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{"sheet":"Table S19","index":0,"n_rows":35,"n_cols":20,"rows_kept":35,"merged":[[0,0,0,255]],"flags":["formulas_cached_only"]}
["Table S19.Screened metabolites in different comparison groups (cortex_vs_cotyledon, cortex_vs_vascular, cotyledon_vs_vascular, callus_vs_hypocotyl)based on AFADESI-MSI data. "]
["Metabolites","KEGG","Measured m/z","Adduct","Relative Error\n(ppm) "," Formula"," MS image","Average expression\ncortex_vs_cotyledon",null,"Average expression\ncortex_vs_cotyledon","average(cortex)","average(vascular)","Average expression\ncortex_vs_vascular","average(cotyledon)","average(vascular)","Average expression\ncotyledon_vs_vascular","average(callus)","average(hypocotyl)","Average expression\ncallus_vs_hypocotyl","Metabolic \npathway"]
["L-Arginine","C00062",197.101003436336,"+Na",0.648014642296551,"C6H14N4O2",null,529.955939617157,2517.21740267038,{"$nulls":4},3097.30676988602,1005.49136695862,{"$nulls":4},"Arginine and proline metabolism"]
["Agmatine","C00179",131.129322959777,"+H",2.10854270556837,"C5H14N4",null,2278.43823183298,37748.6994149423,null,25501.9105660272,38697.1117382813,null,36074.9262960243,1558.75375286102,{"$nulls":4},"Arginine and proline metabolism"]
["Spermidine","C00315",146.165272734448,"+H",1.19803729628713,"C7H19N3",null,25703.7673822021,33323.06650177,{"$nulls":10}," Glutathione metabolism "]
["Zeatin","C00371",237.145969391643,"+NH4",0.67185895248544,"C10H13N5O",null,50038.3788574219,55040.03453125,null,50227.8225097656,54353.8156152344,{"$nulls":4},40856.3623242188,46231.1773925781,null,"Zeatin biosynthesis"]
["Xanthine","C00385",170.066300718464,"+NH4",5.43713558803888,"C5H4N4O2",null,9122.88586761475,7336.64479522705,{"$nulls":4},7755.4601275444,11229.026711731,{"$nulls":4},"Purine metabolism"]
["N-Carbamoylputrescine","C00436",132.113341219102,"+H",2.11308032664356,"C5H13N3O",null,1056.70789425373,5465.62014125586,{"$nulls":4},4796.98099609375,578.959399089813,{"$nulls":4},"Arginine and proline metabolism"]
["D-Malic acid","C00497",133.013158640588,"-H",8.00418111183285,"C4H6O5",null,197611.387663574,95372.4892016602,null,198956.353300781,243836.406054688,null,83945.7319335938,236441.553476562,null,6929.78221981049,3636.55003322601,null,"Butanoate metabolism"]
["Indoleacetaldehyde","C00637",177.102321782062,"+NH4",0.609066337211661,"C10H9NO",null,651.739526330232,4102.29275505543,{"$nulls":10},"Tryptophan metabolism"]
["Urocanic acid","C00785",156.076928993872,"+NH4",1.2913367369133,"C6H6N2O2",null,1489.58074244499,3262.73577295423,{"$nulls":7},9750.12492705345,4122.64502046108,null,"Histidine metabolism"]
["Galactaric acid","C00879",209.029607520039,"-H",3.15637563814323,"C6H10O8",null,455.686594800949,3830.23531431198,{"$nulls":7},1821.53642753601,584.483750343323,null,"Ascorbate and \naldarate metabolism"]
["Linoleic acid","C01595",279.232620734457,"-H",1.10851498137486,"C18H32O2",null,32441.7403081989,1737.99139086723,null,33286.9111388397,5473.56388221741,null,1658.16565683842,5783.57432518244,{"$nulls":4},"Linoleic acid metabolism"]
["Elaidic acid","C01712",281.248355198983,"-H",0.800477630711197,"C18H34O2",null,30729.3402067566,2176.5160682106,null,32399.8000656891,5097.57458686829,null,32399.8000656891,5097.57458686829,{"$nulls":4},"/"]
["Dihydrozeatin","C02029",239.161618855074,"+NH4",0.663685396281445,"C10H15N5O",null,227196.2725,251211.663085938,null,228716.28578125,251829.570820313,null,228716.28578125,251829.570820313,null,182437.27578125,212199.956367187,null,"Zeatin biosynthesis"]
["L-Targinine","C03884",189.134629268087,"+H",0.547187403538687,"C7H16N4O2",{"$nulls":4},1910.92216331005,5721.28282241225,null,6229.525952034,2903.11463130951,{"$nulls":4},"/"]
["Geranic acid","C16461",191.104232644742,"+Na",0.0151160538678919,"C10H16O2",null,17284.6514648438,18862.4581591797,{"$nulls":10},"Geraniol degradation"]
["1,2,3-Propanetricarboxylic acid","C19806",175.023957355445,"-H",4.74582204143083,"C6H8O6",null,7398.94069752693,11488.4272406864,{"$nulls":10},"/"]
["Pyroglutamic acid","C01879",128.034241920149,"-H",8.21010719837569,"C5H7NO3",{"$nulls":4},2280.79059020996,1410.42219032288,null,2280.79059020996,1410.42219032288,null,3814.07273120403,899.894461116791,null," Glutathione metabolism "]
["N,N-Dimethylaniline","C02846",122.096732386223,"+H",3.13709642804407,"C8H11N",{"$nulls":4},17828.4521728516,21965.6049951172,null,19013.4546972656,22076.3841064453,{"$nulls":4},"/"]
["(S)-β-aminoisobutyrate","C03284",104.071079754305,"+H",5.29654642523218,"C4H9NO2",{"$nulls":4},5449.42725892663,2934.29922513843,null,3098.85653049469,5226.84271465301,{"$nulls":4},"\tValine, leucine and \nisoleucine degradation"]
["Succinic acid","C00042",117.018147291484,"-H",9.92485817341607,"C4H6O4",{"$nulls":4},7533.73972602844,5687.93606079102,{"$nulls":7},"Butanoate metabolism"]
["Asymmetric dimethylarginine","C03626",241.105811334438,"+K",1.0970517886337,"C8H18N4O2",{"$nulls":4},109172.207675781,136306.572890625,null,114298.64421875,136285.190839844,null,86750.0310742187,97314.5198046875,null,"/"]
["3'-Ketolactose","C05403",358.13523363052,"+NH4",2.43524914032267,"C12H20O11",{"$nulls":4},8122.71541259766,11142.8104516602,null,8273.11308349609,10916.5390087891,null,16674.6838391113,20923.7333447266,null,"/"]
["Isoeugenol","C10469",187.073105697427,"+Na",0.941179794916985,"C10H12O2",{"$nulls":4},20582.6538647461,25953.1396582031,null,21974.1885083008,26089.0202001953,{"$nulls":4},"Phenylpropanoid biosynthesis"]
["Dibutyl phthalate","C14214",301.14090272501,"+Na",0.353545431190578,"C16H22O4",null,119979.662617187,132659.642773437,{"$nulls":7},116754.541699219,136168.1571875,null,"/"]
["Furanogermenone","C17488",255.135440311963,"+Na",0.351076420272117,"C15H20O2",null,104812.535957031,113523.465488281,{"$nulls":4},1624.05354728699,3257.71762550354,{"$nulls":4},"/"]
["(S)-Isowillardiine","C08289",217.092180399855,"+NH4",4.26266456737528,"C7H9N3O4",{"$nulls":7},11354.5457666016,13374.0451000977,{"$nulls":4},"/"]
["Majoranin","C10191",361.091030644604,"+H",1.90213363740966,"C18H16O8",{"$nulls":7},11354.5457666016,13374.0451000977,null,22943.0204394531,29248.528125,null,"/"]
["L-Aspartic acid","C00049",132.029156111146,"-H",7.96495171678015,"C4H7NO4",{"$nulls":10},720.866682510376,168.815615692139,null,"beta-Alanine metabolism"]
["dTDP","C00363",154.061118587283,"-H",6.86714289918674,"C6H9N3O2",{"$nulls":10},16533.8189526367,20894.5324707031,null,"Pyrimidine metabolism "]
["Galabiose","C00760  ",377.085315358767,"-H",8.00418111183285,"C4H6O5",{"$nulls":10},4067.91410499573,2649.80810840607,null,"Starch and sucrose metabolism"]
["O-acetyl-L-serine","C00979",146.044790646436,"-H",3.15637563814323,"C6H10O8",{"$nulls":10},2700.11105506897,1558.4929076004,null,"Sulfur metabolism "]
["3-Hydroxymethylglutaric acid","C03761",161.044505849485,"+K",1.0970517886337,"C8H18N4O2",{"$nulls":10},3366.86125988007,1118.43333423615,null,"/"]
["Ureidoisobutyric acid","C05100",161.044505849485,"-H",6.31862918868601,"C6H10O5",{"$nulls":10},1624.08326568604,483.285029182434,null,"/"]