data_hy
_audit_creation_date               2023-07-06
_audit_creation_method
;
Olex2 1.2
(compiled 2018.05.29 svn.r3508 for OlexSys, GUI svn.r5506)
;
_shelx_SHELXL_version_number       '2016/4'
_audit_contact_author_address      ?
_audit_contact_author_email        ?
_audit_contact_author_name         ''
_audit_contact_author_phone        ?
_publ_contact_author_id_orcid      ?
_publ_section_references
;
Dolomanov, O.V., Bourhis, L.J., Gildea, R.J, Howard, J.A.K. & Puschmann, H.
 (2009), J. Appl. Cryst. 42, 339-341.

Sheldrick, G.M. (2015). Acta Cryst. A71, 3-8.

Sheldrick, G.M. (2015). Acta Cryst. C71, 3-8.
;
_chemical_name_common              ?
_chemical_name_systematic          ?
_chemical_formula_moiety           'C148 H128 Au8 N2 P8'
_chemical_formula_sum              'C148 H128 Au8 Cl0.25 N2 O0.25 P8'
_chemical_formula_weight           3770.87
_chemical_melting_point            ?
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'C' 'C' 0.0181 0.0091 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Au' 'Au' -4.4197 7.2980
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N' 'N' 0.0311 0.0180 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'P' 'P' 0.2955 0.4335 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Cl' 'Cl' 0.3639 0.7018 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'O' 'O' 0.0492 0.0322 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_shelx_space_group_comment
;
The symmetry employed for this shelxl refinement is uniquely defined
by the following loop, which should always be used as a source of
symmetry information in preference to the above space-group names.
They are only intended as comments.
;
_space_group_crystal_system        'monoclinic'
_space_group_IT_number             15
_space_group_name_H-M_alt          'C 1 2/c 1'
_space_group_name_Hall             '-C 2yc'
loop_
  _space_group_symop_operation_xyz
 'x, y, z'
 '-x, y, -z+1/2'
 'x+1/2, y+1/2, z'
 '-x+1/2, y+1/2, -z+1/2'
 '-x, -y, -z'
 'x, -y, z-1/2'
 '-x+1/2, -y+1/2, -z'
 'x+1/2, -y+1/2, z-1/2'

_cell_length_a                     40.48288(17)
_cell_length_b                     17.18787(7)
_cell_length_c                     24.82685(10)
_cell_angle_alpha                  90
_cell_angle_beta                   103.6391(4)
_cell_angle_gamma                  90
_cell_volume                       16787.73(12)
_cell_formula_units_Z              4
_cell_measurement_reflns_used      28526
_cell_measurement_temperature      200
_cell_measurement_theta_max        73.4850
_cell_measurement_theta_min        2.8410
_shelx_estimated_absorpt_T_max     0.769
_shelx_estimated_absorpt_T_min     0.681
_exptl_absorpt_coefficient_mu      13.858
_exptl_absorpt_correction_T_max    1.00000
_exptl_absorpt_correction_T_min    0.84782
_exptl_absorpt_correction_type     multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro 1.171.39.27b (Rigaku Oxford Diffraction, 2015)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_absorpt_special_details     ?
_exptl_crystal_colour              'clear reddish black'
_exptl_crystal_colour_lustre       clear
_exptl_crystal_colour_modifier     reddish
_exptl_crystal_colour_primary      black
_exptl_crystal_density_diffrn      1.492
_exptl_crystal_density_meas        ?
_exptl_crystal_density_method      ?
_exptl_crystal_description         block
_exptl_crystal_F_000               7153
_exptl_crystal_size_max            0.03
_exptl_crystal_size_mid            0.02
_exptl_crystal_size_min            0.02
_exptl_transmission_factor_max     ?
_exptl_transmission_factor_min     ?
_diffrn_reflns_av_R_equivalents    0.0329
_diffrn_reflns_av_unetI/netI       0.0324
_diffrn_reflns_Laue_measured_fraction_full  0.998
_diffrn_reflns_Laue_measured_fraction_max  0.977
_diffrn_reflns_limit_h_max         48
_diffrn_reflns_limit_h_min         -49
_diffrn_reflns_limit_k_max         21
_diffrn_reflns_limit_k_min         -18
_diffrn_reflns_limit_l_max         30
_diffrn_reflns_limit_l_min         -28
_diffrn_reflns_number              54141
_diffrn_reflns_point_group_measured_fraction_full  0.998
_diffrn_reflns_point_group_measured_fraction_max  0.977
_diffrn_reflns_theta_full          67.684
_diffrn_reflns_theta_max           73.759
_diffrn_reflns_theta_min           2.806
_diffrn_ambient_environment        N~2~
_diffrn_ambient_temperature        200
_diffrn_detector                   'CCD plate'
_diffrn_detector_area_resol_mean   ?
_diffrn_measured_fraction_theta_full  0.998
_diffrn_measured_fraction_theta_max  0.977
_diffrn_measurement_details
;
List of Runs (angles in degrees, time in seconds):

  # Type    Start    End  Width  tₑₓₚ   ω     θ     κ     φ   Frames
--------------------------------------------------------------------------
  1  ω    -27.00   8.00   0.50    0.50    --    0.00  77.00 -90.00   70
  2  ω    -29.00  44.00   0.50    0.50    --    0.00  57.00  60.00  146
  3  ω    -45.00  -3.00   0.50    0.50    --    0.00 -57.00-180.00   84
  4  ω      3.00  89.00   0.50    0.50    --    0.00  57.00-180.00  172
  5  ω     81.00 107.00   0.50    3.00    --   98.80 -82.00 -60.00   52
  6  ω    149.00 187.00   0.50    3.00    --   98.80  30.00   0.00   76
  7  ω     65.00 136.00   0.50    3.00    --   98.80  30.00   0.00  142
  8  ω     78.00 134.00   0.50    3.00    --   98.80  61.00  30.00  112
  9  ω      9.00 126.00   0.50    3.00    --   98.80 -61.00 -90.00  234
 10  ω     28.00 118.00   0.50    3.00    --   98.80 -82.00-150.00  180
 11  ω    107.00 185.00   0.50    3.00    --   98.80  82.00   0.00  156
 12  ω     37.00 128.00   0.50    3.00    --   98.80 -82.00 -90.00  182
 13  ω     78.00 103.00   0.50    3.00    --   98.80 -82.00-120.00   50
 14  ω     41.00 188.00   0.50    3.00    --   98.80  15.00 -30.00  294
;
_diffrn_measurement_device         'four-circle diffractometer'
_diffrn_measurement_device_type    'XtaLAB AFC12 (RINC): Kappa single'
_diffrn_measurement_method         'ω scans'
_diffrn_orient_matrix_type        
 'CrysAlisPro convention (1999,Acta A55,543-557)'
_diffrn_orient_matrix_UB_11        0.0231378000
_diffrn_orient_matrix_UB_12        -0.0555406000
_diffrn_orient_matrix_UB_13        -0.0231526000
_diffrn_orient_matrix_UB_21        0.0146533000
_diffrn_orient_matrix_UB_22        0.0696782000
_diffrn_orient_matrix_UB_23        -0.0257122000
_diffrn_orient_matrix_UB_31        0.0279839000
_diffrn_orient_matrix_UB_32        0.0094606000
_diffrn_orient_matrix_UB_33        0.0536953000
_diffrn_radiation_monochromator    graphite
_diffrn_radiation_probe            x-ray
_diffrn_radiation_type             CuK\a
_diffrn_radiation_wavelength       1.54184
_diffrn_source                     'fine-focus sealed X-ray tube'
_diffrn_source_type                'Enhance (Cu) X-ray Source'
_diffrn_special_details            ?
_reflns_Friedel_coverage           0.000
_reflns_Friedel_fraction_full      .
_reflns_Friedel_fraction_max       .
_reflns_number_gt                  14834
_reflns_number_total               16597
_reflns_odcompleteness_completeness  99.84
_reflns_odcompleteness_iscentric   1
_reflns_odcompleteness_theta       66.97
_reflns_special_details
;
 Reflections were merged by SHELXL according to the crystal
 class for the calculation of statistics and refinement.
 
 Structure factors included contributions from the .fab file.
 
 _reflns_Friedel_fraction is defined as the number of unique
 Friedel pairs measured divided by the number that would be
 possible theoretically, ignoring centric projections and
 systematic absences.
;
_reflns_threshold_expression       'I > 2σ(I)'
_computing_cell_refinement         'CrysAlisPro 1.171.39.27b (Rigaku OD, 2015)'
_computing_data_collection         'CrysAlisPro 1.171.39.27b (Rigaku OD, 2015)'
_computing_data_reduction          'CrysAlisPro 1.171.39.27b (Rigaku OD, 2015)'
_computing_molecular_graphics      'Olex2 (Dolomanov et al., 2009)'
_computing_publication_material    'Olex2 (Dolomanov et al., 2009)'
_computing_structure_refinement    'ShelXL (Sheldrick, 2015)'
_computing_structure_solution      'ShelXT (Sheldrick, 2015)'
_refine_diff_density_max           0.812
_refine_diff_density_min           -0.731
_refine_diff_density_rms           0.083
_refine_ls_extinction_coef         .
_refine_ls_extinction_method       none
_refine_ls_goodness_of_fit_ref     1.069
_refine_ls_hydrogen_treatment      constr
_refine_ls_matrix_type             full
_refine_ls_number_parameters       748
_refine_ls_number_reflns           16597
_refine_ls_number_restraints       0
_refine_ls_R_factor_all            0.0270
_refine_ls_R_factor_gt             0.0239
_refine_ls_restrained_S_all        1.069
_refine_ls_shift/su_max            0.006
_refine_ls_shift/su_mean           0.000
_refine_ls_structure_factor_coef   Fsqd
_refine_ls_weighting_details      
 'w=1/[σ²(Fo²)+(0.0308P)²+3.9815P] where P=(Fo²+2Fc²)/3'
_refine_ls_weighting_scheme        calc
_refine_ls_wR_factor_gt            0.0612
_refine_ls_wR_factor_ref           0.0624
_refine_special_details            ?
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H) groups, All C(H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C1(H1A,H1B), C3(H3A,H3B), C6(H6A,H6B), C7(H7A,H7B), C9(H9A,H9B), C17(H17A,H17B)
2.b Aromatic/amide H refined with riding coordinates:
 C8(H8), C12(H12), C13(H13), C15(H15), C16(H16), C18(H18), C20(H20), C23(H23),
 C26(H26), C27(H27), C28(H28), C29(H29), C30(H30), C32(H32), C33(H33), C34(H34),
  C35(H35), C37(H37), C38(H38), C40(H40), C41(H41), C42(H42), C43(H43),
 C44(H44), C45(H45), C46(H46), C47(H47), C48(H48), C49(H49), C50(H50), C51(H51),
  C54(H54), C55(H55), C56(H56), C57(H57), C58(H58), C59(H59), C60(H60),
 C61(H61), C62(H62), C63(H63), C64(H64), C65(H65), C66(H66), C67(H67), C68(H68),
  C69(H69), C70(H70), C71(H71), C72(H72), C73(H73), C74(H74)
;
_atom_sites_solution_hydrogens     geom
_atom_sites_solution_primary       dual
_atom_sites_solution_secondary     ?
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_site_symmetry_order
  _atom_site_calc_flag
  _atom_site_refinement_flags_posn
  _atom_site_refinement_flags_adp
  _atom_site_refinement_flags_occupancy
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 Au01 Au 0.22954(2) 0.75658(2) 0.53345(2) 0.03288(4) Uani 1 1 d . . . . .
 Au02 Au 0.29895(2) 0.72376(2) 0.58227(2) 0.03590(4) Uani 1 1 d . . . . .
 Au03 Au 0.21500(2) 0.63349(2) 0.45679(2) 0.03711(4) Uani 1 1 d . . . . .
 Au04 Au 0.33573(2) 0.85359(2) 0.65799(2) 0.04382(4) Uani 1 1 d . . . . .
 P005 P 0.19481(2) 0.76111(5) 0.59482(3) 0.03497(17) Uani 1 1 d . . . . .
 P006 P 0.31392(2) 0.60251(5) 0.62185(3) 0.03793(17) Uani 1 1 d . . . . .
 P007 P 0.21497(2) 0.50498(5) 0.48586(3) 0.03974(18) Uani 1 1 d . . . . .
 P008 P 0.30836(2) 0.89049(6) 0.72521(4) 0.04167(19) Uani 1 1 d . . . . .
 C1 C 0.21785(9) 0.5015(2) 0.56049(14) 0.0437(8) Uani 1 1 d . . . . .
 H1A H 0.195438 0.515783 0.567076 0.052 Uiso 1 1 calc R . . . .
 H1B H 0.222699 0.447229 0.573320 0.052 Uiso 1 1 calc R . . . .
 C2 C 0.16730(9) 0.6776(2) 0.59600(15) 0.0428(8) Uani 1 1 d . . . . .
 C3 C 0.24473(9) 0.5543(2) 0.59553(14) 0.0427(7) Uani 1 1 d . . . . .
 H3A H 0.243391 0.550652 0.634754 0.051 Uiso 1 1 calc R . . . .
 H3B H 0.239862 0.608839 0.583403 0.051 Uiso 1 1 calc R . . . .
 C4 C 0.32081(8) 0.5946(2) 0.69719(13) 0.0395(7) Uani 1 1 d . . . . .
 C5 C 0.29441(9) 0.9907(2) 0.72033(14) 0.0439(8) Uani 1 1 d . . . . .
 C6 C 0.27114(9) 0.8326(2) 0.72715(14) 0.0424(7) Uani 1 1 d . . . . .
 H6A H 0.277940 0.777450 0.734064 0.051 Uiso 1 1 calc R . . . .
 H6B H 0.261511 0.850529 0.758132 0.051 Uiso 1 1 calc R . . . .
 C7 C 0.28062(9) 0.5335(2) 0.59134(14) 0.0433(8) Uani 1 1 d . . . . .
 H7A H 0.280516 0.527297 0.551650 0.052 Uiso 1 1 calc R . . . .
 H7B H 0.286587 0.482323 0.609367 0.052 Uiso 1 1 calc R . . . .
 C8 C 0.26812(9) 1.0162(2) 0.74351(15) 0.0474(8) Uani 1 1 d . . . . .
 H8 H 0.257325 0.980422 0.763024 0.057 Uiso 1 1 calc R . . . .
 C9 C 0.21939(9) 0.7706(2) 0.66599(14) 0.0417(7) Uani 1 1 d . . . . .
 H9A H 0.203700 0.778089 0.690693 0.050 Uiso 1 1 calc R . . . .
 H9B H 0.232285 0.721981 0.677232 0.050 Uiso 1 1 calc R . . . .
 C10 C 0.24837(9) 0.4443(2) 0.47138(15) 0.0469(8) Uani 1 1 d . . . . .
 C11 C 0.16498(9) 0.8416(2) 0.58407(13) 0.0407(7) Uani 1 1 d . . . . .
 C12 C 0.26035(10) 0.4621(3) 0.42448(17) 0.0610(11) Uani 1 1 d . . . . .
 H12 H 0.252061 0.506738 0.402959 0.073 Uiso 1 1 calc R . . . .
 N00M N 0.50098(9) 0.7334(2) 0.49502(14) 0.0587(9) Uani 1 1 d . . . . .
 C13 C 0.31907(11) 0.5229(2) 0.72190(16) 0.0525(9) Uani 1 1 d . . . . .
 H13 H 0.311756 0.478178 0.699777 0.063 Uiso 1 1 calc R . . . .
 C14 C 0.35240(10) 0.5555(2) 0.61095(15) 0.0483(8) Uani 1 1 d . . . . .
 C15 C 0.32813(11) 0.5169(3) 0.77941(16) 0.0603(11) Uani 1 1 d . . . . .
 H15 H 0.326932 0.467969 0.796609 0.072 Uiso 1 1 calc R . . . .
 C16 C 0.30998(11) 1.0447(2) 0.69240(16) 0.0534(9) Uani 1 1 d . . . . .
 H16 H 0.327946 1.028376 0.676367 0.064 Uiso 1 1 calc R . . . .
 C17 C 0.24400(9) 0.8386(2) 0.67293(13) 0.0405(7) Uani 1 1 d . . . . .
 H17A H 0.231289 0.887868 0.672516 0.049 Uiso 1 1 calc R . . . .
 H17B H 0.255109 0.839577 0.641426 0.049 Uiso 1 1 calc R . . . .
 C18 C 0.16570(11) 0.6387(3) 0.64444(18) 0.0584(10) Uani 1 1 d . . . . .
 H18 H 0.180860 0.652022 0.678582 0.070 Uiso 1 1 calc R . . . .
 C19 C 0.41917(10) 0.7852(3) 0.56759(16) 0.0522(9) Uani 1 1 d . . . . .
 C20 C 0.16673(10) 0.8993(2) 0.54615(16) 0.0514(9) Uani 1 1 d . . . . .
 H20 H 0.184143 0.897881 0.526348 0.062 Uiso 1 1 calc R . . . .
 C21 C 0.39139(10) 0.8045(3) 0.59183(15) 0.0510(9) Uani 1 1 d . . . . .
 C22 C 0.33614(10) 0.8778(2) 0.79373(16) 0.0481(8) Uani 1 1 d . . . . .
 C23 C 0.14582(10) 0.6546(3) 0.54665(17) 0.0531(9) Uani 1 1 d . . . . .
 H23 H 0.147854 0.677852 0.512869 0.064 Uiso 1 1 calc R . . . .
 C24 C 0.53324(12) 0.7193(3) 0.43245(18) 0.0611(11) Uani 1 1 d . . . . .
 C25 C 0.17634(10) 0.4499(2) 0.45816(16) 0.0507(9) Uani 1 1 d . . . . .
 C26 C 0.33139(9) 0.6591(2) 0.73003(14) 0.0454(8) Uani 1 1 d . . . . .
 H26 H 0.332616 0.708327 0.713169 0.055 Uiso 1 1 calc R . . . .
 C27 C 0.41581(10) 0.7298(3) 0.52553(18) 0.0571(10) Uani 1 1 d . . . . .
 H27 H 0.394681 0.703997 0.512608 0.069 Uiso 1 1 calc R . . . .
 C28 C 0.25757(10) 1.0933(3) 0.73834(15) 0.0527(9) Uani 1 1 d . . . . .
 H28 H 0.239528 1.109875 0.754098 0.063 Uiso 1 1 calc R . . . .
 C29 C 0.37093(10) 0.8717(3) 0.79972(18) 0.0572(10) Uani 1 1 d . . . . .
 H29 H 0.380198 0.874784 0.768009 0.069 Uiso 1 1 calc R . . . .
 C30 C 0.11794(11) 0.9615(3) 0.5650(2) 0.0653(12) Uani 1 1 d . . . . .
 H30 H 0.101552 1.002078 0.557848 0.078 Uiso 1 1 calc R . . . .
 C31 C 0.36822(10) 0.8223(2) 0.61214(16) 0.0508(9) Uani 1 1 d . . . . .
 C32 C 0.33885(10) 0.5817(3) 0.81159(15) 0.0574(10) Uani 1 1 d . . . . .
 H32 H 0.345323 0.577118 0.850809 0.069 Uiso 1 1 calc R . . . .
 C33 C 0.13949(10) 0.8454(3) 0.61286(18) 0.0565(10) Uani 1 1 d . . . . .
 H33 H 0.138026 0.806489 0.639363 0.068 Uiso 1 1 calc R . . . .
 C34 C 0.34017(11) 0.6528(3) 0.78702(16) 0.0556(10) Uani 1 1 d . . . . .
 H34 H 0.347124 0.697567 0.809229 0.067 Uiso 1 1 calc R . . . .
 C35 C 0.14318(12) 0.9593(3) 0.53686(19) 0.0662(11) Uani 1 1 d . . . . .
 H35 H 0.144589 0.999054 0.510893 0.079 Uiso 1 1 calc R . . . .
 C36 C 0.53385(10) 0.7127(3) 0.52381(17) 0.0536(9) Uani 1 1 d . . . . .
 C37 C 0.11622(11) 0.9057(3) 0.6031(2) 0.0659(12) Uani 1 1 d . . . . .
 H37 H 0.098938 0.908232 0.623081 0.079 Uiso 1 1 calc R . . . .
 C38 C 0.14183(13) 0.5802(3) 0.6426(2) 0.0753(14) Uani 1 1 d . . . . .
 H38 H 0.141250 0.552731 0.675544 0.090 Uiso 1 1 calc R . . . .
 C39 C 0.55445(10) 0.7040(3) 0.48561(18) 0.0571(10) Uani 1 1 d . . . . .
 C40 C 0.35507(12) 0.4745(3) 0.60907(19) 0.0634(11) Uani 1 1 d . . . . .
 H40 H 0.336082 0.442929 0.610770 0.076 Uiso 1 1 calc R . . . .
 C41 C 0.44264(10) 0.7121(3) 0.50251(17) 0.0567(10) Uani 1 1 d . . . . .
 H41 H 0.440055 0.673232 0.474611 0.068 Uiso 1 1 calc R . . . .
 C42 C 0.26199(12) 0.3806(3) 0.5034(2) 0.0663(12) Uani 1 1 d . . . . .
 H42 H 0.254545 0.368937 0.535996 0.080 Uiso 1 1 calc R . . . .
 C43 C 0.32330(11) 0.8731(3) 0.84092(17) 0.0585(10) Uani 1 1 d . . . . .
 H43 H 0.299504 0.877318 0.837549 0.070 Uiso 1 1 calc R . . . .
 C44 C 0.37955(14) 0.8559(3) 0.8978(2) 0.0720(13) Uani 1 1 d . . . . .
 H44 H 0.394372 0.847850 0.933183 0.086 Uiso 1 1 calc R . . . .
 C45 C 0.37994(11) 0.6002(3) 0.6086(2) 0.0672(12) Uani 1 1 d . . . . .
 H45 H 0.378436 0.655264 0.610054 0.081 Uiso 1 1 calc R . . . .
 C46 C 0.27311(12) 1.1456(3) 0.71052(17) 0.0580(10) Uani 1 1 d . . . . .
 H46 H 0.265747 1.198213 0.706860 0.070 Uiso 1 1 calc R . . . .
 C47 C 0.29969(12) 1.1214(3) 0.68770(18) 0.0636(11) Uani 1 1 d . . . . .
 H47 H 0.310713 1.157609 0.668932 0.076 Uiso 1 1 calc R . . . .
 C48 C 0.34484(13) 0.8622(3) 0.89288(19) 0.0692(12) Uani 1 1 d . . . . .
 H48 H 0.335837 0.859103 0.924855 0.083 Uiso 1 1 calc R . . . .
 C49 C 0.45051(10) 0.8222(3) 0.58506(18) 0.0604(11) Uani 1 1 d . . . . .
 H49 H 0.453539 0.859889 0.613788 0.072 Uiso 1 1 calc R . . . .
 C50 C 0.28432(13) 0.4146(5) 0.4093(2) 0.0874(18) Uani 1 1 d . . . . .
 H50 H 0.292098 0.426338 0.376997 0.105 Uiso 1 1 calc R . . . .
 C51 C 0.12143(11) 0.5981(3) 0.5459(2) 0.0652(11) Uani 1 1 d . . . . .
 H51 H 0.106182 0.584489 0.511941 0.078 Uiso 1 1 calc R . . . .
 C52 C 0.50052(12) 0.7370(3) 0.43857(19) 0.0666(12) Uani 1 1 d . . . . .
 C53 C 0.47334(10) 0.7504(3) 0.51971(18) 0.0563(10) Uani 1 1 d . . . . .
 C54 C 0.47719(10) 0.8050(3) 0.56136(19) 0.0628(11) Uani 1 1 d . . . . .
 H54 H 0.498340 0.830866 0.573826 0.075 Uiso 1 1 calc R . . . .
 C55 C 0.54644(11) 0.6978(3) 0.57938(19) 0.0638(11) Uani 1 1 d . . . . .
 H55 H 0.532437 0.702959 0.604974 0.077 Uiso 1 1 calc R . . . .
 C56 C 0.58830(11) 0.6820(3) 0.5051(2) 0.0643(12) Uani 1 1 d . . . . .
 H56 H 0.602616 0.676325 0.480027 0.077 Uiso 1 1 calc R . . . .
 C57 C 0.11909(11) 0.5614(3) 0.5942(2) 0.0710(13) Uani 1 1 d . . . . .
 H57 H 0.101936 0.523601 0.593918 0.085 Uiso 1 1 calc R . . . .
 C58 C 0.39243(13) 0.8611(3) 0.8520(2) 0.0754(14) Uani 1 1 d . . . . .
 H58 H 0.416274 0.857537 0.855700 0.091 Uiso 1 1 calc R . . . .
 C59 C 0.57986(12) 0.6752(3) 0.5968(2) 0.0716(12) Uani 1 1 d . . . . .
 H59 H 0.588893 0.663837 0.634835 0.086 Uiso 1 1 calc R . . . .
 C60 C 0.28610(14) 0.3340(3) 0.4886(3) 0.0869(17) Uani 1 1 d . . . . .
 H60 H 0.295369 0.290642 0.510817 0.104 Uiso 1 1 calc R . . . .
 C61 C 0.14601(12) 0.4892(3) 0.4451(2) 0.0808(15) Uani 1 1 d . . . . .
 H61 H 0.145646 0.544256 0.447961 0.097 Uiso 1 1 calc R . . . .
 C62 C 0.60069(12) 0.6687(3) 0.5598(2) 0.0715(13) Uani 1 1 d . . . . .
 H62 H 0.623892 0.654706 0.573118 0.086 Uiso 1 1 calc R . . . .
 C63 C 0.38504(14) 0.4404(3) 0.6048(2) 0.0803(15) Uani 1 1 d . . . . .
 H63 H 0.386788 0.385374 0.603658 0.096 Uiso 1 1 calc R . . . .
 C64 C 0.41228(14) 0.4857(4) 0.6022(2) 0.0835(16) Uani 1 1 d . . . . .
 H64 H 0.432883 0.461911 0.598875 0.100 Uiso 1 1 calc R . . . .
 C65 C 0.17644(13) 0.3700(3) 0.4517(2) 0.0768(15) Uani 1 1 d . . . . .
 H65 H 0.197351 0.342325 0.459500 0.092 Uiso 1 1 calc R . . . .
 C66 C 0.41027(12) 0.5652(4) 0.6042(3) 0.0852(16) Uani 1 1 d . . . . .
 H66 H 0.429419 0.596256 0.602602 0.102 Uiso 1 1 calc R . . . .
 C67 C 0.29671(15) 0.3516(4) 0.4402(3) 0.096(2) Uani 1 1 d . . . . .
 H67 H 0.312809 0.319017 0.429027 0.115 Uiso 1 1 calc R . . . .
 C68 C 0.53935(15) 0.7209(4) 0.3787(2) 0.0833(16) Uani 1 1 d . . . . .
 H68 H 0.561223 0.709397 0.372963 0.100 Uiso 1 1 calc R . . . .
 C69 C 0.14602(16) 0.3303(4) 0.4339(3) 0.107(2) Uani 1 1 d . . . . .
 H69 H 0.146107 0.275434 0.429236 0.128 Uiso 1 1 calc R . . . .
 C70 C 0.47397(14) 0.7563(4) 0.3947(2) 0.0897(19) Uani 1 1 d . . . . .
 H70 H 0.452231 0.770128 0.399990 0.108 Uiso 1 1 calc R . . . .
 C71 C 0.11582(15) 0.4481(4) 0.4275(4) 0.119(3) Uani 1 1 d . . . . .
 H71 H 0.094798 0.475298 0.418478 0.143 Uiso 1 1 calc R . . . .
 C72 C 0.11620(17) 0.3695(4) 0.4233(3) 0.112(2) Uani 1 1 d . . . . .
 H72 H 0.095381 0.341715 0.412716 0.135 Uiso 1 1 calc R . . . .
 C73 C 0.48077(18) 0.7545(5) 0.3418(3) 0.110(2) Uani 1 1 d . . . . .
 H73 H 0.462829 0.763705 0.310131 0.132 Uiso 1 1 calc R . . . .
 C74 C 0.51287(17) 0.7395(5) 0.3351(3) 0.109(2) Uani 1 1 d . . . . .
 H74 H 0.516847 0.742172 0.298931 0.130 Uiso 1 1 calc R . . . .


_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes)
 are estimated using the full covariance matrix.  The cell esds are taken
 into account individually in the estimation of esds in distances, angles
 and torsion angles; correlations between esds in cell parameters are only
 used when they are defined by crystal symmetry.  An approximate (isotropic)
 treatment of cell esds is used for estimating esds involving l.s. planes.
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 Au01 Au01 2.6178(2) 7_566 ?
 Au01 Au02 2.84212(18) . ?
 Au01 Au02 2.85219(18) 7_566 ?
 Au01 Au03 2.90083(18) 7_566 ?
 Au01 Au03 2.81354(19) . ?
 Au01 P005 2.3052(7) . ?
 Au02 Au01 2.85216(18) 7_566 ?
 Au02 Au03 2.64965(19) 7_566 ?
 Au02 Au04 3.0677(2) . ?
 Au02 P006 2.3228(9) . ?
 Au03 Au01 2.90082(18) 7_566 ?
 Au03 Au02 2.64966(19) 7_566 ?
 Au03 Au04 3.1028(2) 7_566 ?
 Au03 P007 2.3239(9) . ?
 Au04 Au03 3.1027(2) 7_566 ?
 Au04 P008 2.2996(8) . ?
 Au04 C31 2.005(4) . ?
 P005 C2 1.821(4) . ?
 P005 C9 1.819(3) . ?
 P005 C11 1.814(4) . ?
 P006 C4 1.830(3) . ?
 P006 C7 1.822(4) . ?
 P006 C14 1.831(4) . ?
 P007 C1 1.830(3) . ?
 P007 C10 1.810(4) . ?
 P007 C25 1.819(4) . ?
 P008 C5 1.809(4) . ?
 P008 C6 1.816(4) . ?
 P008 C22 1.818(4) . ?
 C1 H1A 0.9900 . ?
 C1 H1B 0.9900 . ?
 C1 C3 1.523(5) . ?
 C2 C18 1.392(5) . ?
 C2 C23 1.382(5) . ?
 C3 H3A 0.9900 . ?
 C3 H3B 0.9900 . ?
 C3 C7 1.524(5) . ?
 C4 C13 1.386(5) . ?
 C4 C26 1.383(5) . ?
 C5 C8 1.394(5) . ?
 C5 C16 1.394(5) . ?
 C6 H6A 0.9900 . ?
 C6 H6B 0.9900 . ?
 C6 C17 1.527(5) . ?
 C7 H7A 0.9900 . ?
 C7 H7B 0.9900 . ?
 C8 H8 0.9500 . ?
 C8 C28 1.389(6) . ?
 C9 H9A 0.9900 . ?
 C9 H9B 0.9900 . ?
 C9 C17 1.519(5) . ?
 C10 C12 1.397(5) . ?
 C10 C42 1.388(6) . ?
 C11 C20 1.381(5) . ?
 C11 C33 1.388(5) . ?
 C12 H12 0.9500 . ?
 C12 C50 1.386(7) . ?
 N00M C36 1.400(5) . ?
 N00M C52 1.399(6) . ?
 N00M C53 1.427(5) . ?
 C13 H13 0.9500 . ?
 C13 C15 1.392(5) . ?
 C14 C40 1.398(6) . ?
 C14 C45 1.366(6) . ?
 C15 H15 0.9500 . ?
 C15 C32 1.380(7) . ?
 C16 H16 0.9500 . ?
 C16 C47 1.379(6) . ?
 C17 H17A 0.9900 . ?
 C17 H17B 0.9900 . ?
 C18 H18 0.9500 . ?
 C18 C38 1.387(6) . ?
 C19 C21 1.434(5) . ?
 C19 C27 1.396(6) . ?
 C19 C49 1.393(6) . ?
 C20 H20 0.9500 . ?
 C20 C35 1.387(6) . ?
 C21 C31 1.204(5) . ?
 C22 C29 1.385(5) . ?
 C22 C43 1.391(6) . ?
 C23 H23 0.9500 . ?
 C23 C51 1.382(6) . ?
 C24 C39 1.419(6) . ?
 C24 C52 1.402(6) . ?
 C24 C68 1.414(6) . ?
 C25 C61 1.372(6) . ?
 C25 C65 1.382(6) . ?
 C26 H26 0.9500 . ?
 C26 C34 1.379(5) . ?
 C27 H27 0.9500 . ?
 C27 C41 1.376(6) . ?
 C28 H28 0.9500 . ?
 C28 C46 1.374(6) . ?
 C29 H29 0.9500 . ?
 C29 C58 1.394(6) . ?
 C30 H30 0.9500 . ?
 C30 C35 1.367(6) . ?
 C30 C37 1.360(7) . ?
 C32 H32 0.9500 . ?
 C32 C34 1.372(6) . ?
 C33 H33 0.9500 . ?
 C33 C37 1.383(6) . ?
 C34 H34 0.9500 . ?
 C35 H35 0.9500 . ?
 C36 C39 1.411(5) . ?
 C36 C55 1.377(6) . ?
 C37 H37 0.9500 . ?
 C38 H38 0.9500 . ?
 C38 C57 1.369(7) . ?
 C39 C56 1.394(6) . ?
 C40 H40 0.9500 . ?
 C40 C63 1.374(6) . ?
 C41 H41 0.9500 . ?
 C41 C53 1.382(6) . ?
 C42 H42 0.9500 . ?
 C42 C60 1.378(7) . ?
 C43 H43 0.9500 . ?
 C43 C48 1.389(6) . ?
 C44 H44 0.9500 . ?
 C44 C48 1.385(7) . ?
 C44 C58 1.361(7) . ?
 C45 H45 0.9500 . ?
 C45 C66 1.395(6) . ?
 C46 H46 0.9500 . ?
 C46 C47 1.393(6) . ?
 C47 H47 0.9500 . ?
 C48 H48 0.9500 . ?
 C49 H49 0.9500 . ?
 C49 C54 1.378(6) . ?
 C50 H50 0.9500 . ?
 C50 C67 1.353(9) . ?
 C51 H51 0.9500 . ?
 C51 C57 1.377(7) . ?
 C52 C70 1.378(7) . ?
 C53 C54 1.377(6) . ?
 C54 H54 0.9500 . ?
 C55 H55 0.9500 . ?
 C55 C59 1.376(6) . ?
 C56 H56 0.9500 . ?
 C56 C62 1.352(7) . ?
 C57 H57 0.9500 . ?
 C58 H58 0.9500 . ?
 C59 H59 0.9500 . ?
 C59 C62 1.390(7) . ?
 C60 H60 0.9500 . ?
 C60 C67 1.400(9) . ?
 C61 H61 0.9500 . ?
 C61 C71 1.389(7) . ?
 C62 H62 0.9500 . ?
 C63 H63 0.9500 . ?
 C63 C64 1.364(8) . ?
 C64 H64 0.9500 . ?
 C64 C66 1.369(8) . ?
 C65 H65 0.9500 . ?
 C65 C69 1.386(7) . ?
 C66 H66 0.9500 . ?
 C67 H67 0.9500 . ?
 C68 H68 0.9500 . ?
 C68 C74 1.370(8) . ?
 C69 H69 0.9500 . ?
 C69 C72 1.353(9) . ?
 C70 H70 0.9500 . ?
 C70 C73 1.404(8) . ?
 C71 H71 0.9500 . ?
 C71 C72 1.356(10) . ?
 C72 H72 0.9500 . ?
 C73 H73 0.9500 . ?
 C73 C74 1.373(9) . ?
 C74 H74 0.9500 . ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 Au01 Au01 Au02 62.827(6) 7_566 . ?
 Au01 Au01 Au02 62.437(5) 7_566 7_566 ?
 Au01 Au01 Au03 61.048(6) 7_566 7_566 ?
 Au01 Au01 Au03 64.447(6) 7_566 . ?
 Au02 Au01 Au02 125.264(5) . 7_566 ?
 Au02 Au01 Au03 54.940(5) . 7_566 ?
 Au02 Au01 Au03 97.363(5) 7_566 7_566 ?
 Au03 Au01 Au02 55.761(5) . 7_566 ?
 Au03 Au01 Au02 99.632(6) . . ?
 Au03 Au01 Au03 125.495(5) . 7_566 ?
 P005 Au01 Au01 176.51(2) . 7_566 ?
 P005 Au01 Au02 114.87(2) . . ?
 P005 Au01 Au02 119.80(2) . 7_566 ?
 P005 Au01 Au03 114.18(2) . . ?
 P005 Au01 Au03 120.23(2) . 7_566 ?
 Au01 Au02 Au01 54.737(5) . 7_566 ?
 Au01 Au02 Au04 123.612(6) 7_566 . ?
 Au01 Au02 Au04 113.904(6) . . ?
 Au03 Au02 Au01 63.656(5) 7_566 . ?
 Au03 Au02 Au01 61.380(5) 7_566 7_566 ?
 Au03 Au02 Au04 65.254(5) 7_566 . ?
 P006 Au02 Au01 119.45(2) . . ?
 P006 Au02 Au01 122.39(2) . 7_566 ?
 P006 Au02 Au03 175.91(2) . 7_566 ?
 P006 Au02 Au04 110.66(2) . . ?
 Au01 Au03 Au01 54.503(5) . 7_566 ?
 Au01 Au03 Au04 123.712(6) . 7_566 ?
 Au01 Au03 Au04 111.214(6) 7_566 7_566 ?
 Au02 Au03 Au01 62.858(5) 7_566 . ?
 Au02 Au03 Au01 61.405(5) 7_566 7_566 ?
 Au02 Au03 Au04 63.888(5) 7_566 7_566 ?
 P007 Au03 Au01 121.33(2) . . ?
 P007 Au03 Au01 130.56(2) . 7_566 ?
 P007 Au03 Au02 168.00(2) . 7_566 ?
 P007 Au03 Au04 107.73(2) . 7_566 ?
 Au02 Au04 Au03 50.856(4) . 7_566 ?
 P008 Au04 Au02 113.45(2) . . ?
 P008 Au04 Au03 108.60(2) . 7_566 ?
 C31 Au04 Au02 75.27(11) . . ?
 C31 Au04 Au03 83.02(11) . 7_566 ?
 C31 Au04 P008 168.19(11) . . ?
 C2 P005 Au01 117.05(12) . . ?
 C9 P005 Au01 111.45(11) . . ?
 C9 P005 C2 104.58(16) . . ?
 C11 P005 Au01 114.65(11) . . ?
 C11 P005 C2 102.40(16) . . ?
 C11 P005 C9 105.49(16) . . ?
 C4 P006 Au02 117.43(12) . . ?
 C4 P006 C14 100.87(16) . . ?
 C7 P006 Au02 108.36(12) . . ?
 C7 P006 C4 107.23(16) . . ?
 C7 P006 C14 102.88(18) . . ?
 C14 P006 Au02 118.66(13) . . ?
 C1 P007 Au03 109.94(13) . . ?
 C10 P007 Au03 115.53(13) . . ?
 C10 P007 C1 108.07(17) . . ?
 C10 P007 C25 103.94(19) . . ?
 C25 P007 Au03 116.16(14) . . ?
 C25 P007 C1 102.09(16) . . ?
 C5 P008 Au04 114.23(11) . . ?
 C5 P008 C6 106.04(17) . . ?
 C5 P008 C22 106.95(17) . . ?
 C6 P008 Au04 114.38(12) . . ?
 C6 P008 C22 104.10(17) . . ?
 C22 P008 Au04 110.39(13) . . ?
 P007 C1 H1A 108.5 . . ?
 P007 C1 H1B 108.5 . . ?
 H1A C1 H1B 107.5 . . ?
 C3 C1 P007 115.2(2) . . ?
 C3 C1 H1A 108.5 . . ?
 C3 C1 H1B 108.5 . . ?
 C18 C2 P005 123.1(3) . . ?
 C23 C2 P005 118.1(3) . . ?
 C23 C2 C18 118.7(4) . . ?
 C1 C3 H3A 109.1 . . ?
 C1 C3 H3B 109.1 . . ?
 C1 C3 C7 112.7(3) . . ?
 H3A C3 H3B 107.8 . . ?
 C7 C3 H3A 109.1 . . ?
 C7 C3 H3B 109.1 . . ?
 C13 C4 P006 120.5(3) . . ?
 C26 C4 P006 119.6(3) . . ?
 C26 C4 C13 119.5(3) . . ?
 C8 C5 P008 121.8(3) . . ?
 C8 C5 C16 118.4(4) . . ?
 C16 C5 P008 119.8(3) . . ?
 P008 C6 H6A 109.3 . . ?
 P008 C6 H6B 109.3 . . ?
 H6A C6 H6B 108.0 . . ?
 C17 C6 P008 111.6(2) . . ?
 C17 C6 H6A 109.3 . . ?
 C17 C6 H6B 109.3 . . ?
 P006 C7 H7A 108.2 . . ?
 P006 C7 H7B 108.2 . . ?
 C3 C7 P006 116.3(3) . . ?
 C3 C7 H7A 108.2 . . ?
 C3 C7 H7B 108.2 . . ?
 H7A C7 H7B 107.4 . . ?
 C5 C8 H8 119.7 . . ?
 C28 C8 C5 120.6(4) . . ?
 C28 C8 H8 119.7 . . ?
 P005 C9 H9A 109.2 . . ?
 P005 C9 H9B 109.2 . . ?
 H9A C9 H9B 107.9 . . ?
 C17 C9 P005 111.9(2) . . ?
 C17 C9 H9A 109.2 . . ?
 C17 C9 H9B 109.2 . . ?
 C12 C10 P007 117.5(3) . . ?
 C42 C10 P007 123.7(3) . . ?
 C42 C10 C12 118.7(4) . . ?
 C20 C11 P005 120.6(3) . . ?
 C20 C11 C33 118.7(4) . . ?
 C33 C11 P005 120.7(3) . . ?
 C10 C12 H12 120.0 . . ?
 C50 C12 C10 120.0(5) . . ?
 C50 C12 H12 120.0 . . ?
 C36 N00M C53 125.4(3) . . ?
 C52 N00M C36 108.0(3) . . ?
 C52 N00M C53 126.5(4) . . ?
 C4 C13 H13 120.3 . . ?
 C4 C13 C15 119.4(4) . . ?
 C15 C13 H13 120.3 . . ?
 C40 C14 P006 121.3(3) . . ?
 C45 C14 P006 119.3(3) . . ?
 C45 C14 C40 119.2(4) . . ?
 C13 C15 H15 119.8 . . ?
 C32 C15 C13 120.4(4) . . ?
 C32 C15 H15 119.8 . . ?
 C5 C16 H16 119.5 . . ?
 C47 C16 C5 121.0(4) . . ?
 C47 C16 H16 119.5 . . ?
 C6 C17 H17A 109.4 . . ?
 C6 C17 H17B 109.4 . . ?
 C9 C17 C6 111.4(3) . . ?
 C9 C17 H17A 109.4 . . ?
 C9 C17 H17B 109.4 . . ?
 H17A C17 H17B 108.0 . . ?
 C2 C18 H18 120.2 . . ?
 C38 C18 C2 119.6(4) . . ?
 C38 C18 H18 120.2 . . ?
 C27 C19 C21 121.6(4) . . ?
 C49 C19 C21 120.7(4) . . ?
 C49 C19 C27 117.7(4) . . ?
 C11 C20 H20 119.9 . . ?
 C11 C20 C35 120.3(4) . . ?
 C35 C20 H20 119.9 . . ?
 C31 C21 C19 178.6(5) . . ?
 C29 C22 P008 119.9(3) . . ?
 C29 C22 C43 118.5(4) . . ?
 C43 C22 P008 121.6(3) . . ?
 C2 C23 H23 119.6 . . ?
 C51 C23 C2 120.7(4) . . ?
 C51 C23 H23 119.6 . . ?
 C52 C24 C39 108.6(4) . . ?
 C52 C24 C68 118.6(5) . . ?
 C68 C24 C39 132.8(4) . . ?
 C61 C25 P007 118.4(3) . . ?
 C61 C25 C65 119.3(4) . . ?
 C65 C25 P007 122.3(4) . . ?
 C4 C26 H26 119.7 . . ?
 C34 C26 C4 120.7(4) . . ?
 C34 C26 H26 119.7 . . ?
 C19 C27 H27 119.5 . . ?
 C41 C27 C19 121.0(4) . . ?
 C41 C27 H27 119.5 . . ?
 C8 C28 H28 119.9 . . ?
 C46 C28 C8 120.3(4) . . ?
 C46 C28 H28 119.9 . . ?
 C22 C29 H29 119.8 . . ?
 C22 C29 C58 120.4(4) . . ?
 C58 C29 H29 119.8 . . ?
 C35 C30 H30 119.9 . . ?
 C37 C30 H30 119.9 . . ?
 C37 C30 C35 120.2(4) . . ?
 C21 C31 Au04 170.3(3) . . ?
 C15 C32 H32 120.0 . . ?
 C34 C32 C15 120.1(4) . . ?
 C34 C32 H32 120.0 . . ?
 C11 C33 H33 119.9 . . ?
 C37 C33 C11 120.2(4) . . ?
 C37 C33 H33 119.9 . . ?
 C26 C34 H34 120.0 . . ?
 C32 C34 C26 119.9(4) . . ?
 C32 C34 H34 120.0 . . ?
 C20 C35 H35 119.9 . . ?
 C30 C35 C20 120.2(4) . . ?
 C30 C35 H35 119.9 . . ?
 N00M C36 C39 109.0(4) . . ?
 C55 C36 N00M 129.9(4) . . ?
 C55 C36 C39 121.1(4) . . ?
 C30 C37 C33 120.4(4) . . ?
 C30 C37 H37 119.8 . . ?
 C33 C37 H37 119.8 . . ?
 C18 C38 H38 119.4 . . ?
 C57 C38 C18 121.3(4) . . ?
 C57 C38 H38 119.4 . . ?
 C36 C39 C24 106.4(4) . . ?
 C56 C39 C24 134.7(4) . . ?
 C56 C39 C36 118.9(4) . . ?
 C14 C40 H40 119.9 . . ?
 C63 C40 C14 120.3(5) . . ?
 C63 C40 H40 119.9 . . ?
 C27 C41 H41 119.8 . . ?
 C27 C41 C53 120.4(4) . . ?
 C53 C41 H41 119.8 . . ?
 C10 C42 H42 119.4 . . ?
 C60 C42 C10 121.1(5) . . ?
 C60 C42 H42 119.4 . . ?
 C22 C43 H43 119.6 . . ?
 C48 C43 C22 120.8(4) . . ?
 C48 C43 H43 119.6 . . ?
 C48 C44 H44 120.0 . . ?
 C58 C44 H44 120.0 . . ?
 C58 C44 C48 120.1(4) . . ?
 C14 C45 H45 119.9 . . ?
 C14 C45 C66 120.2(5) . . ?
 C66 C45 H45 119.9 . . ?
 C28 C46 H46 120.1 . . ?
 C28 C46 C47 119.9(4) . . ?
 C47 C46 H46 120.1 . . ?
 C16 C47 C46 119.9(4) . . ?
 C16 C47 H47 120.1 . . ?
 C46 C47 H47 120.1 . . ?
 C43 C48 H48 120.2 . . ?
 C44 C48 C43 119.6(5) . . ?
 C44 C48 H48 120.2 . . ?
 C19 C49 H49 119.4 . . ?
 C54 C49 C19 121.1(4) . . ?
 C54 C49 H49 119.4 . . ?
 C12 C50 H50 119.8 . . ?
 C67 C50 C12 120.4(5) . . ?
 C67 C50 H50 119.8 . . ?
 C23 C51 H51 119.8 . . ?
 C57 C51 C23 120.4(4) . . ?
 C57 C51 H51 119.8 . . ?
 N00M C52 C24 108.0(4) . . ?
 C70 C52 N00M 128.8(4) . . ?
 C70 C52 C24 123.2(5) . . ?
 C41 C53 N00M 120.6(4) . . ?
 C54 C53 N00M 120.0(4) . . ?
 C54 C53 C41 119.4(4) . . ?
 C49 C54 H54 119.8 . . ?
 C53 C54 C49 120.4(4) . . ?
 C53 C54 H54 119.8 . . ?
 C36 C55 H55 121.0 . . ?
 C59 C55 C36 118.1(4) . . ?
 C59 C55 H55 121.0 . . ?
 C39 C56 H56 120.1 . . ?
 C62 C56 C39 119.8(4) . . ?
 C62 C56 H56 120.1 . . ?
 C38 C57 C51 119.0(4) . . ?
 C38 C57 H57 120.5 . . ?
 C51 C57 H57 120.5 . . ?
 C29 C58 H58 119.7 . . ?
 C44 C58 C29 120.6(5) . . ?
 C44 C58 H58 119.7 . . ?
 C55 C59 H59 119.3 . . ?
 C55 C59 C62 121.4(5) . . ?
 C62 C59 H59 119.3 . . ?
 C42 C60 H60 120.6 . . ?
 C42 C60 C67 118.8(6) . . ?
 C67 C60 H60 120.6 . . ?
 C25 C61 H61 120.1 . . ?
 C25 C61 C71 119.8(5) . . ?
 C71 C61 H61 120.1 . . ?
 C56 C62 C59 120.7(4) . . ?
 C56 C62 H62 119.6 . . ?
 C59 C62 H62 119.6 . . ?
 C40 C63 H63 120.0 . . ?
 C64 C63 C40 119.9(5) . . ?
 C64 C63 H63 120.0 . . ?
 C63 C64 H64 119.6 . . ?
 C63 C64 C66 120.8(5) . . ?
 C66 C64 H64 119.6 . . ?
 C25 C65 H65 120.0 . . ?
 C25 C65 C69 119.9(5) . . ?
 C69 C65 H65 120.0 . . ?
 C45 C66 H66 120.2 . . ?
 C64 C66 C45 119.6(5) . . ?
 C64 C66 H66 120.2 . . ?
 C50 C67 C60 120.8(5) . . ?
 C50 C67 H67 119.6 . . ?
 C60 C67 H67 119.6 . . ?
 C24 C68 H68 120.9 . . ?
 C74 C68 C24 118.1(5) . . ?
 C74 C68 H68 120.9 . . ?
 C65 C69 H69 119.9 . . ?
 C72 C69 C65 120.1(6) . . ?
 C72 C69 H69 119.9 . . ?
 C52 C70 H70 121.8 . . ?
 C52 C70 C73 116.4(5) . . ?
 C73 C70 H70 121.8 . . ?
 C61 C71 H71 119.8 . . ?
 C72 C71 C61 120.3(6) . . ?
 C72 C71 H71 119.8 . . ?
 C69 C72 C71 120.5(6) . . ?
 C69 C72 H72 119.8 . . ?
 C71 C72 H72 119.8 . . ?
 C70 C73 H73 119.4 . . ?
 C74 C73 C70 121.2(6) . . ?
 C74 C73 H73 119.4 . . ?
 C68 C74 C73 122.3(6) . . ?
 C68 C74 H74 118.8 . . ?
 C73 C74 H74 118.8 . . ?

loop_
  _geom_torsion_atom_site_label_1
  _geom_torsion_atom_site_label_2
  _geom_torsion_atom_site_label_3
  _geom_torsion_atom_site_label_4
  _geom_torsion
  _geom_torsion_site_symmetry_1
  _geom_torsion_site_symmetry_2
  _geom_torsion_site_symmetry_3
  _geom_torsion_site_symmetry_4
  _geom_torsion_publ_flag
 Au01 P005 C2 C18 128.7(3) . . . . ?
 Au01 P005 C2 C23 -54.6(3) . . . . ?
 Au01 P005 C9 C17 52.8(3) . . . . ?
 Au01 P005 C11 C20 -7.5(3) . . . . ?
 Au01 P005 C11 C33 171.0(3) . . . . ?
 Au02 P006 C4 C13 159.4(3) . . . . ?
 Au02 P006 C4 C26 -27.5(3) . . . . ?
 Au02 P006 C7 C3 -55.7(3) . . . . ?
 Au02 P006 C14 C40 -149.3(3) . . . . ?
 Au02 P006 C14 C45 35.5(4) . . . . ?
 Au03 P007 C1 C3 -46.4(3) . . . . ?
 Au03 P007 C10 C12 -30.2(3) . . . . ?
 Au03 P007 C10 C42 151.4(3) . . . . ?
 Au03 P007 C25 C61 -29.8(4) . . . . ?
 Au03 P007 C25 C65 152.4(4) . . . . ?
 Au04 P008 C5 C8 157.4(3) . . . . ?
 Au04 P008 C5 C16 -22.2(3) . . . . ?
 Au04 P008 C6 C17 -61.5(3) . . . . ?
 Au04 P008 C22 C29 18.9(4) . . . . ?
 Au04 P008 C22 C43 -160.3(3) . . . . ?
 P005 C2 C18 C38 174.0(4) . . . . ?
 P005 C2 C23 C51 -171.9(4) . . . . ?
 P005 C9 C17 C6 -163.7(2) . . . . ?
 P005 C11 C20 C35 177.9(3) . . . . ?
 P005 C11 C33 C37 -177.9(3) . . . . ?
 P006 C4 C13 C15 172.8(3) . . . . ?
 P006 C4 C26 C34 -173.2(3) . . . . ?
 P006 C14 C40 C63 -175.4(4) . . . . ?
 P006 C14 C45 C66 175.6(4) . . . . ?
 P007 C1 C3 C7 -62.1(4) . . . . ?
 P007 C10 C12 C50 -175.8(4) . . . . ?
 P007 C10 C42 C60 176.4(4) . . . . ?
 P007 C25 C61 C71 -175.5(5) . . . . ?
 P007 C25 C65 C69 175.7(5) . . . . ?
 P008 C5 C8 C28 -179.0(3) . . . . ?
 P008 C5 C16 C47 179.5(3) . . . . ?
 P008 C6 C17 C9 159.5(2) . . . . ?
 P008 C22 C29 C58 -179.3(4) . . . . ?
 P008 C22 C43 C48 179.0(4) . . . . ?
 C1 P007 C10 C12 -153.8(3) . . . . ?
 C1 P007 C10 C42 27.8(4) . . . . ?
 C1 P007 C25 C61 89.8(4) . . . . ?
 C1 P007 C25 C65 -88.0(4) . . . . ?
 C1 C3 C7 P006 169.9(2) . . . . ?
 C2 P005 C9 C17 -179.8(3) . . . . ?
 C2 P005 C11 C20 -135.3(3) . . . . ?
 C2 P005 C11 C33 43.2(3) . . . . ?
 C2 C18 C38 C57 -1.8(8) . . . . ?
 C2 C23 C51 C57 -2.8(7) . . . . ?
 C4 P006 C7 C3 71.9(3) . . . . ?
 C4 P006 C14 C40 80.9(4) . . . . ?
 C4 P006 C14 C45 -94.2(4) . . . . ?
 C4 C13 C15 C32 -0.2(6) . . . . ?
 C4 C26 C34 C32 0.8(6) . . . . ?
 C5 P008 C6 C17 65.3(3) . . . . ?
 C5 P008 C22 C29 -105.9(4) . . . . ?
 C5 P008 C22 C43 74.9(4) . . . . ?
 C5 C8 C28 C46 -0.4(6) . . . . ?
 C5 C16 C47 C46 -0.7(7) . . . . ?
 C6 P008 C5 C8 30.5(3) . . . . ?
 C6 P008 C5 C16 -149.1(3) . . . . ?
 C6 P008 C22 C29 142.1(3) . . . . ?
 C6 P008 C22 C43 -37.1(4) . . . . ?
 C7 P006 C4 C13 37.2(3) . . . . ?
 C7 P006 C4 C26 -149.7(3) . . . . ?
 C7 P006 C14 C40 -29.8(4) . . . . ?
 C7 P006 C14 C45 155.1(3) . . . . ?
 C8 C5 C16 C47 0.0(6) . . . . ?
 C8 C28 C46 C47 -0.4(6) . . . . ?
 C9 P005 C2 C18 4.9(4) . . . . ?
 C9 P005 C2 C23 -178.4(3) . . . . ?
 C9 P005 C11 C20 115.5(3) . . . . ?
 C9 P005 C11 C33 -66.0(3) . . . . ?
 C10 P007 C1 C3 80.5(3) . . . . ?
 C10 P007 C25 C61 -157.9(4) . . . . ?
 C10 P007 C25 C65 24.3(4) . . . . ?
 C10 C12 C50 C67 -1.2(8) . . . . ?
 C10 C42 C60 C67 -0.3(8) . . . . ?
 C11 P005 C2 C18 -105.0(3) . . . . ?
 C11 P005 C2 C23 71.7(3) . . . . ?
 C11 P005 C9 C17 -72.2(3) . . . . ?
 C11 C20 C35 C30 -0.4(7) . . . . ?
 C11 C33 C37 C30 0.4(7) . . . . ?
 C12 C10 C42 C60 -2.0(7) . . . . ?
 C12 C50 C67 C60 -1.2(9) . . . . ?
 N00M C36 C39 C24 -0.5(5) . . . . ?
 N00M C36 C39 C56 -178.9(4) . . . . ?
 N00M C36 C55 C59 177.4(5) . . . . ?
 N00M C52 C70 C73 -179.5(6) . . . . ?
 N00M C53 C54 C49 179.4(4) . . . . ?
 C13 C4 C26 C34 -0.1(5) . . . . ?
 C13 C15 C32 C34 0.9(7) . . . . ?
 C14 P006 C4 C13 -70.0(3) . . . . ?
 C14 P006 C4 C26 103.0(3) . . . . ?
 C14 P006 C7 C3 177.8(3) . . . . ?
 C14 C40 C63 C64 -0.2(8) . . . . ?
 C14 C45 C66 C64 0.0(9) . . . . ?
 C15 C32 C34 C26 -1.2(6) . . . . ?
 C16 C5 C8 C28 0.6(5) . . . . ?
 C18 C2 C23 C51 5.0(6) . . . . ?
 C18 C38 C57 C51 4.0(8) . . . . ?
 C19 C27 C41 C53 -1.6(7) . . . . ?
 C19 C49 C54 C53 -0.1(8) . . . . ?
 C20 C11 C33 C37 0.6(6) . . . . ?
 C21 C19 C27 C41 179.8(4) . . . . ?
 C21 C19 C49 C54 -178.9(4) . . . . ?
 C22 P008 C5 C8 -80.2(3) . . . . ?
 C22 P008 C5 C16 100.3(3) . . . . ?
 C22 P008 C6 C17 177.9(3) . . . . ?
 C22 C29 C58 C44 0.6(8) . . . . ?
 C22 C43 C48 C44 -0.1(7) . . . . ?
 C23 C2 C18 C38 -2.7(7) . . . . ?
 C23 C51 C57 C38 -1.7(8) . . . . ?
 C24 C39 C56 C62 -177.2(5) . . . . ?
 C24 C52 C70 C73 2.6(10) . . . . ?
 C24 C68 C74 C73 -1.7(12) . . . . ?
 C25 P007 C1 C3 -170.3(3) . . . . ?
 C25 P007 C10 C12 98.3(3) . . . . ?
 C25 P007 C10 C42 -80.1(4) . . . . ?
 C25 C61 C71 C72 -0.1(12) . . . . ?
 C25 C65 C69 C72 -0.5(11) . . . . ?
 C26 C4 C13 C15 -0.2(6) . . . . ?
 C27 C19 C49 C54 0.4(7) . . . . ?
 C27 C41 C53 N00M -178.5(4) . . . . ?
 C27 C41 C53 C54 1.9(7) . . . . ?
 C28 C46 C47 C16 1.0(7) . . . . ?
 C29 C22 C43 C48 -0.2(7) . . . . ?
 C33 C11 C20 C35 -0.6(6) . . . . ?
 C35 C30 C37 C33 -1.5(7) . . . . ?
 C36 N00M C52 C24 -0.7(6) . . . . ?
 C36 N00M C52 C70 -178.9(6) . . . . ?
 C36 N00M C53 C41 -126.6(5) . . . . ?
 C36 N00M C53 C54 52.9(7) . . . . ?
 C36 C39 C56 C62 0.6(7) . . . . ?
 C36 C55 C59 C62 1.0(8) . . . . ?
 C37 C30 C35 C20 1.4(7) . . . . ?
 C39 C24 C52 N00M 0.3(6) . . . . ?
 C39 C24 C52 C70 178.7(6) . . . . ?
 C39 C24 C68 C74 -178.9(6) . . . . ?
 C39 C36 C55 C59 0.9(7) . . . . ?
 C39 C56 C62 C59 1.3(8) . . . . ?
 C40 C14 C45 C66 0.3(7) . . . . ?
 C40 C63 C64 C66 0.5(9) . . . . ?
 C41 C53 C54 C49 -1.1(7) . . . . ?
 C42 C10 C12 C50 2.7(7) . . . . ?
 C42 C60 C67 C50 1.9(9) . . . . ?
 C43 C22 C29 C58 0.0(7) . . . . ?
 C45 C14 C40 C63 -0.2(7) . . . . ?
 C48 C44 C58 C29 -1.0(8) . . . . ?
 C49 C19 C27 C41 0.5(7) . . . . ?
 C52 N00M C36 C39 0.7(5) . . . . ?
 C52 N00M C36 C55 -176.1(5) . . . . ?
 C52 N00M C53 C41 55.7(7) . . . . ?
 C52 N00M C53 C54 -124.8(5) . . . . ?
 C52 C24 C39 C36 0.1(6) . . . . ?
 C52 C24 C39 C56 178.1(5) . . . . ?
 C52 C24 C68 C74 -0.2(9) . . . . ?
 C52 C70 C73 C74 -4.4(12) . . . . ?
 C53 N00M C36 C39 -177.3(4) . . . . ?
 C53 N00M C36 C55 5.8(8) . . . . ?
 C53 N00M C52 C24 177.4(4) . . . . ?
 C53 N00M C52 C70 -0.8(9) . . . . ?
 C55 C36 C39 C24 176.7(5) . . . . ?
 C55 C36 C39 C56 -1.7(7) . . . . ?
 C55 C59 C62 C56 -2.2(8) . . . . ?
 C58 C44 C48 C43 0.7(8) . . . . ?
 C61 C25 C65 C69 -2.1(9) . . . . ?
 C61 C71 C72 C69 -2.6(14) . . . . ?
 C63 C64 C66 C45 -0.4(10) . . . . ?
 C65 C25 C61 C71 2.4(9) . . . . ?
 C65 C69 C72 C71 2.9(13) . . . . ?
 C68 C24 C39 C36 178.9(6) . . . . ?
 C68 C24 C39 C56 -3.1(10) . . . . ?
 C68 C24 C52 N00M -178.6(5) . . . . ?
 C68 C24 C52 C70 -0.3(9) . . . . ?
 C70 C73 C74 C68 4.2(13) . . . . ?

_smtbx_masks_special_details       ?
loop_
  _smtbx_masks_void_nr
  _smtbx_masks_void_average_x
  _smtbx_masks_void_average_y
  _smtbx_masks_void_average_z
  _smtbx_masks_void_volume
  _smtbx_masks_void_count_electrons
  _smtbx_masks_void_content
 1 0.000 -0.439 -0.518 2892.2 729.3 ?
 2 0.500 -0.058 -0.379 2892.2 729.3 ?

_olex2_submission_special_instructions  'No special instructions were received'
_oxdiff_exptl_absorpt_empirical_details
;
Empirical correction (ABSPACK) includes:
- Absorption correction using spherical harmonics
- Frame scaling
;
_oxdiff_exptl_absorpt_empirical_full_max  1.216
_oxdiff_exptl_absorpt_empirical_full_min  0.834
