,H71B,H71C), C37(H37A,H37B,H37C), C38(H38A,H38B,H38C), C41(H41A,
 H41B,H41C), C42(H42A,H42B,H42C), C73(H73A,H73B,H73C), C78(H78A,H78B,H78C),
 C37A(H37D,H37E,H37F), C38A(H38D,H38E,H38F), C41A(H41D,H41E,H41F), C42A(H42D,
 H42E,H42F), C73A(H73D,H73E,H73F), C78A(H78D,H78E,H78F)
;
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary       dual
_atom_sites_solution_secondary     ?
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_site_symmetry_order
  _atom_site_calc_flag
  _atom_site_refinement_flags_posn
  _atom_site_refinement_flags_adp
  _atom_site_refinement_flags_occupancy
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 C1 C 0.77217(10) 0.22317(8) 0.35511(9) 0.0173(3) Uani 1 1 d D . . . .
 C2 C 0.87092(10) 0.24405(8) 0.35917(9) 0.0154(3) Uani 1 1 d . . . . .
 C3 C 0.95486(10) 0.28574(9) 0.43784(9) 0.0174(3) Uani 1 1 d . . . . .
 C4 C 0.94259(11) 0.30915(9) 0.51631(9) 0.0195(3) Uani 1 1 d . . . . .
 H4 H 0.999614 0.336649 0.570298 0.023 Uiso 1 1 calc R U . . .
 C5 C 0.84505(10) 0.29139(8) 0.51393(9) 0.0166(3) Uani 1 1 d . . . . .
 C6 C 0.76171(10) 0.25018(8) 0.43453(9) 0.0146(3) Uani 1 1 d . . . . .
 C7 C 0.70293(10) 0.26220(9) 0.55162(9) 0.0182(3) Uani 1 1 d . . . . .
 H7A H 0.660531 0.301579 0.569220 0.022 Uiso 1 1 calc R U . . .
 H7B H 0.698274 0.207664 0.573853 0.022 Uiso 1 1 calc R U . . .
 C8 C 0.81636(10) 0.30791(9) 0.59226(9) 0.0170(3) Uani 1 1 d . . . . .
 C9 C 0.82786(12) 0.40645(9) 0.62971(10) 0.0232(3) Uani 1 1 d . . . . .
 H9A H 0.899504 0.433699 0.650054 0.035 Uiso 1 1 calc R U . . .
 H9B H 0.808367 0.414434 0.679872 0.035 Uiso 1 1 calc R U . . .
 H9C H 0.783053 0.434121 0.583111 0.035 Uiso 1 1 calc R U . . .
 C10 C 0.88395(11) 0.26556(10) 0.66715(9) 0.0226(3) Uani 1 1 d . . . . .
 H10A H 0.879171 0.202903 0.643788 0.034 Uiso 1 1 calc R U . . .
 H10B H 0.860371 0.272438 0.714881 0.034 Uiso 1 1 calc R U . . .
 H10C H 0.955546 0.294233 0.690695 0.034 Uiso 1 1 calc R U . . .
 C11 C 1.02199(10) 0.25052(10) 0.32841(9) 0.0206(3) Uani 1 1 d . . . . .
 H11A H 1.053321 0.196333 0.327183 0.025 Uiso 1 1 calc R U . . .
 H11B H 1.046533 0.288991 0.296896 0.025 Uiso 1 1 calc R U . . .
 C12 C 1.05413(10) 0.29854(9) 0.42629(9) 0.0201(3) Uani 1 1 d . . . . .
 C13 C 1.09352(12) 0.39705(10) 0.44176(11) 0.0278(3) Uani 1 1 d . . . . .
 H13A H 1.153758 0.404117 0.428288 0.042 Uiso 1 1 calc R U . . .
 H13B H 1.112667 0.424845 0.504034 0.042 Uiso 1 1 calc R U . . .
 H13C H 1.039201 0.424877 0.402814 0.042 Uiso 1 1 calc R U . . .
 C14 C 1.13784(11) 0.25725(11) 0.49112(11) 0.0284(3) Uani 1 1 d . . . . .
 H14A H 1.113092 0.194732 0.482770 0.043 Uiso 1 1 calc R U . . .
 H14B H 1.154427 0.286930 0.552364 0.043 Uiso 1 1 calc R U . . .
 H14C H 1.199602 0.263661 0.479725 0.043 Uiso 1 1 calc R U . . .
 C15 C 0.66258(10) 0.23999(8) 0.44821(9) 0.0156(3) Uani 1 1 d . . . . .
 C16 C 0.59841(10) 0.14889(9) 0.40621(9) 0.0159(3) Uani 1 1 d . . . . .
 C17 C 0.62490(10) 0.06817(9) 0.42329(9) 0.0178(3) Uani 1 1 d . . . . .
 H17 H 0.691899 0.065432 0.465682 0.021 Uiso 1 1 calc R U . . .
 C18 C 0.55441(11) -0.00969(9) 0.37902(10) 0.0193(3) Uani 1 1 d . . . . .
 C19 C 0.45536(11) -0.00519(9) 0.31528(9) 0.0178(3) Uani 1 1 d . . . . .
 C20 C 0.42939(11) 0.07682(9) 0.29872(9) 0.0185(3) Uani 1 1 d . . . . .
 H20 H 0.362890 0.080217 0.255900 0.022 Uiso 1 1 calc R U . . .
 C21 C 0.49956(10) 0.15313(9) 0.34407(9) 0.0163(3) Uani 1 1 d . . . . .
 C22 C 0.49134(10) 0.24568(9) 0.34098(9) 0.0163(3) Uani 1 1 d . . . . .
 C23 C 0.41079(10) 0.28390(9) 0.28995(9) 0.0178(3) Uani 1 1 d . . . . .
 H23 H 0.347643 0.247872 0.249863 0.021 Uiso 1 1 calc R U . . .
 C24 C 0.42088(10) 0.37523(9) 0.29645(9) 0.0167(3) Uani 1 1 d . . . . .
 C25 C 0.51459(10) 0.42800(9) 0.35705(9) 0.0167(3) Uani 1 1 d . . . . .
 C26 C 0.59628(10) 0.38749(9) 0.40720(9) 0.0165(3) Uani 1 1 d . . . . .
 H26 H 0.660179 0.422753 0.446729 0.020 Uiso 1 1 calc R U . . .
 C27 C 0.58543(10) 0.29733(9) 0.40009(9) 0.0158(3) Uani 1 1 d . . . . .
 C28 C 0.53115(11) 0.52848(9) 0.36812(10) 0.0195(3) Uani 1 1 d . . . . .
 C29 C 0.59456(13) 0.55425(10) 0.31818(12) 0.0295(3) Uani 1 1 d . . . . .
 H29A H 0.601617 0.617925 0.322114 0.044 Uiso 1 1 calc R U . . .
 H29B H 0.559717 0.523954 0.255555 0.044 Uiso 1 1 calc R U . . .
 H29C H 0.662872 0.537353 0.344942 0.044 Uiso 1 1 calc R U . . .
 C30 C 0.58915(12) 0.57564(9) 0.46617(10) 0.0242(3) Uani 1 1 d . . . . .
 H30A H 0.658059 0.559386 0.490571 0.036 Uiso 1 1 calc R U . . .
 H30B H 0.551428 0.558283 0.500037 0.036 Uiso 1 1 calc R U . . .
 H30C H 0.594972 0.639348 0.470440 0.036 Uiso 1 1 calc R U . . .
 C31 C 0.42588(11) 0.56008(9) 0.33257(10) 0.0234(3) Uani 1 1 d . . . . .
 H31A H 0.392652 0.553118 0.373275 0.028 Uiso 1 1 calc R U . . .
 H31B H 0.436389 0.623335 0.331780 0.028 Uiso 1 1 calc R U . . .
 C32 C 0.32779(11) 0.41142(9) 0.23630(9) 0.0198(3) Uani 1 1 d . . . . .
 C33 C 0.29023(13) 0.36275(10) 0.13899(10) 0.0273(3) Uani 1 1 d . . . . .
 H33A H 0.264823 0.300939 0.133288 0.041 Uiso 1 1 calc R U . . .
 H33B H 0.347331 0.366467 0.121083 0.041 Uiso 1 1 calc R U . . .
 H33C H 0.234594 0.389824 0.100589 0.041 Uiso 1 1 calc R U . . .
 C34 C 0.24076(11) 0.39750(10) 0.26674(10) 0.0249(3) Uani 1 1 d . . . . .
 H34A H 0.179936 0.418679 0.227539 0.037 Uiso 1 1 calc R U . . .
 H34B H 0.263379 0.430178 0.328008 0.037 Uiso 1 1 calc R U . . .
 H34C H 0.223586 0.334775 0.264043 0.037 Uiso 1 1 calc R U . . .
 C35 C 0.35546(12) 0.50948(9) 0.23977(10) 0.0254(3) Uani 1 1 d . . . . .
 H35A H 0.389445 0.515508 0.199440 0.031 Uiso 1 1 calc R U . . .
 H35B H 0.291458 0.535429 0.217952 0.031 Uiso 1 1 calc R U . . .
 C44 C 0.90270(10) 0.22691(9) 0.28142(9) 0.0169(3) Uani 1 1 d . . . . .
 C45 C 0.85929(10) 0.13365(9) 0.22788(9) 0.0168(3) Uani 1 1 d . . . . .
 C46 C 0.88521(11) 0.05478(9) 0.25147(9) 0.0195(3) Uani 1 1 d . . . . .
 H46 H 0.938938 0.055325 0.307857 0.023 Uiso 1 1 calc R U . . .
 C47 C 0.83350(11) -0.02568(9) 0.19354(9) 0.0193(3) Uani 1 1 d . . . . .
 C48 C 0.75110(11) -0.02619(9) 0.11077(9) 0.0186(3) Uani 1 1 d . . . . .
 C49 C 0.72614(11) 0.05384(9) 0.08747(9) 0.0186(3) Uani 1 1 d . . . . .
 H49 H 0.671351 0.053920 0.031853 0.022 Uiso 1 1 calc R U . . .
 C50 C 0.78024(10) 0.13314(9) 0.14440(9) 0.0172(3) Uani 1 1 d . . . . .
 C51 C 0.77353(10) 0.22445(9) 0.13442(9) 0.0164(3) Uani 1 1 d . . . . .
 C52 C 0.70814(10) 0.25924(9) 0.06590(9) 0.0170(3) Uani 1 1 d . . . . .
 H52 H 0.657327 0.220993 0.014110 0.020 Uiso 1 1 calc R U . . .
 C53 C 0.71610(10) 0.35041(9) 0.07209(9) 0.0172(3) Uani 1 1 d . . . . .
 C54 C 0.79414(11) 0.40622(9) 0.14803(9) 0.0178(3) Uani 1 1 d . . . . .
 C55 C 0.85921(10) 0.36934(9) 0.21709(9) 0.0182(3) Uani 1 1 d . . . . .
 H55 H 0.911815 0.406777 0.268369 0.022 Uiso 1 1 calc R U . . .
 C56 C 0.84795(10) 0.27964(9) 0.21166(9) 0.0168(3) Uani 1 1 d . . . . .
 C57 C 0.68285(11) -0.11065(9) 0.04688(10) 0.0216(3) Uani 1 1 d . . . . .
 C58 C 0.66668(13) -0.11026(10) -0.04932(10) 0.0283(3) Uani 1 1 d . . . . .
 H58A H 0.625328 -0.064890 -0.070768 0.042 Uiso 1 1 calc R U . . .
 H58B H 0.630825 -0.167842 -0.087236 0.042 Uiso 1 1 calc R U . . .
 H58C H 0.733555 -0.097805 -0.051371 0.042 Uiso 1 1 calc R U . . .
 C59 C 0.57785(12) -0.11581(10) 0.05146(12) 0.0304(3) Uani 1 1 d . . . . .
 H59A H 0.586364 -0.122058 0.111160 0.046 Uiso 1 1 calc R U . . .
 H59B H 0.530903 -0.166653 0.007438 0.046 Uiso 1 1 calc R U . . .
 H59C H 0.549309 -0.062011 0.038706 0.046 Uiso 1 1 calc R U . . .
 C60 C 0.73079(13) -0.19276(10) 0.07178(11) 0.0303(3) Uani 1 1 d . . . . .
 H60A H 0.676303 -0.244936 0.043961 0.036 Uiso 1 1 calc R U . . .
 H60B H 0.782306 -0.200832 0.046946 0.036 Uiso 1 1 calc R U . . .
 C61 C 0.87121(12) -0.11071(10) 0.21906(10) 0.0236(3) Uani 1 1 d . . . . .
 C62 C 0.96034(14) -0.12423(11) 0.19256(12) 0.0324(4) Uani 1 1 d . . . . .
 H62A H 0.939198 -0.120115 0.130162 0.049 Uiso 1 1 calc R U . . .
 H62B H 0.979157 -0.182361 0.200116 0.049 Uiso 1 1 calc R U . . .
 H62C H 1.019690 -0.078861 0.230444 0.049 Uiso 1 1 calc R U . . .
 C63 C 0.91006(14) -0.10746(11) 0.31967(11) 0.0310(4) Uani 1 1 d . . . . .
 H63A H 0.974434 -0.066003 0.351789 0.047 Uiso 1 1 calc R U . . .
 H63B H 0.922119 -0.166083 0.331332 0.047 Uiso 1 1 calc R U . . .
 H63C H 0.858347 -0.088234 0.339908 0.047 Uiso 1 1 calc R U . . .
 C64 C 0.78214(13) -0.18778(10) 0.17114(11) 0.0312(4) Uani 1 1 d . . . . .
 H64A H 0.808615 -0.243403 0.182265 0.037 Uiso 1 1 calc R U . . .
 H64B H 0.730485 -0.181205 0.196029 0.037 Uiso 1 1 calc R U . . .
 C65 C 0.63428(11) 0.38579(9) -0.00050(9) 0.0204(3) Uani 1 1 d . . . . .
 C66 C 0.60519(13) 0.33074(10) -0.09385(10) 0.0280(3) Uani 1 1 d . . . . .
 H66A H 0.667132 0.327813 -0.104758 0.042 Uiso 1 1 calc R U . . .
 H66B H 0.556266 0.358005 -0.138331 0.042 Uiso 1 1 calc R U . . .
 H66C H 0.573592 0.271242 -0.098088 0.042 Uiso 1 1 calc R U . . .
 C67 C 0.53679(12) 0.38213(10) 0.01701(11) 0.0273(3) Uani 1 1 d . . . . .
 H67A H 0.513041 0.321374 0.016545 0.041 Uiso 1 1 calc R U . . .
 H67B H 0.482805 0.403439 -0.029541 0.041 Uiso 1 1 calc R U . . .
 H67C H 0.552456 0.419258 0.075163 0.041 Uiso 1 1 calc R U . . .
 C68 C 0.67339(12) 0.48068(9) 0.00112(9) 0.0224(3) Uani 1 1 d . . . . .
 H68A H 0.727004 0.480571 -0.021956 0.027 Uiso 1 1 calc R U . . .
 H68B H 0.615896 0.506108 -0.038668 0.027 Uiso 1 1 calc R U . . .
 C69 C 0.81221(11) 0.50650(9) 0.15921(9) 0.0204(3) Uani 1 1 d . . . . .
 C70 C 0.90666(12) 0.53302(10) 0.14174(11) 0.0275(3) Uani 1 1 d . . . . .
 H70A H 0.966313 0.511725 0.182474 0.041 Uiso 1 1 calc R U . . .
 H70B H 0.920929 0.597174 0.151487 0.041 Uiso 1 1 calc R U . . .
 H70C H 0.892950 0.507051 0.080136 0.041 Uiso 1 1 calc R U . . .
 C71 C 0.83221(12) 0.55309(10) 0.25409(10) 0.0256(3) Uani 1 1 d . . . . .
 H71A H 0.777707 0.529620 0.269525 0.038 Uiso 1 1 calc R U . . .
 H71B H 0.832775 0.616320 0.256769 0.038 Uiso 1 1 calc R U . . .
 H71C H 0.898855 0.542987 0.296325 0.038 Uiso 1 1 calc R U . . .
 C72 C 0.71783(12) 0.53789(9) 0.09442(10) 0.0244(3) Uani 1 1 d . . . . .
 H72A H 0.664216 0.537673 0.117496 0.029 Uiso 1 1 calc R U . . .
 H72B H 0.737477 0.599122 0.091395 0.029 Uiso 1 1 calc R U . . .
 Ge1 Ge 0.66246(2) 0.12898(2) 0.25596(2) 0.01790(7) Uani 0.9237(9) 1 d D . P A
 1
 N1 N 0.58120(10) 0.20701(10) 0.18867(9) 0.0257(3) Uani 0.9237(9) 1 d D . P A 1
 N2 N 0.60975(12) 0.28478(10) 0.21263(9) 0.0263(3) Uani 0.9237(9) 1 d D . P A 1
 N3 N 0.63253(13) 0.36020(11) 0.23127(11) 0.0348(4) Uani 0.9237(9) 1 d D . P A
 1
 C36 C 0.3679(8) -0.0863(8) 0.2581(8) 0.0160(17) Uani 0.454(4) 1 d D U P B 1
 C37 C 0.3476(16) -0.1009(14) 0.1592(9) 0.0220(19) Uani 0.454(4) 1 d D . P B 1
 H37A H 0.319797 -0.050732 0.134887 0.033 Uiso 0.454(4) 1 calc R U P B 1
 H37B H 0.298003 -0.154679 0.126315 0.033 Uiso 0.454(4) 1 calc R U P B 1
 H37C H 0.412206 -0.106694 0.153330 0.033 Uiso 0.454(4) 1 calc R U P B 1
 C38 C 0.2668(8) -0.0741(8) 0.2668(6) 0.0257(16) Uani 0.454(4) 1 d D . P B 1
 H38A H 0.279653 -0.062692 0.329839 0.039 Uiso 0.454(4) 1 calc R U P B 1
 H38B H 0.216265 -0.127527 0.235115 0.039 Uiso 0.454(4) 1 calc R U P B 1
 H38C H 0.240118 -0.024251 0.241015 0.039 Uiso 0.454(4) 1 calc R U P B 1
 C39 C 0.4041(5) -0.1676(7) 0.2947(6) 0.0234(16) Uani 0.454(4) 1 d D . P B 1
 H39A H 0.395125 -0.166399 0.350446 0.028 Uiso 0.454(4) 1 calc R U P B 1
 H39B H 0.360088 -0.220977 0.251186 0.028 Uiso 0.454(4) 1 calc R U P B 1
 C40 C 0.5898(5) -0.0984(5) 0.3880(4) 0.0202(13) Uani 0.454(4) 1 d D . P B 1
 C41 C 0.6956(4) -0.0989(4) 0.3859(4) 0.0293(11) Uani 0.454(4) 1 d D . P B 1
 H41A H 0.694324 -0.078684 0.333079 0.044 Uiso 0.454(4) 1 calc R U P B 1
 H41B H 0.712076 -0.158713 0.383726 0.044 Uiso 0.454(4) 1 calc R U P B 1
 H41C H 0.747872 -0.059620 0.439534 0.044 Uiso 0.454(4) 1 calc R U P B 1
 C42 C 0.5965(4) -0.1122(3) 0.4788(3) 0.0288(9) Uani 0.454(4) 1 d D . P B 1
 H42A H 0.645070 -0.064183 0.525840 0.043 Uiso 0.454(4) 1 calc R U P B 1
 H42B H 0.620328 -0.168282 0.489114 0.043 Uiso 0.454(4) 1 calc R U P B 1
 H42C H 0.528461 -0.113090 0.479311 0.043 Uiso 0.454(4) 1 calc R U P B 1
 C43 C 0.5149(3) -0.1734(2) 0.3133(2) 0.0230(8) Uani 0.454(4) 1 d D . P B 1
 H43A H 0.524769 -0.171852 0.258271 0.028 Uiso 0.454(4) 1 calc R U P B 1
 H43B H 0.530959 -0.230265 0.330003 0.028 Uiso 0.454(4) 1 calc R U P B 1
 C73 C 0.8935(4) 0.3720(5) -0.0809(4) 0.0490(18) Uani 0.669(9) 1 d D . P C 1
 H73A H 0.863117 0.331906 -0.139349 0.074 Uiso 0.669(9) 1 calc R U P C 1
 H73B H 0.921212 0.429017 -0.086478 0.074 Uiso 0.669(9) 1 calc R U P C 1
 H73C H 0.840525 0.379694 -0.058565 0.074 Uiso 0.669(9) 1 calc R U P C 1
 C74 C 0.9796(3) 0.3336(3) -0.0164(4) 0.0630(13) Uani 0.669(9) 1 d D . P C 1
 H74A H 1.033242 0.327411 -0.039023 0.076 Uiso 0.669(9) 1 calc R U P C 1
 H74B H 1.011118 0.375586 0.041719 0.076 Uiso 0.669(9) 1 calc R U P C 1
 C75 C 0.9457(5) 0.2456(4) -0.0021(4) 0.0460(14) Uani 0.669(9) 1 d D . P C 1
 H75A H 0.914514 0.203535 -0.060195 0.055 Uiso 0.669(9) 1 calc R U P C 1
 H75B H 0.891775 0.251726 0.020197 0.055 Uiso 0.669(9) 1 calc R U P C 1
 C76 C 1.0314(4) 0.2079(4) 0.0624(4) 0.0449(13) Uani 0.669(9) 1 d D . P C 1
 H76A H 1.085864 0.203914 0.040509 0.054 Uiso 0.669(9) 1 calc R U P C 1
 H76B H 1.061426 0.250119 0.120381 0.054 Uiso 0.669(9) 1 calc R U P C 1
 C77 C 1.0037(4) 0.1193(4) 0.0785(5) 0.0787(17) Uani 0.669(9) 1 d D . P C 1
 H77A H 0.948110 0.122330 0.099042 0.094 Uiso 0.669(9) 1 calc R U P C 1
 H77B H 0.976208 0.076171 0.021178 0.094 Uiso 0.669(9) 1 calc R U P C 1
 C78 C 1.0903(7) 0.0864(6) 0.1447(6) 0.092(3) Uani 0.669(9) 1 d D . P C 1
 H78A H 1.149904 0.091494 0.130108 0.137 Uiso 0.669(9) 1 calc R U P C 1
 H78B H 1.069266 0.024729 0.143212 0.137 Uiso 0.669(9) 1 calc R U P C 1
 H78C H 1.108806 0.121492 0.204386 0.137 Uiso 0.669(9) 1 calc R U P C 1
 Ge1A Ge 0.6556(2) 0.2558(2) 0.24639(17) 0.0451(10) Uiso 0.0763(9) 1 d D . P A
 2
 N1A N 0.5817(12) 0.1387(6) 0.1863(11) 0.036(4) Uiso 0.0763(9) 1 d D . P A 2
 N2A N 0.6125(12) 0.0757(8) 0.2115(10) 0.024(3) Uiso 0.0763(9) 1 d D . P A 2
 N3A N 0.6567(18) 0.0247(13) 0.2482(15) 0.053(6) Uiso 0.0763(9) 1 d D . P A 2
 C36A C 0.3784(7) -0.0867(7) 0.2659(7) 0.0227(17) Uani 0.546(4) 1 d D . P B 2
 C37A C 0.3414(14) -0.0887(12) 0.1655(8) 0.028(2) Uani 0.546(4) 1 d D . P B 2
 H37D H 0.304958 -0.038921 0.150741 0.042 Uiso 0.546(4) 1 calc R U P B 2
 H37E H 0.294960 -0.143770 0.131263 0.042 Uiso 0.546(4) 1 calc R U P B 2
 H37F H 0.400877 -0.084567 0.150662 0.042 Uiso 0.546(4) 1 calc R U P B 2
 C38A C 0.2854(7) -0.0818(7) 0.2892(5) 0.0274(15) Uani 0.546(4) 1 d D . P B 2
 H38D H 0.306189 -0.084877 0.351859 0.041 Uiso 0.546(4) 1 calc R U P B 2
 H38E H 0.230830 -0.131121 0.251387 0.041 Uiso 0.546(4) 1 calc R U P B 2
 H38F H 0.259763 -0.026327 0.279295 0.041 Uiso 0.546(4) 1 calc R U P B 2
 C39A C 0.4206(5) -0.1723(5) 0.2850(5) 0.0293(17) Uani 0.546(4) 1 d D . P B 2
 H39C H 0.362351 -0.219996 0.268423 0.035 Uiso 0.546(4) 1 calc R U P B 2
 H39D H 0.457632 -0.188890 0.247548 0.035 Uiso 0.546(4) 1 calc R U P B 2
 C40A C 0.5887(4) -0.0957(4) 0.4104(3) 0.0178(10) Uani 0.546(4) 1 d D . P B 2
 C41A C 0.6581(4) -0.1262(3) 0.3653(3) 0.0297(9) Uani 0.546(4) 1 d D . P B 2
 H41D H 0.621672 -0.131446 0.300898 0.045 Uiso 0.546(4) 1 calc R U P B 2
 H41E H 0.675847 -0.183389 0.377962 0.045 Uiso 0.546(4) 1 calc R U P B 2
 H41F H 0.721059 -0.083182 0.388376 0.045 Uiso 0.546(4) 1 calc R U P B 2
 C42A C 0.6485(3) -0.0847(2) 0.5115(2) 0.0266(7) Uani 0.546(4) 1 d D . P B 2
 H42D H 0.714141 -0.046008 0.531470 0.040 Uiso 0.546(4) 1 calc R U P B 2
 H42E H 0.661391 -0.142281 0.525956 0.040 Uiso 0.546(4) 1 calc R U P B 2
 H42F H 0.607983 -0.058866 0.541548 0.040 Uiso 0.546(4) 1 calc R U P B 2
 C43A C 0.4925(2) -0.16364(17) 0.38160(18) 0.0247(7) Uani 0.546(4) 1 d D . P B
 2
 H43C H 0.513290 -0.221414 0.391383 0.030 Uiso 0.546(4) 1 calc R U P B 2
 H43D H 0.455641 -0.146295 0.419059 0.030 Uiso 0.546(4) 1 calc R U P B 2
 C73A C 0.8895(17) 0.3699(15) -0.0844(11) 0.092(7) Uani 0.331(9) 1 d D . P C
 2
 H73D H 0.829413 0.327284 -0.126799 0.139 Uiso 0.331(9) 1 calc R U P C 2
 H73E H 0.939644 0.376786 -0.109801 0.139 Uiso 0.331(9) 1 calc R U P C 2
 H73F H 0.867921 0.426636 -0.071899 0.139 Uiso 0.331(9) 1 calc R U P C 2
 C74A C 0.9383(8) 0.3370(5) 0.0019(4) 0.050(2) Uani 0.331(9) 1 d D . P C 2
 H74C H 1.001597 0.378359 0.042685 0.060 Uiso 0.331(9) 1 calc R U P C 2
 H74D H 0.890169 0.337124 0.030756 0.060 Uiso 0.331(9) 1 calc R U P C 2
 C75A C 0.9652(13) 0.2463(7) -0.0113(8) 0.050(3) Uani 0.331(9) 1 d D . P C 2
 H75C H 1.016466 0.247109 -0.037047 0.060 Uiso 0.331(9) 1 calc R U P C 2
 H75D H 0.902767 0.205689 -0.054968 0.060 Uiso 0.331(9) 1 calc R U P C 2
 C76A C 1.0083(10) 0.2110(6) 0.0733(8) 0.046(2) Uani 0.331(9) 1 d D . P C 2
 H76C H 1.069497 0.252795 0.117211 0.055 Uiso 0.331(9) 1 calc R U P C 2
 H76D H 0.956253 0.209448 0.098082 0.055 Uiso 0.331(9) 1 calc R U P C 2
 C77A C 1.0385(11) 0.1211(7) 0.0637(6) 0.071(3) Uani 0.331(9) 1 d D . P C 2
 H77C H 0.975487 0.078059 0.026414 0.086 Uiso 0.331(9) 1 calc R U P C 2
 H77D H 1.082893 0.120302 0.031135 0.086 Uiso 0.331(9) 1 calc R U P C 2
 C78A C 1.0939(7) 0.0909(9) 0.1485(8) 0.050(3) Uani 0.331(9) 1 d D . P C 2
 H78D H 1.126358 0.040385 0.136701 0.075 Uiso 0.331(9) 1 calc R U P C 2
 H78E H 1.044779 0.073785 0.172471 0.075 Uiso 0.331(9) 1 calc R U P C 2
 H78F H 1.146787 0.138797 0.191914 0.075 Uiso 0.331(9) 1 calc R U P C 2


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 C1 C2 1.4018(19) . ?
 C1 C6 1.4008(19) . ?
 C1 Ge1 2.0420(13) . ?
 C1 Ge1A 2.092(2) . ?
 C2 C3 1.3957(19) . ?
 C2 C44 1.5363(18) . ?
 C3 C4 1.391(2) . ?
 C3 C12 1.5158(19) . ?
 C4 H4 0.9500 . ?
 C4 C5 1.3898(19) . ?
 C5 C6 1.3967(18) . ?
 C5 C8 1.5164(18) . ?
 C6 C15 1.5300(18) . ?
 C7 H7A 0.9900 . ?
 C7 H7B 0.9900 . ?
 C7 C8 1.5499(18) . ?
 C7 C15 1.5599(18) . ?
 C8 C9 1.5351(19) . ?
 C8 C10 1.5320(19) . ?
 C9 H9A 0.9800 . ?
 C9 H9B 0.9800 . ?
 C9 H9C 0.9800 . ?
 C10 H10A 0.9800 . ?
 C10 H10B 0.9800 . ?
 C10 H10C 0.9800 . ?
 C11 H11A 0.9900 . ?
 C11 H11B 0.9900 . ?
 C11 C12 1.5537(19) . ?
 C11 C44 1.5560(18) . ?
 C12 C13 1.540(2) . ?
 C12 C14 1.531(2) . ?
 C13 H13A 0.9800 . ?
 C13 H13B 0.9800 . ?
 C13 H13C 0.9800 . ?
 C14 H14A 0.9800 . ?
 C14 H14B 0.9800 . ?
 C14 H14C 0.9800 . ?
 C15 C16 1.5243(18) . ?
 C15 C27 1.5335(18) . ?
 C16 C17 1.3849(19) . ?
 C16 C21 1.4000(19) . ?
 C17 H17 0.9500 . ?
 C17 C18 1.4039(19) . ?
 C18 C19 1.413(2) . ?
 C18 C40 1.521(9) . ?
 C18 C40A 1.563(7) . ?
 C19 C20 1.4002(19) . ?
 C19 C36 1.581(13) . ?
 C19 C36A 1.496(12) . ?
 C20 H20 0.9500 . ?
 C20 C21 1.3866(19) . ?
 C21 C22 1.4661(18) . ?
 C22 C23 1.3809(19) . ?
 C22 C27 1.4006(19) . ?
 C23 H23 0.9500 . ?
 C23 C24 1.4037(19) . ?
 C24 C25 1.4100(19) . ?
 C24 C32 1.5319(18) . ?
 C25 C26 1.4075(19) . ?
 C25 C28 1.5377(18) . ?
 C26 H26 0.9500 . ?
 C26 C27 1.3844(18) . ?
 C28 C29 1.533(2) . ?
 C28 C30 1.536(2) . ?
 C28 C31 1.541(2) . ?
 C29 H29A 0.9800 . ?
 C29 H29B 0.9800 . ?
 C29 H29C 0.9800 . ?
 C30 H30A 0.9800 . ?
 C30 H30B 0.9800 . ?
 C30 H30C 0.9800 . ?
 C31 H31A 0.9900 . ?
 C31 H31B 0.9900 . ?
 C31 C35 1.514(2) . ?
 C32 C33 1.538(2) . ?
 C32 C34 1.540(2) . ?
 C32 C35 1.5368(19) . ?
 C33 H33A 0.9800 . ?
 C33 H33B 0.9800 . ?
 C33 H33C 0.9800 . ?
 C34 H34A 0.9800 . ?
 C34 H34B 0.9800 . ?
 C34 H34C 0.9800 . ?
 C35 H35A 0.9900 . ?
 C35 H35B 0.9900 . ?
 C44 C45 1.5188(18) . ?
 C44 C56 1.5287(18) . ?
 C45 C46 1.3856(19) . ?
 C45 C50 1.4044(19) . ?
 C46 H46 0.9500 . ?
 C46 C47 1.400(2) . ?
 C47 C48 1.417(2) . ?
 C47 C61 1.5322(19) . ?
 C48 C49 1.3986(19) . ?
 C48 C57 1.5340(19) . ?
 C49 H49 0.9500 . ?
 C49 C50 1.3879(19) . ?
 C50 C51 1.4674(18) . ?
 C51 C52 1.3833(19) . ?
 C51 C56 1.3980(19) . ?
 C52 H52 0.9500 . ?
 C52 C53 1.4025(19) . ?
 C53 C54 1.4100(19) . ?
 C53 C65 1.5298(19) . ?
 C54 C55 1.4062(19) . ?
 C54 C69 1.5351(18) . ?
 C55 H55 0.9500 . ?
 C55 C56 1.3808(19) . ?
 C57 C58 1.535(2) . ?
 C57 C59 1.537(2) . ?
 C57 C60 1.540(2) . ?
 C58 H58A 0.9800 . ?
 C58 H58B 0.9800 . ?
 C58 H58C 0.9800 . ?
 C59 H59A 0.9800 . ?
 C59 H59B 0.9800 . ?
 C59 H59C 0.9800 . ?
 C60 H60A 0.9900 . ?
 C60 H60B 0.9900 . ?
 C60 C64 1.514(2) . ?
 C61 C62 1.532(2) . ?
 C61 C63 1.541(2) . ?
 C61 C64 1.535(2) . ?
 C62 H62A 0.9800 . ?
 C62 H62B 0.9800 . ?
 C62 H62C 0.9800 . ?
 C63 H63A 0.9800 . ?
 C63 H63B 0.9800 . ?
 C63 H63C 0.9800 . ?
 C64 H64A 0.9900 . ?
 C64 H64B 0.9900 . ?
 C65 C66 1.534(2) . ?
 C65 C67 1.540(2) . ?
 C65 C68 1.5342(19) . ?
 C66 H66A 0.9800 . ?
 C66 H66B 0.9800 . ?
 C66 H66C 0.9800 . ?
 C67 H67A 0.9800 . ?
 C67 H67B 0.9800 . ?
 C67 H67C 0.9800 . ?
 C68 H68A 0.9900 . ?
 C68 H68B 0.9900 . ?
 C68 C72 1.522(2) . ?
 C69 C70 1.537(2) . ?
 C69 C71 1.540(2) . ?
 C69 C72 1.535(2) . ?
 C70 H70A 0.9800 . ?
 C70 H70B 0.9800 . ?
 C70 H70C 0.9800 . ?
 C71 H71A 0.9800 . ?
 C71 H71B 0.9800 . ?
 C71 H71C 0.9800 . ?
 C72 H72A 0.9900 . ?
 C72 H72B 0.9900 . ?
 Ge1 N1 1.9307(15) . ?
 N1 N2 1.199(2) . ?
 N2 N3 1.154(2) . ?
 C36 C37 1.539(6) . ?
 C36 C38 1.539(6) . ?
 C36 C39 1.535(6) . ?
 C37 H37A 0.9800 . ?
 C37 H37B 0.9800 . ?
 C37 H37C 0.9800 . ?
 C38 H38A 0.9800 . ?
 C38 H38B 0.9800 . ?
 C38 H38C 0.9800 . ?
 C39 H39A 0.9900 . ?
 C39 H39B 0.9900 . ?
 C39 C43 1.508(7) . ?
 C40 C41 1.534(6) . ?
 C40 C42 1.536(6) . ?
 C40 C43 1.535(6) . ?
 C41 H41A 0.9800 . ?
 C41 H41B 0.9800 . ?
 C41 H41C 0.9800 . ?
 C42 H42A 0.9800 . ?
 C42 H42B 0.9800 . ?
 C42 H42C 0.9800 . ?
 C43 H43A 0.9900 . ?
 C43 H43B 0.9900 . ?
 C73 H73A 0.9800 . ?
 C73 H73B 0.9800 . ?
 C73 H73C 0.9800 . ?
 C73 C74 1.520(5) . ?
 C74 H74A 0.9900 . ?
 C74 H74B 0.9900 . ?
 C74 C75 1.508(6) . ?
 C75 H75A 0.9900 . ?
 C75 H75B 0.9900 . ?
 C75 C76 1.512(5) . ?
 C76 H76A 0.9900 . ?
 C76 H76B 0.9900 . ?
 C76 C77 1.503(5) . ?
 C77 H77A 0.9900 . ?
 C77 H77B 0.9900 . ?
 C77 C78 1.491(6) . ?
 C78 H78A 0.9800 . ?
 C78 H78B 0.9800 . ?
 C78 H78C 0.9800 . ?
 Ge1A N1A 1.932(9) . ?
 N1A N2A 1.181(9) . ?
 N2A N3A 1.157(9) . ?
 C36A C37A 1.544(5) . ?
 C36A C38A 1.539(6) . ?
 C36A C39A 1.537(6) . ?
 C37A H37D 0.9800 . ?
 C37A H37E 0.9800 . ?
 C37A H37F 0.9800 . ?
 C38A H38D 0.9800 . ?
 C38A H38E 0.9800 . ?
 C38A H38F 0.9800 . ?
 C39A H39C 0.9900 . ?
 C39A H39D 0.9900 . ?
 C39A C43A 1.510(7) . ?
 C40A C41A 1.533(5) . ?
 C40A C42A 1.535(5) . ?
 C40A C43A 1.530(5) . ?
 C41A H41D 0.9800 . ?
 C41A H41E 0.9800 . ?
 C41A H41F 0.9800 . ?
 C42A H42D 0.9800 . ?
 C42A H42E 0.9800 . ?
 C42A H42F 0.9800 . ?
 C43A H43C 0.9900 . ?
 C43A H43D 0.9900 . ?
 C73A H73D 0.9800 . ?
 C73A H73E 0.9800 . ?
 C73A H73F 0.9800 . ?
 C73A C74A 1.525(9) . ?
 C74A H74C 0.9900 . ?
 C74A H74D 0.9900 . ?
 C74A C75A 1.503(8) . ?
 C75A H75C 0.9900 . ?
 C75A H75D 0.9900 . ?
 C75A C76A 1.517(8) . ?
 C76A H76C 0.9900 . ?
 C76A H76D 0.9900 . ?
 C76A C77A 1.504(8) . ?
 C77A H77C 0.9900 . ?
 C77A H77D 0.9900 . ?
 C77A C78A 1.499(8) . ?
 C78A H78D 0.9800 . ?
 C78A H78E 0.9800 . ?
 C78A H78F 0.9800 . ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 C2 C1 Ge1 122.45(10) . . ?
 C2 C1 Ge1A 113.75(13) . . ?
 C6 C1 C2 115.70(12) . . ?
 C6 C1 Ge1 119.26(10) . . ?
 C6 C1 Ge1A 112.08(13) . . ?
 C1 C2 C44 126.65(12) . . ?
 C3 C2 C1 122.56(12) . . ?
 C3 C2 C44 110.79(11) . . ?
 C2 C3 C12 112.87(12) . . ?
 C4 C3 C2 120.30(12) . . ?
 C4 C3 C12 126.81(12) . . ?
 C3 C4 H4 120.7 . . ?
 C5 C4 C3 118.51(12) . . ?
 C5 C4 H4 120.7 . . ?
 C4 C5 C6 120.48(12) . . ?
 C4 C5 C8 126.73(12) . . ?
 C6 C5 C8 112.72(12) . . ?
 C1 C6 C15 126.87(12) . . ?
 C5 C6 C1 122.38(12) . . ?
 C5 C6 C15 110.75(11) . . ?
 H7A C7 H7B 108.3 . . ?
 C8 C7 H7A 110.0 . . ?
 C8 C7 H7B 110.0 . . ?
 C8 C7 C15 108.70(11) . . ?
 C15 C7 H7A 110.0 . . ?
 C15 C7 H7B 110.0 . . ?
 C5 C8 C7 102.84(11) . . ?
 C5 C8 C9 111.89(11) . . ?
 C5 C8 C10 110.66(11) . . ?
 C9 C8 C7 112.12(11) . . ?
 C10 C8 C7 110.80(11) . . ?
 C10 C8 C9 108.49(11) . . ?
 C8 C9 H9A 109.5 . . ?
 C8 C9 H9B 109.5 . . ?
 C8 C9 H9C 109.5 . . ?
 H9A C9 H9B 109.5 . . ?
 H9A C9 H9C 109.5 . . ?
 H9B C9 H9C 109.5 . . ?
 C8 C10 H10A 109.5 . . ?
 C8 C10 H10B 109.5 . . ?
 C8 C10 H10C 109.5 . . ?
 H10A C10 H10B 109.5 . . ?
 H10A C10 H10C 109.5 . . ?
 H10B C10 H10C 109.5 . . ?
 H11A C11 H11B 108.3 . . ?
 C12 C11 H11A 109.9 . . ?
 C12 C11 H11B 109.9 . . ?
 C12 C11 C44 108.98(11) . . ?
 C44 C11 H11A 109.9 . . ?
 C44 C11 H11B 109.9 . . ?
 C3 C12 C11 102.96(11) . . ?
 C3 C12 C13 110.49(12) . . ?
 C3 C12 C14 111.45(12) . . ?
 C13 C12 C11 112.06(12) . . ?
 C14 C12 C11 111.12(12) . . ?
 C14 C12 C13 108.70(12) . . ?
 C12 C13 H13A 109.5 . . ?
 C12 C13 H13B 109.5 . . ?
 C12 C13 H13C 109.5 . . ?
 H13A C13 H13B 109.5 . . ?
 H13A C13 H13C 109.5 . . ?
 H13B C13 H13C 109.5 . . ?
 C12 C14 H14A 109.5 . . ?
 C12 C14 H14B 109.5 . . ?
 C12 C14 H14C 109.5 . . ?
 H14A C14 H14B 109.5 . . ?
 H14A C14 H14C 109.5 . . ?
 H14B C14 H14C 109.5 . . ?
 C6 C15 C7 102.74(10) . . ?
 C6 C15 C27 113.26(11) . . ?
 C16 C15 C6 113.34(11) . . ?
 C16 C15 C7 112.88(11) . . ?
 C16 C15 C27 100.70(10) . . ?
 C27 C15 C7 114.42(11) . . ?
 C17 C16 C15 128.94(12) . . ?
 C17 C16 C21 119.55(12) . . ?
 C21 C16 C15 111.49(11) . . ?
 C16 C17 H17 119.4 . . ?
 C16 C17 C18 121.11(13) . . ?
 C18 C17 H17 119.4 . . ?
 C17 C18 C19 119.11(12) . . ?
 C17 C18 C40 120.1(2) . . ?
 C17 C18 C40A 116.6(2) . . ?
 C19 C18 C40 120.0(2) . . ?
 C19 C18 C40A 124.0(2) . . ?
 C18 C19 C36 125.7(3) . . ?
 C18 C19 C36A 120.8(3) . . ?
 C20 C19 C18 119.26(12) . . ?
 C20 C19 C36 115.1(3) . . ?
 C20 C19 C36A 120.0(3) . . ?
 C19 C20 H20 119.6 . . ?
 C21 C20 C19 120.79(13) . . ?
 C21 C20 H20 119.6 . . ?
 C16 C21 C22 108.21(12) . . ?
 C20 C21 C16 120.16(12) . . ?
 C20 C21 C22 131.63(13) . . ?
 C23 C22 C21 130.60(12) . . ?
 C23 C22 C27 120.61(12) . . ?
 C27 C22 C21 108.77(12) . . ?
 C22 C23 H23 119.5 . . ?
 C22 C23 C24 120.94(12) . . ?
 C24 C23 H23 119.5 . . ?
 C23 C24 C25 118.92(12) . . ?
 C23 C24 C32 117.15(12) . . ?
 C25 C24 C32 123.94(12) . . ?
 C24 C25 C28 121.85(12) . . ?
 C26 C25 C24 119.16(12) . . ?
 C26 C25 C28 118.96(12) . . ?
 C25 C26 H26 119.3 . . ?
 C27 C26 C25 121.36(12) . . ?
 C27 C26 H26 119.3 . . ?
 C22 C27 C15 110.83(11) . . ?
 C26 C27 C15 130.18(12) . . ?
 C26 C27 C22 119.00(12) . . ?
 C25 C28 C31 109.33(11) . . ?
 C29 C28 C25 109.36(11) . . ?
 C29 C28 C30 107.95(12) . . ?
 C29 C28 C31 111.13(12) . . ?
 C30 C28 C25 112.15(11) . . ?
 C30 C28 C31 106.91(12) . . ?
 C28 C29 H29A 109.5 . . ?
 C28 C29 H29B 109.5 . . ?
 C28 C29 H29C 109.5 . . ?
 H29A C29 H29B 109.5 . . ?
 H29A C29 H29C 109.5 . . ?
 H29B C29 H29C 109.5 . . ?
 C28 C30 H30A 109.5 . . ?
 C28 C30 H30B 109.5 . . ?
 C28 C30 H30C 109.5 . . ?
 H30A C30 H30B 109.5 . . ?
 H30A C30 H30C 109.5 . . ?
 H30B C30 H30C 109.5 . . ?
 C28 C31 H31A 109.2 . . ?
 C28 C31 H31B 109.2 . . ?
 H31A C31 H31B 107.9 . . ?
 C35 C31 C28 112.13(12) . . ?
 C35 C31 H31A 109.2 . . ?
 C35 C31 H31B 109.2 . . ?
 C24 C32 C33 110.29(12) . . ?
 C24 C32 C34 108.67(11) . . ?
 C24 C32 C35 111.17(11) . . ?
 C33 C32 C34 109.10(12) . . ?
 C35 C32 C33 107.41(12) . . ?
 C35 C32 C34 110.18(12) . . ?
 C32 C33 H33A 109.5 . . ?
 C32 C33 H33B 109.5 . . ?
 C32 C33 H33C 109.5 . . ?
 H33A C33 H33B 109.5 . . ?
 H33A C33 H33C 109.5 . . ?
 H33B C33 H33C 109.5 . . ?
 C32 C34 H34A 109.5 . . ?
 C32 C34 H34B 109.5 . . ?
 C32 C34 H34C 109.5 . . ?
 H34A C34 H34B 109.5 . . ?
 H34A C34 H34C 109.5 . . ?
 H34B C34 H34C 109.5 . . ?
 C31 C35 C32 112.70(12) . . ?
 C31 C35 H35A 109.1 . . ?
 C31 C35 H35B 109.1 . . ?
 C32 C35 H35A 109.1 . . ?
 C32 C35 H35B 109.1 . . ?
 H35A C35 H35B 107.8 . . ?
 C2 C44 C11 103.01(11) . . ?
 C45 C44 C2 110.36(11) . . ?
 C45 C44 C11 116.41(11) . . ?
 C45 C44 C56 100.81(11) . . ?
 C56 C44 C2 110.50(11) . . ?
 C56 C44 C11 115.93(11) . . ?
 C46 C45 C44 129.38(13) . . ?
 C46 C45 C50 119.64(13) . . ?
 C50 C45 C44 110.96(12) . . ?
 C45 C46 H46 119.5 . . ?
 C45 C46 C47 121.07(13) . . ?
 C47 C46 H46 119.5 . . ?
 C46 C47 C48 119.23(12) . . ?
 C46 C47 C61 119.09(13) . . ?
 C48 C47 C61 121.60(13) . . ?
 C47 C48 C57 123.20(12) . . ?
 C49 C48 C47 119.12(13) . . ?
 C49 C48 C57 117.57(12) . . ?
 C48 C49 H49 119.5 . . ?
 C50 C49 C48 120.96(13) . . ?
 C50 C49 H49 119.5 . . ?
 C45 C50 C51 108.31(12) . . ?
 C49 C50 C45 119.89(13) . . ?
 C49 C50 C51 131.78(13) . . ?
 C52 C51 C50 131.11(12) . . ?
 C52 C51 C56 120.54(12) . . ?
 C56 C51 C50 108.33(12) . . ?
 C51 C52 H52 119.7 . . ?
 C51 C52 C53 120.68(12) . . ?
 C53 C52 H52 119.7 . . ?
 C52 C53 C54 119.00(12) . . ?
 C52 C53 C65 118.48(12) . . ?
 C54 C53 C65 122.33(12) . . ?
 C53 C54 C69 122.96(12) . . ?
 C55 C54 C53 119.24(12) . . ?
 C55 C54 C69 117.80(12) . . ?
 C54 C55 H55 119.4 . . ?
 C56 C55 C54 121.14(12) . . ?
 C56 C55 H55 119.4 . . ?
 C51 C56 C44 110.94(12) . . ?
 C55 C56 C44 129.70(12) . . ?
 C55 C56 C51 119.29(12) . . ?
 C48 C57 C58 111.27(12) . . ?
 C48 C57 C59 107.96(12) . . ?
 C48 C57 C60 111.54(12) . . ?
 C58 C57 C59 108.77(13) . . ?
 C58 C57 C60 107.53(12) . . ?
 C59 C57 C60 109.75(13) . . ?
 C57 C58 H58A 109.5 . . ?
 C57 C58 H58B 109.5 . . ?
 C57 C58 H58C 109.5 . . ?
 H58A C58 H58B 109.5 . . ?
 H58A C58 H58C 109.5 . . ?
 H58B C58 H58C 109.5 . . ?
 C57 C59 H59A 109.5 . . ?
 C57 C59 H59B 109.5 . . ?
 C57 C59 H59C 109.5 . . ?
 H59A C59 H59B 109.5 . . ?
 H59A C59 H59C 109.5 . . ?
 H59B C59 H59C 109.5 . . ?
 C57 C60 H60A 108.9 . . ?
 C57 C60 H60B 108.9 . . ?
 H60A C60 H60B 107.7 . . ?
 C64 C60 C57 113.45(13) . . ?
 C64 C60 H60A 108.9 . . ?
 C64 C60 H60B 108.9 . . ?
 C47 C61 C63 112.55(12) . . ?
 C47 C61 C64 109.43(12) . . ?
 C62 C61 C47 107.98(12) . . ?
 C62 C61 C63 108.36(13) . . ?
 C62 C61 C64 111.32(13) . . ?
 C64 C61 C63 107.23(13) . . ?
 C61 C62 H62A 109.5 . . ?
 C61 C62 H62B 109.5 . . ?
 C61 C62 H62C 109.5 . . ?
 H62A C62 H62B 109.5 . . ?
 H62A C62 H62C 109.5 . . ?
 H62B C62 H62C 109.5 . . ?
 C61 C63 H63A 109.5 . . ?
 C61 C63 H63B 109.5 . . ?
 C61 C63 H63C 109.5 . . ?
 H63A C63 H63B 109.5 . . ?
 H63A C63 H63C 109.5 . . ?
 H63B C63 H63C 109.5 . . ?
 C60 C64 C61 112.25(13) . . ?
 C60 C64 H64A 109.2 . . ?
 C60 C64 H64B 109.2 . . ?
 C61 C64 H64A 109.2 . . ?
 C61 C64 H64B 109.2 . . ?
 H64A C64 H64B 107.9 . . ?
 C53 C65 C66 112.34(12) . . ?
 C53 C65 C67 108.14(11) . . ?
 C53 C65 C68 110.14(11) . . ?
 C66 C65 C67 107.78(12) . . ?
 C66 C65 C68 108.20(12) . . ?
 C68 C65 C67 110.22(12) . . ?
 C65 C66 H66A 109.5 . . ?
 C65 C66 H66B 109.5 . . ?
 C65 C66 H66C 109.5 . . ?
 H66A C66 H66B 109.5 . . ?
 H66A C66 H66C 109.5 . . ?
 H66B C66 H66C 109.5 . . ?
 C65 C67 H67A 109.5 . . ?
 C65 C67 H67B 109.5 . . ?
 C65 C67 H67C 109.5 . . ?
 H67A C67 H67B 109.5 . . ?
 H67A C67 H67C 109.5 . . ?
 H67B C67 H67C 109.5 . . ?
 C65 C68 H68A 109.2 . . ?
 C65 C68 H68B 109.2 . . ?
 H68A C68 H68B 107.9 . . ?
 C72 C68 C65 112.11(12) . . ?
 C72 C68 H68A 109.2 . . ?
 C72 C68 H68B 109.2 . . ?
 C54 C69 C70 108.75(12) . . ?
 C54 C69 C71 111.22(11) . . ?
 C70 C69 C71 108.72(12) . . ?
 C72 C69 C54 110.87(11) . . ?
 C72 C69 C70 109.88(12) . . ?
 C72 C69 C71 107.37(12) . . ?
 C69 C70 H70A 109.5 . . ?
 C69 C70 H70B 109.5 . . ?
 C69 C70 H70C 109.5 . . ?
 H70A C70 H70B 109.5 . . ?
 H70A C70 H70C 109.5 . . ?
 H70B C70 H70C 109.5 . . ?
 C69 C71 H71A 109.5 . . ?
 C69 C71 H71B 109.5 . . ?
 C69 C71 H71C 109.5 . . ?
 H71A C71 H71B 109.5 . . ?
 H71A C71 H71C 109.5 . . ?
 H71B C71 H71C 109.5 . . ?
 C68 C72 C69 112.63(12) . . ?
 C68 C72 H72A 109.1 . . ?
 C68 C72 H72B 109.1 . . ?
 C69 C72 H72A 109.1 . . ?
 C69 C72 H72B 109.1 . . ?
 H72A C72 H72B 107.8 . . ?
 N1 Ge1 C1 97.46(5) . . ?
 N2 N1 Ge1 119.26(11) . . ?
 N3 N2 N1 176.02(19) . . ?
 C37 C36 C19 111.2(11) . . ?
 C37 C36 C38 109.0(7) . . ?
 C38 C36 C19 111.5(8) . . ?
 C39 C36 C19 107.5(7) . . ?
 C39 C36 C37 109.7(7) . . ?
 C39 C36 C38 107.8(6) . . ?
 C36 C37 H37A 109.5 . . ?
 C36 C37 H37B 109.5 . . ?
 C36 C37 H37C 109.5 . . ?
 H37A C37 H37B 109.5 . . ?
 H37A C37 H37C 109.5 . . ?
 H37B C37 H37C 109.5 . . ?
 C36 C38 H38A 109.5 . . ?
 C36 C38 H38B 109.5 . . ?
 C36 C38 H38C 109.5 . . ?
 H38A C38 H38B 109.5 . . ?
 H38A C38 H38C 109.5 . . ?
 H38B C38 H38C 109.5 . . ?
 C36 C39 H39A 108.9 . . ?
 C36 C39 H39B 108.9 . . ?
 H39A C39 H39B 107.7 . . ?
 C43 C39 C36 113.2(7) . . ?
 C43 C39 H39A 108.9 . . ?
 C43 C39 H39B 108.9 . . ?
 C18 C40 C41 111.4(5) . . ?
 C18 C40 C42 105.5(4) . . ?
 C18 C40 C43 112.3(4) . . ?
 C41 C40 C42 109.8(5) . . ?
 C41 C40 C43 107.4(5) . . ?
 C43 C40 C42 110.4(5) . . ?
 C40 C41 H41A 109.5 . . ?
 C40 C41 H41B 109.5 . . ?
 C40 C41 H41C 109.5 . . ?
 H41A C41 H41B 109.5 . . ?
 H41A C41 H41C 109.5 . . ?
 H41B C41 H41C 109.5 . . ?
 C40 C42 H42A 109.5 . . ?
 C40 C42 H42B 109.5 . . ?
 C40 C42 H42C 109.5 . . ?
 H42A C42 H42B 109.5 . . ?
 H42A C42 H42C 109.5 . . ?
 H42B C42 H42C 109.5 . . ?
 C39 C43 C40 112.5(5) . . ?
 C39 C43 H43A 109.1 . . ?
 C39 C43 H43B 109.1 . . ?
 C40 C43 H43A 109.1 . . ?
 C40 C43 H43B 109.1 . . ?
 H43A C43 H43B 107.8 . . ?
 H73A C73 H73B 109.5 . . ?
 H73A C73 H73C 109.5 . . ?
 H73B C73 H73C 109.5 . . ?
 C74 C73 H73A 109.5 . . ?
 C74 C73 H73B 109.5 . . ?
 C74 C73 H73C 109.5 . . ?
 C73 C74 H74A 108.7 . . ?
 C73 C74 H74B 108.7 . . ?
 H74A C74 H74B 107.6 . . ?
 C75 C74 C73 114.2(4) . . ?
 C75 C74 H74A 108.7 . . ?
 C75 C74 H74B 108.7 . . ?
 C74 C75 H75A 108.7 . . ?
 C74 C75 H75B 108.7 . . ?
 C74 C75 C76 114.1(5) . . ?
 H75A C75 H75B 107.6 . . ?
 C76 C75 H75A 108.7 . . ?
 C76 C75 H75B 108.7 . . ?
 C75 C76 H76A 108.0 . . ?
 C75 C76 H76B 108.0 . . ?
 H76A C76 H76B 107.3 . . ?
 C77 C76 C75 117.1(5) . . ?
 C77 C76 H76A 108.0 . . ?
 C77 C76 H76B 108.0 . . ?
 C76 C77 H77A 108.5 . . ?
 C76 C77 H77B 108.5 . . ?
 H77A C77 H77B 107.5 . . ?
 C78 C77 C76 114.9(5) . . ?
 C78 C77 H77A 108.5 . . ?
 C78 C77 H77B 108.5 . . ?
 C77 C78 H78A 109.5 . . ?
 C77 C78 H78B 109.5 . . ?
 C77 C78 H78C 109.5 . . ?
 H78A C78 H78B 109.5 . . ?
 H78A C78 H78C 109.5 . . ?
 H78B C78 H78C 109.5 . . ?
 N1A Ge1A C1 98.4(4) . . ?
 N2A N1A Ge1A 122.0(11) . . ?
 N3A N2A N1A 168(2) . . ?
 C19 C36A C37A 107.6(9) . . ?
 C19 C36A C38A 109.0(8) . . ?
 C19 C36A C39A 114.2(6) . . ?
 C38A C36A C37A 108.2(6) . . ?
 C39A C36A C37A 108.5(6) . . ?
 C39A C36A C38A 109.2(6) . . ?
 C36A C37A H37D 109.5 . . ?
 C36A C37A H37E 109.5 . . ?
 C36A C37A H37F 109.5 . . ?
 H37D C37A H37E 109.5 . . ?
 H37D C37A H37F 109.5 . . ?
 H37E C37A H37F 109.5 . . ?
 C36A C38A H38D 109.5 . . ?
 C36A C38A H38E 109.5 . . ?
 C36A C38A H38F 109.5 . . ?
 H38D C38A H38E 109.5 . . ?
 H38D C38A H38F 109.5 . . ?
 H38E C38A H38F 109.5 . . ?
 C36A C39A H39C 109.2 . . ?
 C36A C39A H39D 109.2 . . ?
 H39C C39A H39D 107.9 . . ?
 C43A C39A C36A 112.2(6) . . ?
 C43A C39A H39C 109.2 . . ?
 C43A C39A H39D 109.2 . . ?
 C41A C40A C18 106.3(3) . . ?
 C41A C40A C42A 108.6(4) . . ?
 C42A C40A C18 114.7(4) . . ?
 C43A C40A C18 108.4(3) . . ?
 C43A C40A C41A 111.6(4) . . ?
 C43A C40A C42A 107.2(4) . . ?
 C40A C41A H41D 109.5 . . ?
 C40A C41A H41E 109.5 . . ?
 C40A C41A H41F 109.5 . . ?
 H41D C41A H41E 109.5 . . ?
 H41D C41A H41F 109.5 . . ?
 H41E C41A H41F 109.5 . . ?
 C40A C42A H42D 109.5 . . ?
 C40A C42A H42E 109.5 . . ?
 C40A C42A H42F 109.5 . . ?
 H42D C42A H42E 109.5 . . ?
 H42D C42A H42F 109.5 . . ?
 H42E C42A H42F 109.5 . . ?
 C39A C43A C40A 112.3(4) . . ?
 C39A C43A H43C 109.2 . . ?
 C39A C43A H43D 109.2 . . ?
 C40A C43A H43C 109.2 . . ?
 C40A C43A H43D 109.2 . . ?
 H43C C43A H43D 107.9 . . ?
 H73D C73A H73E 109.5 . . ?
 H73D C73A H73F 109.5 . . ?
 H73E C73A H73F 109.5 . . ?
 C74A C73A H73D 109.5 . . ?
 C74A C73A H73E 109.5 . . ?
 C74A C73A H73F 109.5 . . ?
 C73A C74A H74C 108.8 . . ?
 C73A C74A H74D 108.8 . . ?
 H74C C74A H74D 107.7 . . ?
 C75A C74A C73A 113.6(9) . . ?
 C75A C74A H74C 108.8 . . ?
 C75A C74A H74D 108.8 . . ?
 C74A C75A H75C 108.7 . . ?
 C74A C75A H75D 108.7 . . ?
 C74A C75A C76A 114.0(8) . . ?
 H75C C75A H75D 107.6 . . ?
 C76A C75A H75C 108.7 . . ?
 C76A C75A H75D 108.7 . . ?
 C75A C76A H76C 108.3 . . ?
 C75A C76A H76D 108.3 . . ?
 H76C C76A H76D 107.4 . . ?
 C77A C76A C75A 115.9(8) . . ?
 C77A C76A H76C 108.3 . . ?
 C77A C76A H76D 108.3 . . ?
 C76A C77A H77C 108.3 . . ?
 C76A C77A H77D 108.3 . . ?
 H77C C77A H77D 107.4 . . ?
 C78A C77A C76A 116.1(8) . . ?
 C78A C77A H77C 108.3 . . ?
 C78A C77A H77D 108.3 . . ?
 C77A C78A H78D 109.5 . . ?
 C77A C78A H78E 109.5 . . ?
 C77A C78A H78F 109.5 . . ?
 H78D C78A H78E 109.5 . . ?
 H78D C78A H78F 109.5 . . ?
 H78E C78A H78F 109.5 . . ?

loop_
  _geom_torsion_atom_site_label_1
  _geom_torsion_atom_site_label_2
  _geom_torsion_atom_site_label_3
  _geom_torsion_atom_site_label_4
  _geom_torsion
  _geom_torsion_site_symmetry_1
  _geom_torsion_site_symmetry_2
  _geom_torsion_site_symmetry_3
  _geom_torsion_site_symmetry_4
  _geom_torsion_publ_flag
 C1 C2 C3 C4 -0.6(2) . . . . ?
 C1 C2 C3 C12 178.01(12) . . . . ?
 C1 C2 C44 C11 -171.77(13) . . . . ?
 C1 C2 C44 C45 -46.84(17) . . . . ?
 C1 C2 C44 C56 63.79(17) . . . . ?
 C1 C6 C15 C7 167.84(12) . . . . ?
 C1 C6 C15 C16 45.72(18) . . . . ?
 C1 C6 C15 C27 -68.21(17) . . . . ?
 C2 C1 C6 C5 -3.06(19) . . . . ?
 C2 C1 C6 C15 177.01(12) . . . . ?
 C2 C3 C4 C5 -1.1(2) . . . . ?
 C2 C3 C12 C11 -4.82(15) . . . . ?
 C2 C3 C12 C13 115.02(13) . . . . ?
 C2 C3 C12 C14 -124.01(13) . . . . ?
 C2 C44 C45 C46 -69.10(18) . . . . ?
 C2 C44 C45 C50 109.08(13) . . . . ?
 C2 C44 C56 C51 -109.08(13) . . . . ?
 C2 C44 C56 C55 67.75(18) . . . . ?
 C3 C2 C44 C11 9.06(14) . . . . ?
 C3 C2 C44 C45 133.99(12) . . . . ?
 C3 C2 C44 C56 -115.38(12) . . . . ?
 C3 C4 C5 C6 0.6(2) . . . . ?
 C3 C4 C5 C8 177.15(13) . . . . ?
 C4 C3 C12 C11 173.71(13) . . . . ?
 C4 C3 C12 C13 -66.46(18) . . . . ?
 C4 C3 C12 C14 54.52(19) . . . . ?
 C4 C5 C6 C1 1.5(2) . . . . ?
 C4 C5 C6 C15 -178.52(12) . . . . ?
 C4 C5 C8 C7 -171.46(13) . . . . ?
 C4 C5 C8 C9 68.03(17) . . . . ?
 C4 C5 C8 C10 -53.09(18) . . . . ?
 C5 C6 C15 C7 -12.11(14) . . . . ?
 C5 C6 C15 C16 -134.22(12) . . . . ?
 C5 C6 C15 C27 111.85(12) . . . . ?
 C6 C1 C2 C3 2.61(19) . . . . ?
 C6 C1 C2 C44 -176.47(12) . . . . ?
 C6 C5 C8 C7 5.29(14) . . . . ?
 C6 C5 C8 C9 -115.22(13) . . . . ?
 C6 C5 C8 C10 123.67(12) . . . . ?
 C6 C15 C16 C17 59.90(18) . . . . ?
 C6 C15 C16 C21 -121.63(12) . . . . ?
 C6 C15 C27 C22 122.24(12) . . . . ?
 C6 C15 C27 C26 -57.77(19) . . . . ?
 C7 C15 C16 C17 -56.38(18) . . . . ?
 C7 C15 C16 C21 122.09(12) . . . . ?
 C7 C15 C27 C22 -120.45(12) . . . . ?
 C7 C15 C27 C26 59.54(18) . . . . ?
 C8 C5 C6 C1 -175.45(12) . . . . ?
 C8 C5 C6 C15 4.50(15) . . . . ?
 C8 C7 C15 C6 15.21(13) . . . . ?
 C8 C7 C15 C16 137.64(11) . . . . ?
 C8 C7 C15 C27 -107.98(12) . . . . ?
 C11 C44 C45 C46 47.8(2) . . . . ?
 C11 C44 C45 C50 -134.03(12) . . . . ?
 C11 C44 C56 C51 134.23(12) . . . . ?
 C11 C44 C56 C55 -48.9(2) . . . . ?
 C12 C3 C4 C5 -179.48(13) . . . . ?
 C12 C11 C44 C2 -11.91(14) . . . . ?
 C12 C11 C44 C45 -132.80(12) . . . . ?
 C12 C11 C44 C56 108.88(13) . . . . ?
 C15 C7 C8 C5 -12.80(13) . . . . ?
 C15 C7 C8 C9 107.55(13) . . . . ?
 C15 C7 C8 C10 -131.08(12) . . . . ?
 C15 C16 C17 C18 178.66(13) . . . . ?
 C15 C16 C21 C20 -179.88(12) . . . . ?
 C15 C16 C21 C22 -0.29(15) . . . . ?
 C16 C15 C27 C22 0.90(14) . . . . ?
 C16 C15 C27 C26 -179.11(13) . . . . ?
 C16 C17 C18 C19 0.8(2) . . . . ?
 C16 C17 C18 C40 170.6(3) . . . . ?
 C16 C17 C18 C40A -174.0(2) . . . . ?
 C16 C21 C22 C23 178.99(14) . . . . ?
 C16 C21 C22 C27 0.88(15) . . . . ?
 C17 C16 C21 C20 -1.2(2) . . . . ?
 C17 C16 C21 C22 178.34(12) . . . . ?
 C17 C18 C19 C20 -0.9(2) . . . . ?
 C17 C18 C19 C36 178.6(5) . . . . ?
 C17 C18 C19 C36A 179.3(4) . . . . ?
 C17 C18 C40 C41 -40.3(5) . . . . ?
 C17 C18 C40 C42 78.8(4) . . . . ?
 C17 C18 C40 C43 -160.8(3) . . . . ?
 C17 C18 C40A C41A -80.8(4) . . . . ?
 C17 C18 C40A C42A 39.3(4) . . . . ?
 C17 C18 C40A C43A 159.1(2) . . . . ?
 C18 C19 C20 C21 0.0(2) . . . . ?
 C18 C19 C36 C37 -111.4(6) . . . . ?
 C18 C19 C36 C38 126.7(5) . . . . ?
 C18 C19 C36 C39 8.7(8) . . . . ?
 C18 C19 C36A C37A -125.8(5) . . . . ?
 C18 C19 C36A C38A 117.1(4) . . . . ?
 C18 C19 C36A C39A -5.3(8) . . . . ?
 C18 C40 C43 C39 -44.3(6) . . . . ?
 C18 C40A C43A C39A 48.8(5) . . . . ?
 C19 C18 C40 C41 129.5(3) . . . . ?
 C19 C18 C40 C42 -111.4(3) . . . . ?
 C19 C18 C40 C43 9.0(5) . . . . ?
 C19 C18 C40A C41A 104.8(3) . . . . ?
 C19 C18 C40A C42A -135.2(3) . . . . ?
 C19 C18 C40A C43A -15.4(4) . . . . ?
 C19 C20 C21 C16 1.1(2) . . . . ?
 C19 C20 C21 C22 -178.36(13) . . . . ?
 C19 C36 C39 C43 -44.1(9) . . . . ?
 C19 C36A C39A C43A 38.9(8) . . . . ?
 C20 C19 C36 C37 68.1(7) . . . . ?
 C20 C19 C36 C38 -53.8(7) . . . . ?
 C20 C19 C36 C39 -171.8(5) . . . . ?
 C20 C19 C36A C37A 54.4(7) . . . . ?
 C20 C19 C36A C38A -62.7(6) . . . . ?
 C20 C19 C36A C39A 175.0(4) . . . . ?
 C20 C21 C22 C23 -1.5(3) . . . . ?
 C20 C21 C22 C27 -179.60(14) . . . . ?
 C21 C16 C17 C18 0.3(2) . . . . ?
 C21 C22 C23 C24 -178.38(13) . . . . ?
 C21 C22 C27 C15 -1.13(15) . . . . ?
 C21 C22 C27 C26 178.88(12) . . . . ?
 C22 C23 C24 C25 -0.8(2) . . . . ?
 C22 C23 C24 C32 179.23(12) . . . . ?
 C23 C22 C27 C15 -179.46(12) . . . . ?
 C23 C22 C27 C26 0.5(2) . . . . ?
 C23 C24 C25 C26 1.96(19) . . . . ?
 C23 C24 C25 C28 -179.74(12) . . . . ?
 C23 C24 C32 C33 -51.98(17) . . . . ?
 C23 C24 C32 C34 67.57(16) . . . . ?
 C23 C24 C32 C35 -171.01(12) . . . . ?
 C24 C25 C26 C27 -1.9(2) . . . . ?
 C24 C25 C28 C29 -101.74(15) . . . . ?
 C24 C25 C28 C30 138.55(13) . . . . ?
 C24 C25 C28 C31 20.15(18) . . . . ?
 C24 C32 C35 C31 -39.73(17) . . . . ?
 C25 C24 C32 C33 128.06(14) . . . . ?
 C25 C24 C32 C34 -112.39(15) . . . . ?
 C25 C24 C32 C35 9.03(19) . . . . ?
 C25 C26 C27 C15 -179.33(13) . . . . ?
 C25 C26 C27 C22 0.7(2) . . . . ?
 C25 C28 C31 C35 -50.89(16) . . . . ?
 C26 C25 C28 C29 76.56(16) . . . . ?
 C26 C25 C28 C30 -43.15(17) . . . . ?
 C26 C25 C28 C31 -161.56(12) . . . . ?
 C27 C15 C16 C17 -178.82(13) . . . . ?
 C27 C15 C16 C21 -0.35(14) . . . . ?
 C27 C22 C23 C24 -0.5(2) . . . . ?
 C28 C25 C26 C27 179.74(12) . . . . ?
 C28 C31 C35 C32 63.55(17) . . . . ?
 C29 C28 C31 C35 69.92(16) . . . . ?
 C30 C28 C31 C35 -172.51(12) . . . . ?
 C32 C24 C25 C26 -178.08(12) . . . . ?
 C32 C24 C25 C28 0.2(2) . . . . ?
 C33 C32 C35 C31 -160.47(13) . . . . ?
 C34 C32 C35 C31 80.80(15) . . . . ?
 C44 C2 C3 C4 178.59(12) . . . . ?
 C44 C2 C3 C12 -2.78(16) . . . . ?
 C44 C11 C12 C3 10.43(14) . . . . ?
 C44 C11 C12 C13 -108.31(13) . . . . ?
 C44 C11 C12 C14 129.85(12) . . . . ?
 C44 C45 C46 C47 177.73(13) . . . . ?
 C44 C45 C50 C49 -176.03(12) . . . . ?
 C44 C45 C50 C51 5.33(15) . . . . ?
 C45 C44 C56 C51 7.63(14) . . . . ?
 C45 C44 C56 C55 -175.54(14) . . . . ?
 C45 C46 C47 C48 -2.1(2) . . . . ?
 C45 C46 C47 C61 174.58(13) . . . . ?
 C45 C50 C51 C52 -178.88(14) . . . . ?
 C45 C50 C51 C56 -0.20(15) . . . . ?
 C46 C45 C50 C49 2.4(2) . . . . ?
 C46 C45 C50 C51 -176.29(12) . . . . ?
 C46 C47 C48 C49 2.5(2) . . . . ?
 C46 C47 C48 C57 -173.74(13) . . . . ?
 C46 C47 C61 C62 -82.94(16) . . . . ?
 C46 C47 C61 C63 36.62(19) . . . . ?
 C46 C47 C61 C64 155.74(13) . . . . ?
 C47 C48 C49 C50 -0.5(2) . . . . ?
 C47 C48 C57 C58 -134.44(14) . . . . ?
 C47 C48 C57 C59 106.28(15) . . . . ?
 C47 C48 C57 C60 -14.37(19) . . . . ?
 C47 C61 C64 C60 52.40(17) . . . . ?
 C48 C47 C61 C62 93.69(16) . . . . ?
 C48 C47 C61 C63 -146.75(14) . . . . ?
 C48 C47 C61 C64 -27.63(19) . . . . ?
 C48 C49 C50 C45 -1.9(2) . . . . ?
 C48 C49 C50 C51 176.34(13) . . . . ?
 C48 C57 C60 C64 39.24(19) . . . . ?
 C49 C48 C57 C58 49.23(17) . . . . ?
 C49 C48 C57 C59 -70.05(16) . . . . ?
 C49 C48 C57 C60 169.30(13) . . . . ?
 C49 C50 C51 C52 2.7(3) . . . . ?
 C49 C50 C51 C56 -178.62(14) . . . . ?
 C50 C45 C46 C47 -0.3(2) . . . . ?
 C50 C51 C52 C53 179.37(13) . . . . ?
 C50 C51 C56 C44 -4.97(15) . . . . ?
 C50 C51 C56 C55 177.82(12) . . . . ?
 C51 C52 C53 C54 2.1(2) . . . . ?
 C51 C52 C53 C65 -173.05(12) . . . . ?
 C52 C51 C56 C44 173.88(12) . . . . ?
 C52 C51 C56 C55 -3.3(2) . . . . ?
 C52 C53 C54 C55 -2.6(2) . . . . ?
 C52 C53 C54 C69 177.22(12) . . . . ?
 C52 C53 C65 C66 -41.46(18) . . . . ?
 C52 C53 C65 C67 77.36(15) . . . . ?
 C52 C53 C65 C68 -162.14(12) . . . . ?
 C53 C54 C55 C56 0.1(2) . . . . ?
 C53 C54 C69 C70 -103.36(15) . . . . ?
 C53 C54 C69 C71 136.94(14) . . . . ?
 C53 C54 C69 C72 17.56(19) . . . . ?
 C53 C65 C68 C72 -49.09(16) . . . . ?
 C54 C53 C65 C66 143.54(14) . . . . ?
 C54 C53 C65 C67 -97.64(15) . . . . ?
 C54 C53 C65 C68 22.85(18) . . . . ?
 C54 C55 C56 C44 -173.73(13) . . . . ?
 C54 C55 C56 C51 2.9(2) . . . . ?
 C54 C69 C72 C68 -43.86(17) . . . . ?
 C55 C54 C69 C70 76.42(15) . . . . ?
 C55 C54 C69 C71 -43.28(17) . . . . ?
 C55 C54 C69 C72 -162.67(12) . . . . ?
 C56 C44 C45 C46 174.08(14) . . . . ?
 C56 C44 C45 C50 -7.74(14) . . . . ?
 C56 C51 C52 C53 0.8(2) . . . . ?
 C57 C48 C49 C50 175.96(12) . . . . ?
 C57 C60 C64 C61 -61.16(19) . . . . ?
 C58 C57 C60 C64 161.49(14) . . . . ?
 C59 C57 C60 C64 -80.35(17) . . . . ?
 C61 C47 C48 C49 -174.09(13) . . . . ?
 C61 C47 C48 C57 9.6(2) . . . . ?
 C62 C61 C64 C60 -66.87(17) . . . . ?
 C63 C61 C64 C60 174.76(13) . . . . ?
 C65 C53 C54 C55 172.42(13) . . . . ?
 C65 C53 C54 C69 -7.8(2) . . . . ?
 C65 C68 C72 C69 62.65(17) . . . . ?
 C66 C65 C68 C72 -172.24(13) . . . . ?
 C67 C65 C68 C72 70.14(16) . . . . ?
 C69 C54 C55 C56 -179.73(12) . . . . ?
 C70 C69 C72 C68 76.38(15) . . . . ?
 C71 C69 C72 C68 -165.53(12) . . . . ?
 Ge1 C1 C2 C3 -158.98(10) . . . . ?
 Ge1 C1 C2 C44 21.94(18) . . . . ?
 Ge1 C1 C6 C5 159.16(10) . . . . ?
 Ge1 C1 C6 C15 -20.78(18) . . . . ?
 C36 C19 C20 C21 -179.6(4) . . . . ?
 C36 C39 C43 C40 65.2(8) . . . . ?
 C37 C36 C39 C43 77.0(11) . . . . ?
 C38 C36 C39 C43 -164.4(8) . . . . ?
 C40 C18 C19 C20 -170.8(3) . . . . ?
 C40 C18 C19 C36 8.7(6) . . . . ?
 C41 C40 C43 C39 -167.1(6) . . . . ?
 C42 C40 C43 C39 73.1(7) . . . . ?
 C73 C74 C75 C76 -179.7(5) . . . . ?
 C74 C75 C76 C77 -178.7(5) . . . . ?
 C75 C76 C77 C78 -178.2(6) . . . . ?
 Ge1A C1 C2 C3 134.47(15) . . . . ?
 Ge1A C1 C2 C44 -44.61(19) . . . . ?
 Ge1A C1 C6 C5 -135.70(15) . . . . ?
 Ge1A C1 C6 C15 44.37(18) . . . . ?
 Ge1A N1A N2A N3A 2(12) . . . . ?
 C36A C19 C20 C21 179.7(4) . . . . ?
 C36A C39A C43A C40A -63.1(7) . . . . ?
 C37A C36A C39A C43A 158.9(9) . . . . ?
 C38A C36A C39A C43A -83.4(8) . . . . ?
 C40A C18 C19 C20 173.4(2) . . . . ?
 C40A C18 C19 C36A -6.3(5) . . . . ?
 C41A C40A C43A C39A -68.0(6) . . . . ?
 C42A C40A C43A C39A 173.2(4) . . . . ?
 C73A C74A C75A C76A -176.7(13) . . . . ?
 C74A C75A C76A C77A -178.7(10) . . . . ?
 C75A C76A C77A C78A 172.1(11) . . . . ?

_olex2_submission_special_instructions  'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
